Ostracode stratigraphy and paleoecology from surficial sediments of Lake Tanganyika, Africa

We report here on the first detailed ostracode stratigraphic record to be obtained from late Holocene sediments of Lake Tanganyika. We analyzed four cores, three from the northern lake region and a fourth from a more southern lake locality, that collectively record ostracode assemblages under a variety of disturbance regimes. These cores provide a stratigraphic record of ostracode abundance and diversity, as well as depositional changes over time periods of decades to millennia. We have investigated the fossil ostracodes in these cores by looking at temporal changes of species diversity and population structure for the species present. All four cores provided distinct patterns of ostracode diversity and abundance. BUR-1, a northern lake core obtained close to the Ruisizi River delta, yielded a sparse ostracode record. Karonge #3, another northern core from a site that is closely adjacent to a river delta with high sediment loading, yielded almost no ostracodes. The third core 86-DG-14, taken from a somewhat less disturbed area of the lake, suggests that there have been recent changes in ostracode populations. Through most of the lower portion of this core, ostracode abundance is low and species richness is relatively constant. Above 7 cm there is a marked increase in ostracode abundance and a corresponding decrease in species richness, probably signaling the onset of a major community disturbance, perhaps due to human activities. The southernmost core, 86-DG-32, is from a site that is well removed from influent rivers. Ostracode abundance varies erratically throughout the core, whereas species richness is relatively constant and high throughout the core. The temporal variation evident in ostracode community makeup both within and between the studied cores may be a result of naturally patchy distributions among ostracodes, coupled with local extinctions and recolonizations, or it may reflect inadequate sampling of these high diversity assemblages. In either case, these cores illustrate the potential to obtain high resolution ostracode records from the rich, endemic fauna of Lake Tanganyika that can be used to address questions about the history of community structure and human impacts in this lake.     

Sediment‐rich meltwater plumes and ice‐proximal fans at the margins of modern and ancient tidewater glaciers: Observations and modelling

Turbid meltwater plumes and ice‐proximal fans occur where subglacial streams reach the grounded marine margins of modern and ancient tidewater glaciers. However, the spacing and temporal stability of these subglacial channels is poorly understood. This has significant implications for understanding the geometry and distribution of Quaternary and ancient ice‐proximal fans that can form important aquifers and hydrocarbon reservoirs. Remote‐sensing and numerical‐modelling techniques are applied to the 200 km long marine margin of a Svalbard ice cap, Austfonna, to quantify turbid meltwater‐plume distribution and predict its temporal stability. Results are combined with observations from geophysical data close to the modern ice front to refine existing depositional models for ice‐proximal fans. Plumes are spaced ca 3 km apart and their distribution along the ice front is stable over decades. Numerical modelling also predicts the drainage pattern and meltwater discharge beneath the ice cap; modelled water‐routing patterns are in reasonable agreement with satellite‐mapped plume locations. However, glacial retreat of several kilometres over the past 40 years has limited build‐up of significant ice‐proximal fans. A single fan and moraine ridge is noted from marine‐geophysical surveys. Closer to the ice front there are smaller recessional moraines and polygonal sediment lobes but no identifiable fans. Schematic models of ice‐proximal deposits represent varying glacier‐terminus stability: (i) stable terminus where meltwater sedimentation produces an ice‐proximal fan; (ii) quasi‐stable terminus, where glacier readvance pushes or thrusts up ice‐proximal deposits into a morainal bank; and (iii) retreating terminus, with short still‐stands, allowing only small sediment lobes to build up at melt‐stream portals. These modern investigations are complemented with outcrop and subsurface observations and numerical modelling of an ancient, Ordovician glacial system. Thick turbidite successions and large fans in the Late Ordovician suggest either high‐magnitude events or sustained high discharge, consistent with a relatively mild palaeo‐glacial setting for the former North African ice sheet.     

Renewable energy from the ocean

Growing concern over the threat of global climate change has led to an increased interest in research and development of renewable energy technologies. The ocean provides a vast source of potential energy resources, and as renewable energy technology develops, investment in ocean energy is likely to grow. Research in ocean thermal energy conversion, wave energy, tidal energy, and offshore wind energy has led to promising technologies and in some cases, commercial deployment. These sources have the potential to help alleviate the global climate change threat, but the ocean environment should be protected while these technologies are developed. Renewable energy sources from the ocean may be exploited without harming the marine environment if projects are sited and scaled appropriately and environmental guidelines are followed.     

The effects of nitric oxide cooling and the photodissociation of molecular oxygen on the thermosphere/ionosphere system over the Argentine Islands

In the past the global, fully coupled, time-dependent mathematical model of the Earths thermo-sphere/ionosphere/plasmasphere (CTIP) has been unable to reproduce accurately observed values of the maximum plasma frequency, foF2, at extreme geophysical locations such as the Argentine Islands during the summer solstice where the ionosphere remains in sunlight throughout the day. This is probably because the seasonal dependence of thermospheric cooling by 5.3 m nitric oxide has been neglected and the photodissociation of O₂ and heating rate calculations have been over-simplified. Now we have included an up-to-date calculation of the solar EUV and UV thermospheric heating rate, coupled with a new calculation of a diurnally varying O₂ photodissociation rate, in the model. Seasonally dependent 5.3 m nitric oxide cooling is also included. With these important improvements, it is found that model values of foF2 are in substantially better agreement with observation. The height of the F2-peak is reduced throughout the day, but remains within acceptable limits of values derived from observation, except at around 0600 h LT. We also carry out two studies of the sensitivity of the upper atmosphere to changes in the magnitude of nitric oxide cooling and photodissociation rates. We find that hmF2 increases with increased heating, whilst foF2 falls. The converse is true for an increase in the cooling rate. Similarly increasing the photodissociation rate increases both hmF2 and foF2. These changes are explained in terms of changes in the neutral temperature, composition and neutral wind.     

