Anisotropic mechanical properties of zircon and the effect of radiation damage

This study provides new insights into the relationship between radiation-dose-dependent structural damage due to natural U and Th impurities and the anisotropic mechanical properties (Poisson’s ratio, elastic modulus and hardness) of zircon. Natural zircon samples from Sri Lanka (see Muarakami et al. in Am Mineral 76:1510–1532, 1991) and synthetic samples, covering a dose range of zero up to 6.8 × 10¹⁸ α-decays/g, have been studied by nanoindentation. Measurements along the [100] crystallographic direction and calculations, based on elastic stiffness constants determined by Özkan (J Appl Phys 47:4772–4779, 1976), revealed a general radiation-induced decrease in stiffness (~54 %) and hardness (~48 %) and an increase in the Poisson’s ratio (~54 %) with increasing dose. Additional indentations on selected samples along the [001] allowed one to follow the amorphization process to the point that the mechanical properties are isotropic. This work shows that the radiation-dose-dependent changes of the mechanical properties of zircon can be directly correlated with the amorphous fraction as determined by previous investigations with local and global probes (Ríos et al. in J Phys Condens Matter 12:2401–2412, 2000a; Farnan and Salje in J Appl Phys 89:2084–2090, 2001; Zhang and Salje in J Phys Condens Matter 13:3057–3071, 2001). The excellent agreement, revealed by the different methods, indicates a large influence of structural and even local phenomena on the macroscopic mechanical properties. Therefore, this study indicates the importance of acquiring better knowledge about the mechanical long-term stability of radiation-damaged materials.     

Historical pollution trends in a disturbed, estuarine sedimentary environment, SW Sweden

The objective of this article is to determine whether pollution trends can be reconstructed from sediments in the outer Göta älv estuary. Detailed interpretation of heavy metal profiles in the recent sediment, in combination with profiles of ²¹⁰Pb- and ¹³⁷Cs-activity, organic carbon content and grain size distribution, allows estimation of historical trends. This is based on the assumption that only certain intervals, which can be identified, are disturbed. The sediment data are compared with archive data on historical trends in emissions of heavy metals. Special attention is given to mercury, which shows high enrichment over long periods of time. It is found that the most polluted sediments were deposited between 1930 and 1980, but that episodic discharges have also occurred more recently. Nevertheless, the effects of remediation since the 1970s are apparent.     

Application of discriminant function analysis to the felsic rocks of the Bushveld Complex,South Africa

The technique of multivariate analysis was used to investigate the geochemical relationships between the felsic rocks of the Bushveld Complex. The Bushveld granite and Rooiberg felsite form two distinct geochemical groups based on their major element compositions, possibly indicating that they originated from separate and genetically unrelated magmas. A discriminant function based on six major oxides was found to be 90 percent effective in distinguishing between the two groups. These conclusions have important implications for the petrogenesis of the Bushveld Complex.     

Broad search for unstable resonant orbits in the planar circular restricted three-body problem

Unstable resonant orbits in the circular restricted three-body problem have increasingly been used for trajectory design using optimization and invariant manifold techniques. In this study, several methods for computing these unstable resonant orbits are explored including grid searches, flyby maps, and continuation. Families of orbits are computed focusing on orbits with multiple loops near the secondary in the Jupiter–Europa system, and their characteristics are explored. Different parameters such as period and stability are examined for each set of resonant orbits, and the continuation of several specific orbits is explored in more detail.     

The use of invariant manifolds for transfers between unstable periodic orbits of different energies

Techniques from dynamical systems theory have been applied to the construction of transfers between unstable periodic orbits that have different energies. Invariant manifolds, trajectories that asymptotically depart or approach unstable periodic orbits, are used to connect the initial and final orbits. The transfer asymptotically departs the initial orbit on a trajectory contained within the initial orbit’s unstable manifold and later asymptotically approaches the final orbit on a trajectory contained within the stable manifold of the final orbit. The manifold trajectories are connected by the execution of impulsive maneuvers. Two-body parameters dictate the selection of the individual manifold trajectories used to construct efficient transfers. A bounding sphere centered on the secondary, with a radius less than the sphere of influence of the secondary, is used to study the manifold trajectories. A two-body parameter, κ, is computed within the bounding sphere, where the gravitational effects of the secondary dominate. The parameter κ is defined as the sum of two quantities: the difference in the normalized angular momentum vectors and eccentricity vectors between a point on the unstable manifold and a point on the stable manifold. It is numerically demonstrated that as the κ parameter decreases, the total cost to complete the transfer decreases. Preliminary results indicate that this method of constructing transfers produces a significant cost savings over methods that do not employ the use of invariant manifolds.     

Lightning-strike fusion of gabbro and formation of magnetite-bearing fulgurite, Cornone di Blumone, Adamello, Western Alps, Italy

The Adamello gabbro exposed on the summit of Cornone di Blumone, Western Alps, Italy, has been fused by lightning strikes to form magnetite-rich fulgurites produced by melting of magnetite, hornblende, calcic plagioclase and minor clinopyroxene. The composition of quench magnetite in the fulgurite is 44.4 Fe₃O₄; 27.5 MgFe₂O₄; 15.1 FeAl₂O₄; 7.9 Fe₂TiO₄; 2.5 Fe₂SiO₄; 1.9 CaFe₂O₄; 0.8 MnFe₂O₄ and is inferred to have crystallized from a low-Si, Fe-rich melt under high oxidation conditions of about 1 log unit below the log₁₀?O₂ of hematite–magnetite. The low Si, Fe-rich melt is considered to have been produced from fusion of magnetite + hornblende-rich areas of the host gabbro and/or possible separation of an immiscible high Fe₂O₃/FeO Fe-rich, low-Si melt from a more siliceous glass during superheating. Skeletal-dendritic morphologies of magnetite in the fulgurite indicate crystallization under conditions of extreme supercooling. Juxtaposition of areas exhibiting different growth habits and crystal sizes of magnetite may reflect compositionally different local melt domains and/or small differences in the delicate balance between nucleation and growth in domains that had slightly different, although ultrafast, cooling rates.     

Atmospheric tracer monitoring and surface plume development at the ZERT pilot test in Bozeman,Montana, USA

A controlled release of CO₂ was conducted at a field site in Bozeman, Montana, USA in July of 2008 in a multi-laboratory study of near surface transport and detection technologies. The development of a subsurface CO₂ plume near the middle packer section of the horizontal release was studied using soil-gas and surface flux measurements of CO₂. A perfluorocarbon tracer was added to the CO₂ released from this section of the horizontal well, and the development of atmospheric plumes of the tracer was studied under various meteorological conditions using horizontal and vertical grids of monitors containing sorbent material to collect the tracer. This study demonstrated the feasibility of using remote sensing for the ultra low level detection of atmospheric plumes of tracers as means to monitor the near surface leakage of sequestered CO₂.