Late Pleistocene outburst flooding from pluvial Lake Alvord into the Owyhee River, Oregon

At least one large, late Pleistocene flood traveled into the Owyhee River as a result of a rise and subsequent outburst from pluvial Lake Alvord in southeastern Oregon. Lake Alvord breached Big Sand Gap in its eastern rim after reaching an elevation of 1292 m, releasing 11.3 km³ of water into the adjacent Coyote Basin as it eroded the Big Sand Gap outlet channel to an elevation of about 1280 m. The outflow filled and then spilled out of Coyote Basin through two outlets at 1278 m and into Crooked Creek drainage, ultimately flowing into the Owyhee and Snake Rivers. Along Crooked Creek, the resulting flood eroded canyons, stripped bedrock surfaces, and deposited numerous boulder bars containing imbricated clasts up to 4.1 m in diameter, some of which are located over 30 m above the present-day channel.Critical depth calculations at Big Sand Gap show that maximum outflow from a 1292- to 1280-m drop in Lake Alvord was  10,000 m³ s^− 1. Flooding became confined to a single channel approximately 40 km downstream of Big Sand Gap, where step-backwater calculations show that a much larger peak discharge of 40,000 m³ s^− 1 is required to match the highest geologic evidence of the flood in this channel. This inconsistency can be explained by (1) a single 10,000 m³ s^− 1 flood that caused at least 13 m of vertical incision in the channel (hence enlarging the channel cross-section); (2) multiple floods of 10,000 m³ s^− 1 or less, each producing some incision of the channel; or (3) an earlier flood of 40,000 m³ s^− 1 creating the highest flood deposits and crossed drainage divides observed along Crooked Creek drainage, followed by a later 10,000 m³ s^− 1 flood associated with the most recent shorelines in Alvord and Coyote Basins.Well-developed shorelines of Lake Alvord at 1280 m and in Coyote Basin at 1278 m suggest that after the initial flood, postflood overflow persisted for an extended period, connecting Alvord and Coyote Basins with the Owyhee River of the Columbia River drainage. Surficial weathering characteristics and planktonic freshwater diatoms in Lake Alvord sediment stratigraphically below Mt. St. Helens set Sg tephra, suggest deep open-basin conditions at  13–14 ka (¹⁴C yr) and that the flood and prominent shorelines date to about this time. But geomorphic and sedimentological evidence also show that Alvord and Coyote Basins held older, higher-elevation lakes that may have released earlier floods down Crooked Creek.     

Seasonal variation of Mn adsorption on to calcareous surfaces in the English Channel, and its implication on the manganese distribution coefficient

Dissolved and particulate manganese in seawater samples derived from the English Channel has been analyzed using graphite furnace atomic absorption (GFAAS), and inductively coupled plasma atomic emission (ICP—AES) spectroscopies. Because of the high contents of carbonate minerals found in the suspended matter samples, the English Channel constitutes an ideal field area for the study of the Mn²⁺/Ca²⁺/CaCO₃ system. Owing to the chemical speciation of particulate manganese and the combined use of the X-ray diffraction and electron spin resonance spectroscopy we have shown the importance of the carbonate phase in the stabilization of manganese (II). This has been confirmed by p-pH measurements in the field. All these studies have also indicated that: (1) manganese is associated with calcite in the form of a solid solution, Mn_xCa_1−xCO₃; and (2) significant increases in the concentrations of particulate manganese, especially in offshore waters, occur in summer. This seasonal phenomenon has been attributed to the proliferation of coccolithophorids, which are known to be covered with calcified skeletons at high specific surface areas. To appraise the implication of the coccolithophorid-blooms phenomenon on the Mn²⁺/Ca²⁺/CaCO₃ system, we have used the manganese distribution coefficient, D_i, between the liquid phase and CaCO₃ particles. Overall we have shown that: (1) D_i in summer (i.e. when coccoliths considered as very fine-grained calcite are abundant) is much higher than that obtained in winter; and (2) in the vicinity of the French coast, D_i does not vary significantly even in summer. This is because of the high content of chalk-derived particles found in the near-shore waters.     