Measurement of vertical distribution of isoprene in surface seawater, its chemical fate, and its emission from several phytoplankton monocultures

Concurrent measurements of isoprene (2-methyl-1,3-butadiene) in seawater together with atmospheric concentrations in the Gulf Stream off the Florida coast were made. Florida Straits surface water concentrations of isoprene varied between 9.8 and 50.8 pmol 1⁻¹. Surface water isoprene concentrations showed a positive correlation with measured chlorophyll fluorescence, consistent with the biogenic origin of this non-methane hydrocarbon. Depth profiles showed a maximum in isoprene concentration similar to that of biological productivity as indicated by chlorophyll fluorescence. Daytime atmospheric mixing ratios of isoprene were never above 11 parts-per-trillion (pptv) and eight of eleven samples taken were below the ˜ 5 pptv detection limit. Using an estimated value of the Henry's law constant (K_H ˜ 3.1) a supersaturation of surface seawater of 2 to 3 orders of magnitude is estimated.Laboratory grown monocultures of several common phytoplankton species showed production of isoprene. Processes controlling the isoprene concentration in the photic zone of the ocean and the marine boundary layer are discussed. A calculation using a simple time dependent photochemical box model confirmed that isoprene is rapidly consumed by its reaction with the OH radical in the marine atmosphere.     

Sources of sediment to the Neuse River estuary, North Carolina

The Neuse River estuary is part of the large Albemarle/Pamlico estuarine/lagoonal system (APES) of North Carolina. Exchange between the APES and the open ocean is restricted to inlets in the Outer Banks barrier islands. Freshwater discharge of the Neuse River is low in relation to the size of its estuary, so that the estuary is normally brackish over most of the area which accumulates fine-grained sediments. Mud (silt + clay) accumulation rates are low ( 6 mm year⁻¹).From the mud distribution and the dynamics of suspended sediment in the estuary it has been inferred that the Neuse retains fines efficiently, with probable episodic (high discharge) losses seaward, to Pamlico Sound.As part of a study of particle transport, deposition, and accumulation in the Neuse estuary, we have collected radiochemical data (10 cores) and chemical data (seven cores) on sediment cores from the main channel of the estuary between New Bern, North Carolina and the estuary mouth. K/Al increases in the lower estuary, consistent with earlier reports of increasing illite in the clay fraction. Landward transport of sediment from Pamlico Sound is the most plausible explanation for the increasing K/Al (illite). A marine sediment source may, therefore, be important for the lower estuary.The distribution of sediment inventories (quantities per cm² of sediment column) of particle-reactive radionuclides is consistent with the hypothesis of landward sediment transport. Inventories of excess ²¹⁰Pb, ¹³⁷Cs, and ^239,240Pu are coherent through the estuary and show the effects of particle redistribution processes on regionally uniform inputs. To obtain excess (anthropogenic) Zn and Cu, we use metal/Al normalization to estimate natural backgrounds. Anthropogenic metal inputs are concentrated at the head of the estuary, and sediment inventories of excess Zn and Cu generally decrease seaward. Normalization of the excess Zn and excess Cu inventories to excess ²¹⁰Pb inventories corrects the raw metal inventories for effects of lithology and sediment redistribution. The normalized excess Zn inventory decreases smoothly seaward, while the normalized excess Cu inventory shows an unexplained mid-estuary maximum. Low normalized inventories of anthropogenic metals at the estuary mouth indicate that little modern riverine sediment is stored there.Increasing K/Al (illite) and decreasing anthropogenic Zn and Cu in the lower estuary are thus both consistent with a predominantly marine sediment source. We conclude that landward transport of muds from Pamlico Sound has contributed significantly to the sediment balance of the lower Neuse estuary.     

Variations in the chemical lability of iron in estuarine, coastal and shelf waters and its implications for phytoplankton

The relationship between total and chemically labile Fe has been studied in estuarine, coastal and shelf waters of the Gulf of Maine, U.S.A. Measurements of the labile fraction of total Fe, defined by complexation with 8-hydroxyquinoline in 1 h, correlate with the availability of Fe to marine phytoplankton and therefore can be used to estimate Fe availability in seawater. The results show that the relative lability (=labile/total) of Fe in seawater varied both spatially and temporally from near-zero to 100%. Although particulate Fe (>0.45 μm) was generally less labile than dissolved Fe (<0.45 μm), the particulate fraction often contributed substantially to labile Fe concentrations overall. Conversely, as much as 75% of ‘dissolved’ Fe was non-labile, and therefore was probably not available to phytoplankton. In seawater/river-water mixing experiments, aggregation diminished the relative lability of Fe by 30%, even though much of it remained in the ‘dissolved’ fraction. Considering phytoplankton nutrition, these results demonstrate that equating dissolved Fe concentrations with ‘available’ metal can be misleading. Furthermore, the large variability observed in the labile proportion of total Fe in seawater indicates that Fe availability to phytoplankton cannot be estimated by applying fixed lability-ratios to total Fe concentrations.