Groundwater recharge in Pleistocene sediments overlying basalt aquifers in the Palouse Basin, USA: modeling of distributed recharge potential and identification of water pathways

Groundwater levels in basalt aquifers around the world have been declining for many years. Understanding water pathways is needed for solutions like artificial drainage. Water supply in the Palouse Basin, Washington and Idaho, USA, primarily relies on basalt aquifers. This study presents a combination of modeling and field observations to understand the spatial distribution of recharge pathways in the overlying Pleistocene sediments. A spatially distributed model was used to quantify potential recharge rates. The model shows clearly that recharge predominantly occurs through non-argilic soils and soils that are not underlain by fine-grained sediments, i.e. the upper area of the watershed. A field survey was conducted to determine recharge pathways from this area. It revealed 83 ?perennial springs. Drillings near springs showed connection of coarse-grained layers within the fine-grained Sediments of Bovill to these springs. Such layers, with streambed-like features, act as paleo-channels. Water from one of these coarse-grained layers had a similar electrical conductivity (200? ??S? cm^?C1) to water from a downstream perennial spring, also suggesting the existence of a lateral conduit for deep percolation water.     

Evaluating the impact of soil redistribution on the in situ mineralization of soil organic carbon

Soil erosion, transport and deposition by water drastically affect the distribution of soil organic carbon (SOC) within a landscape. Moreover, soil redistribution may have a large impact on the exchange of carbon (C) between the pedosphere and the atmosphere. One of the large information gaps within this research domain, concerns the fate of SOC after erosion by water. According to different (mainly laboratory) studies, soil redistribution leads to aggregate breakdown, thereby exposing the contained SOC to mineralization. Our study aims to quantify the extent to which such increased mineralization occurs in a real field situation. Carbon dioxide (CO₂)‐efflux was measured in the field after an important erosion event for a continuous period of 112 days. The specific situation on the field ensured that almost none of eroded SOC was exported from the field. Measurements of CO₂‐efflux were done in areas with sediment deposition, as well as in comparable areas without sedimentation. Comparison of these measurements allowed the net effect of soil deposition on CO₂‐efflux to be assessed. Field data were complemented by measurements on incubated, undisturbed soil core samples, in order to disentangle the contribution of environmental factors (moisture, temperature) from any erosional effect on CO₂‐efflux. Results of these measurements on the field showed that CO₂‐efflux was regulated by a complex interplay of different factors (mostly soil porosity, soil moisture and soil temperature). In combination with the incubation measurements, it could be concluded that the processes of erosion and transport indeed led to an increased mineralization of SOC, as a result of aggregate breakdown and exposure of previously encapsulated SOC. This effect was, however, much smaller than observed in previous laboratory studies. Moreover, it was only important in the first weeks, immediately after the erosion event. The calculated net erosional effect on CO₂‐efflux represented a mere 1·6% of total SOC, originally present in the soil. Copyright © 2010 John Wiley & Sons, Ltd.     

Short and zero baseline analysis of GPS L1 C/A, L5Q, GIOVE E1B, and E5aQ signals

Stochastic properties of GNSS range measurements can accurately be estimated using a geometry-free short and zero baseline analysis method. This method is now applied to dual-frequency measurements from a new field campaign. Results are presented for the new GPS L5Q and GIOVE E5aQ wideband signals, in addition to the GPS L1 C/A and GIOVE E1B signals. As expected, the results clearly show the high precision of the new signals, but they also show, rather unexpectedly, significant, slowly changing variations in the pseudorange code measurements that are probably a result of strong multipath interference on the data. Carrier phase measurement noise is assessed on both frequencies, and finally successful mixed GPS-GIOVE double difference ambiguity resolution is demonstrated.     