Concentration,composition and sources of PAHs in the coastal sediments of the exclusive economic zone (EEZ) of Qatar,Arabian Gulf

Surface sediments were collected from sixteen locations in order to assess levels and sources of polycyclic aromatic hydrocarbons (PAHs) in sediments of Qatar exclusive economic zone (EEZ). Samples were analyzed for 16 parent PAHs, 18 alkyl homologs and for dibenzothiophenes. Total PAHs concentration (∑PAHs) ranged from 2.6 ng g⁻¹ to 1025 ng g⁻¹. The highest PAHs concentrations were in sediments in and adjacent to harbors. Alkylated PAHs predominated most of the sampling locations reaching up to 80% in offshore locations. Parent PAHs and parent high molecular weight PAHs dominated location adjacent to industrial activities and urban areas. The origin of PAHs sources to the sediments was elucidated using ternary plot, indices, and molecular ratios of specific compounds such as (Ant/Phe + Ant), (Flt/Flt + Pyr). PAHs inputs to most coastal sites consisted of mixture of petroleum and combustion derived sources. However, inputs to the offshore sediments were mainly of petroleum origin.     

The Magma Feeding System of the Klyuchevskaya Group of Volcanoes (Kamchatka)

Doklady Earth Sciences - Using observations from a large-scale seismic station network, we built a seismic tomography model of velocity anomalies for longitudinal (P-wave) and transverse (S-wave)...     

Hydrodynamic and geochemical conditions of the formation of stratiform Zn-Pb ore mineralization by chloride solutions

Ore mineralization is formed by postsedimentary (concentrated by evaporation to stage SW2) chloride brines metamorphosed in hydrogeochemical systems that are closed with respect to CO₂, evolve according to “calcic” trend, and have high 2mCa²⁺ > mHCO ₃ ^? + 2mCO ₃ ^2? ratios. In these situations at high R/W ratios (10–100) and temperatures (100–200°C), these brines concentrate ore elements (Zn, Pb, Fe, and Mn) that are geochemical analogues of Ca. The sulfide precipitation of these elements occurs under the effect of carbonate rocks at the abiogenic sulfate reduction of S(VI) of the original brines at low Eh values, which are created in carbonate rocks at higher (>100°C) temperatures. This origin of sulfide mineralization is intensified at decreasing R/W ratios during the dilution of the original brines by elision waters and an increase in the temperature. The hydrodynamics of these ore-forming brines is controlled by the elision hydrogeological regime, which is defined in hydrogeological structures by the geostatic pressure. The brines migrate into the zones of geochemical barriers during the relaxation of hydrogeological structures toward their equilibrium hydrostatic state. Hydrogeological structures, optimal for the precipitation of ore mineralization, are hydrodynamically active and able to maintain a steady (during 10⁵-10⁶ years) inflow of ore-forming brines into the zones of geochemical barriers and the maximum number of water-exchange cycles at these barriers. Modern analogues of these structures are miogeosyncline foredeeps with Cl-Na-Ca chloride brines with high concentrations of ore elements and overall flow rates ranging from 0.n to n m³/year. Stagnate hydrogeological platform structures in hydrostatic equilibrium cannot ensure water exchange needed for ore formation, and, hence, the brines of these structures are not able to deposit the ore elements contained in them, in spite of the high concentrations of these elements.     

Geological setting and chemistry of kimberlite clan rocks in the Dharwar Craton, India

Diamond exploration in India over the past decade has led to the discovery of over 80 kimberlite-inferred and lamproite-related intrusions in three of the four major Archean cratons that dominate the subcontinent. These intrusions are Proterozoic (1.1 Ga), and are structurally controlled: locally (at the intersections of faults); regionally (in a 200 km wide, 1000 km long diamond corridor); and globally (in the reconstructed supercontinent of Rodinia). The geochemistry of 57 samples from 13 intrusions in the southern Dharwar Craton of Andhra Pradesh has been determined by XRF spectrometry. The bodies are iron-rich with mg#=50–70 and are neither archetypal kimberlites nor ideal lamproites; this may be the underlying reason that conventional exploration techniques have thus far failed to locate the primary sources of India's historically famous diamonds. The two major fields of kimberlite-clan rocks (KCR) in the Dharwar Craton, Wajrakur and Narayanpet, are separated by a NW–SE trending, transcontinental (Mumbai-Chennai) gravity lineament. About 80% of intrusions in Wajrakur are diamondiferous, but diamonds have not yet been reported in Narayanpet. The gravity anomaly may mark the boundary of an architectural modification in the keel of the sub-continental lithosphere, a suggestion that is supported by differences in kimberlite mineralogy, chemistry, mantle xenoliths, structural setting and crustal host rocks.     

