Relative oxidation states of magmas inferred from Ce(IV)/Ce(III) in zircon: application to porphyry copper deposits of northern Chile

Major- and trace-element compositions of zircons and whole rocks from 14 barren and seven ore-bearing calc-alkaline intrusions from the Chuquicamata-El Abra porphyry copper belt of northern Chile have been measured in situ by excimer laser ablation (ELA) ICP-MS. These data permit the Ce(IV)/Ce(III) ratio within zircon to be calculated using a lattice-strain model for mineral-melt partitioning of Ce(IV) and Ce(III). Zircon Ce(IV)/Ce(III) and Eu_N/Eu_N* ratios, and by inference magmatic oxidation states, generally increase from older, mafic to younger, felsic units. Within this sequence, porphyry copper mineralization is directly associated only with intrusions with zircon Ce(IV)/Ce(III)>300 and Eu_N/Eu_N*>0.4. Such trends can be understood in terms of interdependent relations between oxygen fugacity, sulfur speciation and solubility, and chalcophile element partitioning in silicate magmas. Because zircon occurs in most calc-alkaline intrusions and is resistant to subsolidus alteration, zircon Ce(IV)/Ce(III) ratios provide a useful tool for evaluating the economic potential of such rocks for magmatic-hydrothermal Cu-Au mineralization. The approach is general and may provide a means to infer relative oxidation state in a wide range of intermediate to felsic igneous rocks.     

Robust multivariate procedures applied to the interpretation of atypical individuals of a Cretaceous foraminifer

Robust multivariate statistical methods are applied to samples of the Cretaceous bolivinid foraminifer Afrobolivina afra, in which individuals from microspheric and megalospheric generations dominate, but which also contain some pseudo-megalospheric specimens. Pseudo-megalospheric tests may cause values which are atypical in the statistical sense but which are fully normal biologically. Other atypical values derive from crushed specimens, microspheric individuals and unusual normal megalospheres with exceptionally wide shells and pointed last chambers. A wrongly punched specimen was also found by the procedure. The method employed here consists of plotting the generalized statistical distances calculated from robust estimates of means and of covariances against the quantiles of a Gaussian distribution; the presence of an atypical observation(s) is readily exposed by its departure from the main trend of the plot.     

Isotopic and textural discrimination between hypogene,ancient supergene,and modern sulfates at the Questa mine,New Mexico

Chemical and mineralogical changes due to pyrite weathering are of interest with respect to understanding long-term physical stability of mine rock piles at the Questa mine, New Mexico. The ability to discriminate between ancient and modern processes is important for establishing the extent of modern weathering within the piles. Initial inventories of sulfur minerals and representative isotope compositions in rocks from orebodies, the hydrothermal alteration zones associated with orebodies, hydrothermal alteration scars, and mine rock piles were determined. Ore body sulfides have δ³⁴S_CDT of 0 ± 4‰, typical for sulfides formed by magmatic processes in stockwork Mo systems. Pyrite from alteration scars has a wide range of δ³⁴S values from 0.0‰ to −13.6‰. Sulfate from the ore body has markedly positive δ³⁴S (5–10‰) accompanied by positive δ¹⁸OSO₄${\delta }^{18}{\text{O}}_{{\text{SO}}_4}$ values (6–15‰) reflecting equilibrium formation from magmatic fluids. Sulfates from alteration scars have δ³⁴S values over a broad range, similar to alteration scar pyrites, from −10.6‰ to 0‰ and δ¹⁸OSO₄${\delta }^{18}{\text{O}}_{{\text{SO}}_4}$ of 0 ± 3‰. Sulfates with fine grained, delicate, and euhedral mineral habits suggesting recent formation within the mine rock piles, have δ³⁴S values similar to orebody pyrite and alteration scars but more negative δ¹⁸OSO₄${\delta }^{18}{\text{O}}_{{\text{SO}}_4}$ values (−3‰ to −10‰). Sulfates from all three sources occur in these piles, and their stable isotope values have proven useful in differentiating them and their environments of formation (i.e., hypogene, ancient supergene, and recent weathering). Correlating the isotopic compositions with textures allows petrographic assessment for the origins of sulfate minerals in the rock piles, but this must be applied with caution because some sulfate mineral recycling has occurred.     

