Petrologic provinces in Jurassic tholeiites of Gondwanaland

Application of discriminant function analysis to the Jurassic tholeiites of Gondwanaland allows delineation of three petrologic subprovinces. TiO₂ is the most important element in discrimination and a combination of TiO₂ and P₂O₅ was found to be the most suitable. Tholeiites in the foredeep of the Gondwanide fold belt are distinctly different in minor-element composition from those in zones of deep fracturing associated with the Nuanetsi rift-rift-rift triple junction in southern Africa. Intermediate basalt types are found in areas of regional tension not associated with rifted plate margins. The minor-element composition of tholeiites is dependant upon the depth (pressure) from which the magma was tapped and is closely related to prevailing regional tectonic environments.     

Importance of organic Fe complexing ligands in the Mississippi River plume

As part of a larger program focused on understanding the biogeochemistry of large river plumes, we participated in two expeditions during 2000 to sample the Mississippi River plume. Surface water samples were collected using a trace metal clean towed fish and analyzed for total dissolved Fe, organic Fe complexing ligands and their associated conditional stability constants. The ligands in the river plume have conditional stability constants (log K′_FeL between 10.5 and 12.3 with an average of 11.2 and standard deviation of 0.6) very similar to ligands found in the open ocean. Comparison of high flow and low flow regimes indicates that variability in flow may be the main cause of the variability in Fe concentrations in the plume. The organic Fe complexing ligands are in greatest excess during a time of higher flow. These ligands are responsible for maintaining very high (5 nM) Fe concentrations throughout the plume. Due to complexation with these organic ligands, the concentration of Fe remains above the Fe-hydroxide solubility level until a salinity above 35 is reached where there appears to be a sink for Fe in the less productive waters. Therefore, Fe is transported a great distance from the river source and is available for biological utilization in the coastal zone.     

Composite methodology for interpreting sediment transport pathways from spatial trends in grain size: A case study of the Lithuanian coast

To achieve a more robust interpretation of sediment conditions and transport based on grain size, this study combines the perspectives of two different interpretation techniques that have been developed separately and applied in the literature: (i) ‘grain size trend analysis’ interprets changes between interrelated sampling sites assuming that sediment in the direction of transport should become either coarser, better sorted and more positively skewed, or finer, better sorted and more negatively skewed; and (ii) the ‘population anomalies’ method, which estimates the balance between erosion and accumulation processes at each sampling site based on individual site deviations compared with average values for grain‐size parameters in the area of interest. The simultaneous use of both approaches enables sedimentological conditions and transport alternatives to be distinguished. This improvement is necessary because site‐specific changes and general textural trends provide information that complements the strengths and weaknesses of each perspective. The methods are implemented here using two‐dimensional Geographic Information System tools and illustrated for the Lithuanian coast. Grain‐size characteristics of 712 surface samples of sandy sediments are used to interpret sediment transport pathways and predominant sedimentological conditions in the Lithuanian coastal zone. In general, coast‐parallel sediment transport dominates the entire investigation area, although wave‐induced movement perpendicular to the coastline is inferred in the shallow nearshore zone. The deepest areas offshore are characterized by sea floor erosion in the north, whereas an accumulation zone occurs in the relatively deep central part of the study area.     

华南花岗岩暗色微粒包体的岩石化学组成特征及其意义

对华南诸多花岗岩体暗色微粒包体的野外调查表明, 非均一包体是包体中最普遍的类型,常具有暗色基性边.岩石化学分析结果表明,包体边缘的岩性为二长岩-石英二长岩-二长闪长岩,中心则为石英二长闪长岩-英云闪长岩.从包体中心到边缘,具有Si、Ca含量和Na/K比值降低,K、Al、Ti、P和Fe+Mg含量升高的变化趋势,揭示包体应...     

Ecological evaluation of an experimental beneficial use scheme for dredged sediment disposal in shallow tidal waters

An experiment was performed to test an alternative dredging strategy for the Westerschelde estuary. Clean sand dredged from the navigation channel was disposed seawards of an eroding intertidal flat in order to modify morphology and hydrodynamics, improving the multi-channel system with ecologically productive shallow water habitat. Five years of intensive monitoring revealed that part of the disposed sediment moved slowly towards the flat, increasing the very shallow subtidal and intertidal area, as planned. The sand in the impact zone became gradually finer after disposal, possibly due to reduced current velocities. Nevertheless, no changes in macrobenthic biomass, density, species richness and composition were detected in the subtidal zone, also demonstrating rapid macrobenthic recovery. In the intertidal zone, no ecological effects could be revealed superimposed on trends associated with long-term sediment fining. Thus, despite morphological success and absence of detected negative ecological impacts of the experiment, new beneficial habitat was not created.     