Wavefield smoothing and the effect of rough velocity perturbations on arrival times and amplitudes

Geometric ray theory is an extremely efficient tool for modelling wave propagation through heterogeneous media. Its use is, however, only justified when the inhomogeneity satisfies certain smoothness criteria. These criteria are often not satisfied, for example in wave propagation through turbulent media. In this paper, the effect of velocity perturbations on the phase and amplitude of transient wavefields is investigated for the situation that the velocity perturbation is not necessarily smooth enough to justify the use of ray theory. It is shown that the phase and amplitude perturbations of transient arrivals can to first order be written as weighted averages of the velocity perturbation over the first Fresnel zone. The resulting averaging integrals are derived for a homogeneous reference medium as well as for inhomogeneous reference media where the equations of dynamic ray tracing need to be invoked. The use of the averaging integrals is illustrated with a numerical example. This example also shows that the derived averaging integrals form a useful starting point for further approximations. The fact that the delay time due to the velocity perturbation can be expressed as a weighted average over the first Fresnel zone explains the success of tomographic inversions schemes that are based on ray theory in situations where ray theory is strictly not justified; in that situation one merely collapses the true sensitivity function over the first Fresnel zone to a line integral along a geometric ray.     

Resistant biomacromolecules in marine microalgae of the classes Eustigmatophyceae and Chlorophyceae: Geochemical implications

Non-hydrolysable macromolecular constituents (i.e. algaenans) were isolated from two out of seven marine microalgae investigated. Nannochloropsis salina and Nannochloropsis sp. from the class of Eustigmatophyceae produce highly aliphatic algaenans. Flash pyrolysis and chemical degradations with HI and RuO₄ allowed for the identification of their chemical structure, which is mainly composed of polyether-linked long-chain (up to C₃₆) n-alkyl units. The building blocks of this polymer were also recognized in lipid fractions. The green microalgae (Chlorophyceae) Chlorella spaerckii, Chlorococcum sp. and Nannochloris sp. were earlier thought to biosynthesize algaenans comprising aliphatic and/or aromatic moieties. However, a new isolation method utilizing trifluoroacetic acid (TFA) prior to the other hydrolyses revealed that the macromolecular material isolated from these three chlorophytes was either hydrolysable with TFA or artefacts from the former method. Similar to algaenans from fresh water green microalgae, the aliphatic eustigmatophyte algaenans are likely to be selectively preserved in depositional environments and might ultimately serve as source rock organic matter of marine crude oils. Furthermore, they may play an important role in the cycling of carbon.     

A Comparison of Strategies for Seismic Interferometry

The extraction of the response from field fluctuations excited by random sources has received considerable attention in a variety of different fields. We present three methods for the extraction of the systems response that are based on cross-correlation, deconvolution, and the solution of an integral equation, respectively. For systems that are invariant for time-reversal the correlation method requires random sources on a bounding surface only, but when time-reversal invariance is broken, for example by attenuation, a volume distribution of sources is needed. For this reason the correlation method is not useful for diffusive or strongly attenuating systems. We provide examples of the three methods and compare their merits and drawbacks. We show that the extracted field may satisfy different boundary conditions than does the physical field. This can be used, for example, to suppress surface-related multiples in exploration seismology, to study the coupling of buildings to the subsurface, and to remove the airwave in controlled source electromagnetics (CSEM).     

Review paper: Virtual sources and their responses,Part II: data‐driven single‐sided focusing

In Part I of this paper, we defined a focusing wave field as the time reversal of an observed point‐source response. We showed that emitting a time‐reversed field from a closed boundary yields a focal spot that acts as an isotropic virtual source. However, when emitting the field from an open boundary, the virtual source is highly directional and significant artefacts occur related to multiple scattering. The aim of this paper is to discuss a focusing wave field, which, when emitted into the medium from an open boundary, yields an isotropic virtual source and does not give rise to artefacts. We start the discussion from a horizontally layered medium and introduce the single‐sided focusing wave field in an intuitive way as an inverse filter. Next, we discuss single‐sided focusing in two‐dimensional and three‐dimensional inhomogeneous media and support the discussion with mathematical derivations. The focusing functions needed for single‐sided focusing can be retrieved from the single‐sided reflection response and an estimate of the direct arrivals between the focal point and the accessible boundary. The focal spot, obtained with this single‐sided data‐driven focusing method, acts as an isotropic virtual source, similar to that obtained by emitting a time‐reversed point‐source response from a closed boundary.