Anisotropic elastic full‐waveform inversion of walkaway vertical seismic profiling data from the Arabian Gulf

Borehole seismic addresses the need for high‐resolution images and elastic parameters of the subsurface. Full‐waveform inversion of vertical seismic profile data is a promising technology with the potential to recover quantitative information about elastic properties of the medium. Full‐waveform inversion has the capability to process the entire wavefield and to address the wave propagation effects contained in the borehole data—multi‐component measurements; anisotropic effects; compressional and shear waves; and transmitted, converted, and reflected waves and multiples. Full‐waveform inversion, therefore, has the potential to provide a more accurate result compared with conventional processing methods. We present a feasibility study with results of the application of high‐frequency (up to 60 Hz) anisotropic elastic full‐waveform inversion to a walkaway vertical seismic profile data from the Arabian Gulf. Full‐waveform inversion has reproduced the majority of the wave events and recovered a geologically plausible layered model with physically meaningful values of the medium.     

Recent history provides sustainable African water quality project insight

Small-scale projects to provide clean drinking water undertaken in the developing world can contribute to significantly improving the livelihood of rural communities. There has been a historical tendency to poorly plan such projects leading to an unsustainable future. Recent history indicates three simple steps to ensuring successful and enduring clean water projects. First, identification of need by the indigenous community provides ownership in the project. Second, a partnership between key individuals in the indigenous community with the donor provides for ambassadors on both sides of the project. Finally, an exit strategy by the donors for the indigenous communities ensures local sustainability for the future. The study site is the village of Geisha in northern Malawi, Africa. Sustainable implementation approaches are discussed in this case study as well as the various lessons learned. Improved project processes ensure sustainable small-scale water quality projects by donor organizations in developing countries.     

Turbidite deposition and the development of canyons through time on an intermittently glaciated continental margin: The Bonanza Canyon system,offshore eastern Canada

Bonanza Canyon is a complex canyon system on the slope from the intermittently glaciated Grand Bank on the south side of Orphan Basin. A 3D seismic reflection volume, 2D high-resolution seismic reflection profiles and ten piston cores were acquired to study the evolution of this canyon system in relation to glacial processes on the continental shelf and the effects of different types of turbidity currents on the development of deep water channels. Mapped reflector surfaces from the 3D seismic volume show that the Bonanza Canyons developed in a depression created by a large submarine slide of middle Pleistocene age, coincident with the onset of glacigenic debris flows entering western Orphan Basin. Two 3–5 km wide, flat-floored channels were cut into the resulting mass-transport deposit and resemble catastrophic glacial meltwater channels elsewhere on the margin. Both channels subsequently aggraded. The eastern channel A became narrower but maintained a sandy channel floor. The western channel, B, heads at a spur on the continental slope and appears to have been rather passively draped by muds and minor sands that have built 1500-m wave length sediment waves.Muddy turbidites recorded by piston cores in the channel and on the inter-channel ridges are restricted to marine isotope stage (MIS) 2 and were deposited from thick, sheet-like, and sluggish turbidity current derived from western Orphan Basin that resulted in aggradation of the channels and inter-channel ridges. Sandy turbidites in channels and on inner levees were deposited throughout MIS 2–3 and were restricted to the channels, locally causing erosion. Some coincide with Heinrich events. Channels with well-developed distributaries on the upper slope more readily trap the sediments on Grand Bank to form sandy turbidity currents. Channel B dominated by muddy turbidity currents has wide and relatively smooth floor whereas channel A dominated by sandy turbidity currents has a sharp geometry.     

Glaciation of a mixed-phase boundary layer cloud at a coastal arctic site as depicted in continuous lidar measurements

The dynamic seeding and glaciation of a mixed-phase cloud by ice crystals injected from above at Ny Ålesund, Svalbard, Norway is described using continuous lidar measurements and thermodynamic data. Glaciation of this cloud was caused by ice crystal growth and sedimentation due to the preferential differences in saturation vapor pressure over ice versus liquid water and riming. The lidar data suggest that precipitation reached the ground for nearly 4 h as a result. The symbiosis between ice and liquid water hydrometeor presence in the polar troposphere is unique. Thermal perturbations and airmass fluctuations influence microphysical cloud characteristics and radiative balance, which makes the otherwise pristine region sensitive to lower-latitude anthropogenic and biogenic influences and a focal point for observing indirect effects and their influence on climate change. The development of lidar technologies capable of continuous and autonomous measurements is yielding important datasets to study unique atmospheric phenomena.     

Distributed velocity method of solving the convective-dispersion equation: 1. Introduction,mathematical theory,and numerical implementation

This is the first part of a two-part paper presenting a new method for treating convective-dispersive transport. The motivation for developing this technique arises from the demands of performing a risk assessment for a nuclear waste repository. These demands include computational efficiency over a relatively large range of Peclet numbers, the ability to handle chains of decaying radionuclides with rather extreme contrasts in both solution velocities and half lives, and the ability to treat leach- or solubility-limited sources. To the extent it has been tested to date, the distributed velocity method (DVM) appears to satisfy these demands. This part contains an overall introduction and presents the mathematical theory, numerical implementation, and example results.