ROBUST: The ROle of BUffering capacities in STabilising coastal lagoon ecosystems

“Buffer capacities” has been defined in ecology as a holistic concept (e.g., Integration of Ecosystem Theories: A Pattern, second ed. Kluwer, Dordrecht, 1997, 388pp), but we show that it can also be worked out in mechanistic studies. Our mechanistic approach highlights that “buffering capacities” can be depleted progressively, and, therefore, we make a distinction between current and potential “buffering capacities”. We have applied this concept to understand the limited “local stability” in seagrass ecosystems and their vulnerability towards structural changes into macro-algal dominated communities. We explored the following processes and studied how they confer buffering capacities to the seagrass ecosystem: (i) net autotrophy is persistent in Zostera noltii meadows where plant assimilation acts as a sink for nutrients, this contrasted with the Ulva system that shifted back and forth between net autotrophy and net heterotrophy; (ii) the Z. noltii ecosystem possesses a certain albeit rather limited capacity to modify the balance between nitrogen fixation and denitrification, i.e., it was found that in situ nitrogen fixation always exceeded denitrification; (iii) the nitrogen demand of organoheterotrophic bacteria in the sediment results in nitrogen retention of N in the sediment and hence a buffer against release of nitrogen compounds from sediments, (iv) habitat diversification in seagrass meadows provides shelter for meiofauna and hence buffering against adverse conditions, (v) sedimentary iron provides a buffer against noxious sulfide (note: bacterial sulfide production is enhanced in anoxic sediment niches by increased organic matter loading). On the other hand, in the coastal system we studied, sedimentary iron appears less important as a redox-coupled buffer system against phosphate loading. This is because most inorganic phosphate is bound to calcium rather than to iron. In addition, our studies have highlighted the importance of plant–microbe interactions in the seagrass meadows.     

Microbial food web contributions to bottom water hypoxia in the northern Gulf of Mexico

Nutrients from the Mississippi/Atchafalaya Rivers greatly stimulate biological production in the ‘classical’ food web on the inner shelf of the northern Gulf of Mexico. Portions of this production, especially large diatoms and zooplankton fecal pellets, sink and decompose in the bottom water, consuming oxygen and contributing to the annual development of an extensive zone of bottom water hypoxia, typically >15,000 km² since 1993. The microbial food web is also active in the Mississippi River plume, but consists of small organisms that sink slowly. This ‘recycling’ food web has not been considered as a significant contributor to vertical flux and hypoxia. However, gelatinous zooplankton, especially pelagic appendicularians such as Oikopleura dioica, mediate the conversion of microbial web organisms to organic particles with high sinking rates. When pelagic appendicularians are abundant in coastal regions of the northern Gulf of Mexico, they stimulate the rapid vertical transfer of microbial web productivity in the surface layer, which is only 5–15 m thick in the coastal hypoxic region, to the sub-pycnocline layer that becomes hypoxic each summer. In this paper we present results from two studies examining the significance of this pathway. In both 2002 and 2004, we observed high production rates of appendicularians in coastal waters. Discarded gelatinous houses and fecal pellets from the appendicularian populations often provided more than 1 g m⁻² d⁻¹ of organic carbon for the establishment and maintenance of hypoxia in the northern Gulf of Mexico. This source of organic matter flux is especially important in regions far from the river plumes and during periods of low river discharge. Autotrophic elements of this food web are primarily supported by recycled inorganic nutrients originating in the Mississippi and Atchafalaya Rivers. Sources of dissolved organic matter (DOM) supporting the heterotrophic components of this microbial food web may include in situ production, the Mississippi/Atchafalaya Rivers, and Louisiana's coastal wetlands. If significant, the latter source provides a possible link between Louisiana's high rates of coastal land loss and the large hypoxic zone observed along the coast during summer. Both of the latter DOM sources are independent of phytoplankton production stimulated by inputs of riverine inorganic nutrients.     

Extragalactic integral field spectroscopy on the Gemini telescopes

We have been undertaking a programme on the Gemini 8‐m telescopes to demonstrate the power of integral field spectroscopy, using the optical GMOS spectrograph, and the new CIRPASS instrument in the near‐infrared. Here we present some preliminary results from 3D spectroscopy of extra‐galactic objects, mapping the emission lines in a 3CR radio galaxy and in a gravitationally lensed arc, exploring dark matter sub‐structure through observations of an Einstein Cross gravitational lens, and the star formation time‐scales of young massive clusters in the starburst galaxy NGC 1140. (© 2004 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Resolving the 180° Ambiguity in Solar Vector Magnetic Field Data: Evaluating the Effects of Noise,Spatial Resolution,and Method Assumptions

The objective testing of algorithms for performing ambiguity resolution in vector magnetic field data is continued, with an examination of the effects of noise in the data. Through the use of analytic magnetic field models, two types of noise are “added” prior to resolving: noise to simulate Poisson photon noise in the observed polarization spectra, and a spatial binning to simulate the effects of unresolved structure. The results are compared through the use of quantitative metrics and performance maps. We find that while no algorithm severely propagates the effects of Poisson noise beyond very local influences, some algorithms are more robust against high photon-noise levels than others. In the case of limited spatial resolution, loss of information regarding fine-scale structure can easily result in erroneous solutions. Our tests imply that photon noise and limited spatial resolution can act so as to make assumptions used in some ambiguity resolution algorithms no longer consistent with the observed magnetogram. We confirm a finding of the earlier comparison study that results can be very sensitive to the details of the treatment of the observed boundary and the assumptions governing that treatment. We discuss the implications of these findings, given the relative sensitivities of the algorithms to the two sources of noise tested here. We also touch on further implications for interpreting observational vector magnetic field data for general solar physics research.