Geochemical controls on a calcite precipitating spring

A small spring fed stream was found to precipitate calcite by mainly inorganic processes and in a nonuniform manner. The spring water originated by rainwater falling in a 0.8 km² basin, infiltrating, and dissolving calcite and dolomite followed by dissolution of gypsum or anhydrite. The Ca²⁺/Mg²⁺ indicates that calcite is probably precipitated in the subsurface from a supersaturated solution. This water emerges from the spring still about 5 times supersaturated with respect to calcite and continues calcite precipitation. When 10 times supersaturation is reached, due to CO₂ degassing the precipitation is more rapid. The calcite accumulation from the stream with a flow of 5 l/s is calculated to be 12600 kg/yr with the highest rates in areas where CO₂ degassing is the greatest. The non-equilibrium, as shown by the high calcite supersaturation, is also reflected in a variable partitioning pattern for Sr²⁺ between the water and calcite.     

Petrological and trace element geochemical features of the Okete Volcanics,western North Island,New Zealand

The Okete Volcanics form small volume monogenetic volcanoes situated around the flanks of larger tholeiitic cones of the Plio-Pleistocene Alexandra Volcanics, in the back-arc tectonic environment of western North Island, New Zealand. The lavas and tuffs of the Okete Volcanics have compositions which include basanites, alkali olivine basalts, olivine tholeiites, and hawaiites. Most rocks have Mg numbers >66, >250 p.p.m. Ni, >500 p.p.m. Cr, and often contain ultramafic xenoliths, which indicate that they are very close to being primary magmas. The Okete Volcanics show geochemical trends, from basanite to hawaiite, of progressive depletion of both compatible and incompatible trace elements, progressive increase in Al₂O₃, and heavy REE and Y enrichment with crossingover REE patterns in the hawaiites. These geochemical trends can be accounted for by varying degrees of partial melting of a light REE enriched garnet peridotite with subsequent modification of the melts near source or during ascent by fractional crystallization of olivine and minor clinopyroxene. Mass balance calculations cannot quantitatively constrain the degree of partial melting or fractional crystallization, but nevertheless indicate that the Okete alkali olivine basalts, olivine tholeiites, and hawaiites have been derived by successively larger degrees of partial melting relative to basanites, and have also been progressively more modified by fractional crystallization than have the basanites. Sources of the alkalic melts lay at depths corresponding to >20 kb, and most of the ultramafic xenoliths, apart from some which may be cognate cumulates, are unrelated to the magmas that brought them to the surface. Magmas have changed in composition with time from older smaller-volume volcanoes of basanite or alkali olivine basalt compositions, to younger and more voluminous volcanoes which contain hawaiites. The geochemical trends shown by the Okete Volcanics and their spatial association with voluminous tholeiitic volcanism, are features which are different from those observed elsewhere in the Pliocene to Recent basaltic fields of northern North Island, and may be related to their unique tectonic setting, situated in a distinct structural domain.     

Experimental studies At 5–12 GPa of the Ondermatjie hypabyssal kimberlite

Liquidus and sub-liquidus phase relationships are reported for melts formed from an aphanitic kimberlite composition crystallized at 5–12 GPa and 900–1400 °C. The liquidus phase over the pressure range investigated is forsteritic olivine. This is followed with decreasing temperature by olivine plus garnet as the initial sub-liquidus solid phase assemblage. Supra-solidus assemblages consist of olivine+garnet+clinopyroxene+Mg-ilmenite+liquid at 5–7 GPa or olivine+garnet+clinopyroxene+hematite–ilmenite solid solutions (+/−perovskite)+liquid at 8–12 GPa. Phlogopite forms as a near-solidus phase only at 900 °C and 6 GPa. Orthopyroxene does not form at any temperature and pressure. All garnets formed at 6–7 GPa are Ti-rich almandine–grossular–pyrope solid solutions and not Cr-pyrope, whereas garnets formed above 8 GPa are Ti- and Fe³⁺-rich and have no natural counterparts. Quenched liquids are represented by magnesite at 10–12 GPa and Mg–Ca-carbonates at lower pressures. In addition to forming discrete crystals, Mg-ilmenite and hematite–ilmenite solid solutions occur as lamellar intergrowths that are identical in texture to naturally occurring intergrowths. Mg-ilmenite compositions at 6–7 GPa are similar to those of the natural occurrences, whereas clinopyroxenes are richer in Ca. The effects of graphite versus platinum capsules on the oxygen fugacity of the experimental charges and the composition of the olivine, clinopyroxene, Fe–Ti-oxides and garnets formed are described. These experimental data are interpreted to indicate that kimberlite magmas are unlikely to be formed by very small degrees of partial melting of a simple homogeneous carbonated garnet lherzolite mantle. It is proposed that kimberlite magmas form by extensive partial melting of metasomatized mantle, i.e. mineralogically complex carbonate-bearing veins in a lherzolitic/harzburgitic substrate, and that lamellar ilmenite–clinopyroxene intergrowths represent the products of non-equilibrium growth in kimberlite magma.     