Particle Acceleration in Reconnecting Current Sheets in Impulsive Electron-Rich Solar Flares

Electron and proton acceleration in reconnecting current sheets in electron-rich solar flares is considered. A significant three-dimensional magnetic field is assumed in the current sheet where the particles are accelerated by the DC electric field. The tearing instability of a pre-flare current sheet leads to the formation of multiple singular lines of magnetic field where the electric and magnetic fields are coaligned. Magnetized electrons are shown to be accelerated to a few tens of MeV before they leave the vicinity of a singular line. The acceleration time is estimated to be less than 10^–3 s. By contrast, much heavier protons are unmagnetized and their energy gain is more modest. The model explains a high electron-to-proton ratio and the unusually intense gamma-ray continuum above 1 MeV observed in the electron-rich flares.     

Modelling phytoplankton succession on the Bering Sea shelf: role of climate influences and trophic interactions in generating Emiliania huxleyi blooms 1997–2000

Several years of continuous physical and biological anomalies have been affecting the Bering Sea shelf ecosystem starting from 1997. Such anomalies reached their peak in a striking visual phenomenon: the first appearance in the area of bright waters caused by massive blooms of the coccolithophore Emiliania huxleyi (E. huxleyi). This study is intended to provide an insight into the mechanisms of phytoplankton succession in the south-eastern part of the shelf during such years and addresses the causes of E. huxleyi success by means of a 2-layer ecosystem model, field data and satellite-derived information. A number of potential hypotheses are delineated based on observations conducted in the area and on previous knowledge of E. huxleyi general ecology. Some of these hypotheses are then considered as causative factors and explored with the model. The unusual climatic conditions of 1997 resulted most notably in a particularly shallow mixed layer depth and high sea surface temperature (about 4 °C above climatological mean). Despite the fact that the model could not reproduce for E. huxleyi a clear non-bloom to bloom transition (pre- vs. post-1997), several tests suggest that this species was favoured by the shallow mixed layer depth in conjunction with a lack of photoinhibition. A top-down control by microzooplankton selectively grazing phytoplankton other than E. huxleyi appears to be responsible for the long persistence of the blooms. Interestingly, observations reveal that the high N:P ratio hypothesis, regarded as crucial in the formation of blooms of this species in previous studies, does not hold on the Bering Sea shelf.     

Metamorphic evolution of the Maud Belt: P–T–t path for high-grade gneisses in Gjelsvikfjella, Dronning Maud Land, East Antarctica

A metamorphic petrological study, in conjunction with recent precise geochronometric data, revealed a complex P–T–t path for high-grade gneisses in a hitherto poorly understood sector of the Mesoproterozoic Maud Belt in East Antarctica. The Maud Belt is an extensive high-grade, polydeformed, metamorphic belt, which records two significant tectono-thermal episodes, once towards the end of the Mesoproterozoic and again towards the late Neoproterozoic/Cambrian. In contrast to previous models, most of the metamorphic mineral assemblages are related to a Pan-African tectono-thermal overprint, with only very few relics of late Mesoproterozoic granulite-facies mineral assemblages (M₁) left in strain-protected domains. Petrological and mineral chemical evidence indicates a clockwise P–T–t path for the Pan-African orogeny. Peak metamorphic (M_2b) conditions recorded by most rocks in the area (T = 709–785 °C and P = 7.0–9.5 kbar) during the Pan-African orogeny were attained subsequent to decompression from probably eclogite-facies metamorphic conditions (M_2a).The new data acquired in this study, together with recent geochronological and geochemical data, permit the development of a geodynamic model for the Maud Belt that involves volcanic arc formation during the late Mesoproterozoic followed by extension at 1100 Ma and subsequent high-grade tectono-thermal reworking once during continent–continent collision at the end of the Mesoproterozoic (M₁; 1090–1030 Ma) and again during the Pan-African orogeny (M_2a, M_2b) between 565 and 530 Ma. Post-peak metamorphic K-metasomatism under amphibolite-facies conditions (M_2c) followed and is ascribed to post-orogenic bimodal magmatism between 500 and 480 Ma.