Thermal DNAPL Source Zone Treatment Impact on a CVOC Plume

The tetrachloroethene (PCE) source zone at a site in Endicott, New York had caused a dissolved PCE plume. This plume was commingled with a petroleum hydrocarbon plume from an upgradient source of fuel oil. The plume required a system for hydraulic containment, using extraction wells located about 360 m downgradient of the source. The source area was remediated using in situ thermal desorption (ISTD). Approximately 1406 kilograms (kg) of PCE was removed in addition to 4082 kg of commingled petroleum‐related compounds. The ISTD treatment reduced the PCE mass discharge into the plume from an estimated 57 kg/year to 0.07 kg/year, essentially removing the source term. In the 5 years following the completion of the thermal treatment in early 2010, the PCE plume has collapsed, and the concentration of degradation products in the PCE‐series plume area has declined by two to three orders of magnitude. Anaerobic dechlorination is the suspected dominant mechanism, assisted by the presence of a fuel oil smear zone and a petroleum hydrocarbon plume from a separate source area upgradient of the PCE source. Based on the post‐thermal treatment groundwater monitoring data, the hydraulic containment system was reduced in 2014 and discontinued in early 2015.     

A governance perspective on the large marine ecosystem approach

The large marine ecosystem (LME) concept and approach has had a global impact on marine ecosystem-based management. The LME approach provides a framework for assessing and monitoring LMEs and is based on five modules: productivity, fish and fisheries, pollution and ecosystem health, socioeconomics, and governance. It appears that the LME approach is also being used to structure interventions to bring about change. Its appropriateness for the latter purpose is questioned. The major concerns are that the LME approach is not consistent with current thinking about enabling governance and its compartmentalized structure does not facilitate effective governance intervention. Current thinking on good governance suggests that it is more appropriate to approach governance interventions at the LME scale through multi-level governance policy cycles.     

Partial melting and recrystallization of Archeaan komatiites by residual heat from rapidly accumulated flows

Spinifex-textured komatiites at Honeymoon Well, Western Australia, show evidence of partial melting and recrystallization of original igneous textures. Their textures and mineral compositions differ markedly from those typical of komatiites. Spinifex olivine plates are bent and broken, while interstitial space between spinifex and cumulus olivine is occupied by polygonal aggregates of clinopyroxene, orthopyroxene, minor olivine and plagioclase. Similar granular pyroxene-plagioclase aggregates occur as diffuse veins cutting spinifex zones and cumulate zones of the flows and, in places, form the matrix to a breccia containing corroded fragments of spinifex rock. Thermometry based on the two pyroxene assemblages yields temperatures of 1055° to 1141° C, just below the low-pressure komatiite solidus. Mineral compositions are different from those of typical komatiites: clinopyroxenes are Al-poor and Cr-rich, olivines are unusually iron-rich and depleted in Cr and Ca, and the low-Ca pyroxene is bronzite rather than the more typical pigeonite. We interpret these observations as the results of thermal metamorphism, partial remelting and subsequent slow crystallization of originally normal spinifex-textured komatiite flows. The rocks in question occupy a 40–70 m interval sandwiched between two olivine-rich units: an underlying 90 m-thick olivine adcumulate layer, forming part of the cumulate zone of a basal 160 m-thick flow, and an overlying 1 km-thick extrusive body composed mostly of olivine mesocumulate and adcumulate and capped in turn by spinifex-textured flows. Thermal modelling shows that a sinusoidal temperature profile of cool flow tops and hot flow centres would exist within this sequence shortly after eruption. Conductive thermal relaxation of this profile could reheat spinifex zones to the extent of inducing partial melting and textural reconstitution. Such reheating is largely dependent on the time interval between the emplacement of successive flows. Calculations suggest that at Honeymoon Well the emplacement interval must have been of the order of 10 years or less. Textural reconstitution may have contributed to the development of the thick orthocumulate sequences characteristic of komatiites in the Agnew-Wiluna belt. Present address: Geochemex Australia, P.O. Box 281, West Perth, 6005, Western Australia     

Modelling China’s potential maize production at regional scale under climate change