Measurements of coupled fluid and sediment motion over mobile sand dunes in a laboratory flume

The relationship between turbulent fluid motions and sediment particle motions over mobile sand dunes was investigated by using a laser Doppler velocimeter and an acoustic backscatter system in laboratory experiments performed at the USDA-ARS-National Sedimentation Laboratory. Profiles of acoustic backscatter from particles and at-a-point turbulence data were collected while translating both measurement devices downstream at the speed of mobile dune bedforms. The resulting data set was used to examine the frequency （recurrence frequency） at which the fluctuating backscatter and fluid velocity signals exceeded magnitude thresholds based on the standard deviation （σ） of the local velocity and the magnitude the acoustic signal resulting from backscatter from suspended particles. The slope of the downstream and vertical velocity recurrence frequencies generally indicated a gradually increasing recurrence time with increasing elevation. The recurrence frequency for acoustic backscatter data was not strongly variable with elevation. The closest correspondence between the recurrence frequencies of sediment backscatter and vertical velocities at the 1σ magnitude threshold was in a region defined by X/L〈0.4 and y〈6 cm. The downstream velocity was most closely related to backscatter in a small region at 0.4〈X/L〈0.8 and less than 3-4 cm from the bed.     

中国大中城市流动人口迁移规律研究

本文在对西方国家人口流动研究进行综述的基础上,通过北京,天津,南京,廓坊,唐山和昆山等大中城市流动人口问卷调查,首次对大中城市流动人口迁移和流动特征,从业结构,迁移原因与途径进行了系统的研究。中国现在正在经历大规模的农村流动人口向城市迁移的过程。     

Three-Dimensional Scalar Microfront Systems in a Large-Eddy Simulation of Vegetation Canopy Flow

Large-eddy simulation is used to reproduce neutrallystratified airflow inside and immediately above a vegetation canopy. A passive scalaris released from the canopy and the evolution of scalar concentration above the canopyis studied. The most significant characteristic of the scalar concentration is the repeatedformation and dissipation of scalar microfronts, a phenomenon that has been observedin nature. These scalar microfronts consist of downstream-tilted regions of highscalar concentration gradients. Computer visualization tools and a conditional samplingand compositing technique are utilized to analyze these microfronts. Peaks in positivepressure perturbation exceeding an experimental threshold are found to be effectiveindicators of scalar microfronts. Convergence of the streamwise velocity componentand divergence of the cross-stream velocity component are observed in the immediatevicinity of scalar microfronts, which helps explain their relatively longlifetimes. Many of these three-dimensional features have been observedin previous field studies of canopy flow.     

On the role of criticality in coastal flows over irregular bottom topography

A simple expansion technique is developed for predicting the response of a horizontally sheared oceanic coastal flow over uniform coastal topography to variations in that bottom topography. The technique is illustrated by application to supercritical and subcritical flows. The response of the supercritical flow is local, while that of the subcritical flow extends downstream to be eventually attenuated by frictional damping. However, the response of both flow types is weak unless the flow is nearly critical.     

The eastern French Pyrenees: from mountain belt to foreland basin

The Pyrenees is a young mountain belt formed as part of the larger Alpine collision zone. This excursion explores the development of the Pyrenean Mountain Belt in southern France, from its early extensional phase in the mid‐Cretaceous and subsequent collisional phase, through its uplift and erosion in the Late Cretaceous and again in the Eocene, which led to the development of the Aquitaine‐Languedoc foreland basin. One of the complexities of the Pyrenean Belt is that thrusting, uplift and erosion during the Pyrenean orogeny exposed older Variscan basement rocks in the central core of the mountains, rocks which were metamorphosed during an earlier event in the late Carboniferous. Thus, this orogenic belt also tells the story of an earlier collision between Laurussia in the north and Gondwana in the south at c. 300 Ma, prior to the onset of the Pyrenean events at c. 100 Ma. Here we seek to unravel these two separate orogenic stories.     

A novel platform to evaluate the dampening of water and solute transport in an experimental channel under unsteady flow conditions

This paper presents a novel platform to study the dampening of water and solute transport in an experimental channel under unsteady flow conditions, where literature data are scarce. We address the question about what could be the smallest size of experimental platform that is useful for research, project studies, and teaching activities and that allows to do rational experiments characterized by small space occupation, short experimental duration, high measurement precision, high quality and reproducible experimental curves, low water and energy consumption, and the possibility to test a large variety of hydrograph scenarios. Whereas large scale hydraulic laboratories have focused their studies on sediment transport, our platform deals with solute transport. The objectives of our study are (a) building a platform that allows to do rational experiments, (b) enriching the lack of experimental data concerning water and solute transport under unsteady state conditions, and (c) studying the dampening of water and solute transport. We studied solute transport in a channel with lateral gain and lateral loss under different experimental configurations, and we show how the same lateral loss flow event can lead to different lateral loss mass repartitions under different configurations. In order to characterize water and solute dampening between the input and the output of the channel, we calculate dampening ratios based on peak coordinates of time flow curves and time mass curves and that express the decrease of peak amplitude and the increase of peak occurrence time between the input and output curves. Finally, we use a solute transport model coupling the diffusive wave equation for water transfer and the advection–diffusion equation for solute transport in order to simulate the experimental data. The simulations are quite good with a Nash–Sutcliffe efficiency NSE > 0.98 for water transfer and 0.84 < NSE < 0.97 for solute transport. This platform could serve hydrological modellers because it offers a variety of measured parameters (flow, water height, and solute concentration), at a fine time step under unsteady flow conditions.     

Correction to: Nexus between vulnerability and adaptive capacity of drought-prone rural households in northern Bangladesh

Natural Hazards - The article was published with a spelling error in one of the co-author names. The correct spelling is reflected in this correction, and the original work has been updated to...