With the continuing warming due to greenhouse gases concentration, it is important to examine the potential impacts on regional crop production spatially and temporally. We assessed China’s potential maize production at 50 × 50 km grid scale under climate change scenarios using modelling approach. Two climate changes scenarios (A2 and B2) and three time slices (2011–2040, 2041–2070, 2071–2100) produced by the PRECIS Regional Climate Model were used. Rain-fed and irrigated maize yields were simulated with the CERES-Maize model, with present optimum management practices. The model was run for 30 years of baseline climate and three time slices for the two climate change scenarios, without and with simulation of direct CO₂ fertilization effects. Crop simulation results under climate change scenarios varied considerably between regions and years. Without the CO₂ fertilization effect, China’s maize production was predicted to suffer a negative effect under both A2 and B2 scenarios for all time slices, with greatest production decreases in today’s major maize planting areas. When the CO₂ fertilization effect is taken into account, production was predicted to increase for rain-fed maize but decrease for irrigated maize, under both A2 and B2 scenarios for most time periods.     

A new approach to geobarometry by combining fluid inclusion and clumped isotope thermometry in hydrothermal carbonates

This study presents a new approach to geobarometry by combining fluid inclusion and clumped isotope (Δ₄₇) thermometry on carbonate minerals. The offset between homogenisation temperatures of primary fluid inclusions with known composition and Δ₄₇ temperatures of the host mineral allows a direct estimation of the fluid pressure at the time of carbonate crystallisation. This new approach is illustrated via hydrothermal dolomite samples from the Variscan foreland fold‐and‐thrust belt in northern Spain. Clumped isotope analyses yield crystallisation temperatures (107–168°C) which are higher than homogenisation temperatures in corresponding samples (95–145°C). The calculated pressure values suggest that dolomitizing fluids were overpressured during formation of zebra dolomite textures, whereas lower pressures are obtained for dolomite cement from breccia textures. This new approach to geobarometry opens up the possibility of estimating the pressure of carbonate crystallisation and has potential applications in diagenesis, basin analysis, ore geology and tectonics.     

The queen conch fishery on Pedro Bank, Jamaica: discovery, development, management

The history, methods, problems and regulation of fishing of the last remaining large queen conch resource in the world, located on a Jamaican fishing bank, are examined. The fishery activities for the queen conch, Strombus gigas Linnaeus are briefly described with the main activities in the industrial sector which produce the bulk of the harvest, which is exported. There are a few large producers harvesting the single major fishing ground of Pedro Bank, southwest of Kingston. These fishers harvested at least 1500 t annually between 1992 and 1998. Management is by licensing, individual quotas and a close season from July to October. Regulations related to CITES are thought to greatly assist in making licensed harvesters provide catch data to the Fisheries Division. The industrial operators have provided funding to undertake stock assessment studies in 1994 and again in 1997. We highlight the focus on management on a participatory consensual approach with meetings with all players in the industry. The conch fishery is thought to be one of the few areas of the Jamaica fishery where there is close and successful collaboration between fishers and the Fisheries Division. It provides an example of how rapid, precautionary, participatory action can provide an adequate basis for management until more definitive scientific information becomes available. The status of the conch fishery is thought to be sustainable at present, once reductions are made to the annual quota.     

Linking uplift,erosion, and sedimentation using landscape evolution models: Madagascar since the Late Cretaceous

We present a study to estimate the large-scale landscape history of a continental margin, by establishing a source-to-sink volume balance between the eroding onshore areas and the offshore basins. Assuming erosion as the primary process for sediment production, we strive to constrain a numerical model of landscape evolution that balances the volumes of eroded materials from the continent and that deposited in the corresponding basins, with a ratio imposed for loss of erosion products. We use this approach to investigate the landscape history of Madagascar since the Late Cretaceous. The uplift history prescribed in the model is inferred from elevations of planation surfaces formed at various ages. By fitting the volumes of terrigenous sediments in the Morondava Basin along the west coast and the current elevation of the island, the landscape evolution model is optimized by constraining the erosion law parameters and ratios of sediment loss. The results include a best-fit landscape evolution model, which features two major periods of uplift and erosion during the Late Cretaceous and the middle to late Cenozoic. The model supports suggestions from previous studies that most of the high topography of the island was constructed since the middle to late Miocene, and on the central plateau the erosion has not reached an equilibrium with the high uplift rates in the late Cenozoic. Our models also indicate that over the geological time scale a significant portion of materials eroded from Madagascar was not archived in the offshore basin, possibly consumed by chemical weathering, the intensity of which might have varied with climate.