In Situ Measurement of Electro-Osmotic Fluxes and Conductivity Using Single Wellbore Tracer Tests

Electro-osmosis (EO), the movement of water through porous media in response to an electric field, offers a means for extracting contaminated ground water from fine-grained sediments, such as clays, that are not easily amenable to conventional pump-and-treat approaches. The EO-induced water flux is proportional to the voltage gradient in a manner analogous to the flux dependence on the hydraulic gradient under Darcy's law. The proportionality constant, the soil electro-osmotic conductivity or k_eo, is most easily measured in soil cores using bench-top tests, where flow is one-dimensional and interfering effects attributable to Darcy's law can be directly accounted for. In contrast, quantification of EO fluxes and k_eo in the field under deployment conditions can be difficult because electrodes are placed in ground water wells that may be screened across a heterogeneous mixture of lithologies. As a result, EO-induced water fluxes constitute an approximate radial flow system that is superimposed upon a Darcy flow regime through permeable pathways that may or may not be coupled with hydraulic head differences created by the EO-induced water fluxes. A single well comparative tracer test, which indirectly measures EO fluxes by comparing wellbore tracer dilution rates between background and EO-induced water fluxes, may provide a means for routinely quantifying the efficacy of EO systems in such settings. EO fluxes measured in field tests through this technique at a ground water contamination site were used to estimate a mean k_eo value through a semianalytic line source model of the electric field. The resulting estimate agrees well with values reported in the literature and with values obtained with bench-top tests conducted on a soil core collected in the test area.     

Carbonate-hosted siliceous crust type mineralization of Carnic Alps (Italy-Austria)

A carbonate-hosted stratabound siliceous crust type (SCT) mineralization (base metal sulphides, barite, fluorite) occurs over large areas of Carnic Alps and Karawanken in the Eastern Alps. It concerns a pervasively silicified lithological unit, up to some tens of metres thick, which caps the unconformity landscapes developed on epicontinental Devonian–Dinantian carbonates. The SCT mineralization is directly overlaid by different transgressive siliciclastic sediments, which range from Lower Carboniferous to Lower Permian. The presence of fragments of the SCT mineralization in the transgressive siliciclastic sediment bounds its whole lithological evolution within a short stratigraphic interval of Lower Carboniferous age. Selected features of the regional and lithostratigraphic setting are discussed. The chemical characterisation is based on the statistical evaluation of compositional data of 581 selected samples. Three significant groups of elements have been distinguished: (1) the hydrological and metasomatically active elements (Si, Ba, F), which show a strong negative correlation amongst themselves and characterise the silica-saturated aqueous solutions; (2) the terrigenous elements (Al₂O₃, K₂O, Fe_tot, TiO₂, B, Be, Ce, La, Nb, V, Y, Zr), which suggest a continental margin environment for silica deposition; (3) the sulphide metals (Cu, Pb, Zn, Ni, Sb, As, Hg, Cd), which define the metalliferous signature of the SCT mineralization.Some consistent, but still debatable genetic aspects of the SCT mineralization are as follow: (1) silica may be supplied by illitization of clay-rich basinal sediments during their diagenesis. δ¹⁸O of microcrystalline quartz ranges from +18.5‰ and +24.6‰ and is very similar to δ¹⁸O of authigenic quartz deriving from diagenetic processes of illitization of clay-rich basinal sequences. (2) The diagenetic evolution of these sediments may trigger off the movement of silica-rich marine pore waters. δ³⁴S of barite ranges from +15.5‰ to +19.3‰ with an average of +17.7‰ and are in good agreement with δ³⁴S of sulphate in ocean waters of Upper Devonian–Lower Carboniferous age. (3) A convective hydrological system, connected with sinsedimentary transtensive tectonics, active in the Carnic Alps since the Frasnian, may be the transport mechanism of aqueous solutions. (4) A weak drop in pH in the dominant carbonate environment represents the conditions for silica precipitation.SCT mineralization, showing persistent, independent and distinct characters, occurs over large areas also in other sites of the Alpine belt and outside Italy and Austria. Therefore, it points to important markers for some sedimentary sequences as well as to a worldwide significant cyclic metallogenic event. It represents a new ore deposit-type within the carbonate-hosted mineralization.     

Neutron activation analysis of the 1965 taal volcanic ash

Neutron activation analysis of the Taal volcanic ash revealed the presence of unusual amount of scandium in the volcanic ash as compared to the standard basalt BCR-1. The BCR-1 value for Fe/Sc is 2760 while that of Taal ash is about 2649. It is suggested that the eruption was probably characterized by the ejection of scandium-rich materials. Scandium may be used as supplementary evidence in evaluating an impending future Taal volcanic activity.     

Plio-Quaternary volcanotectonic activity in the northern sector of the Main Ethiopian Rift: relationships with oblique rifting

Deformation and magmatism within the 90 km wide northern Ethiopian Rift system is concentrated along a narrow zone - the Wonji Fault Belt. Two key areas (the Nazret-Dera and Asela-Ziway areas), located along the eastern margin of the north-northeast to northeast trending Main Ethiopian Rift, have been investigated in order to reconstruct the recent tectonomagmatic evolution of the northern branch of the Main Ethiopian Rift. In these areas, Early Pleistocene volcanic products (Wonji Group) overlie Pliocene volcanic rocks (Eastern Margin Unit). Detailed stratigraphical reconstructions have revealed the presence of several tectonomagmatic units which can be correlated between the two study areas. The stratigraphical and petrological study of these units outlined (1) the bimodal composition (basalts-pantellerites) of the oldest and youngest units and the unimodal character (pantellerites) of the products erupted during the intervening period; (2) the mainly fissural origin of the ignimbrites and oldest basalts; and (3) a mafic/felsic volumetric ratio of 1:5.The geological data suggest that, around the Pliocene-Quaternary boundary, a change in the stress field occurred in this Main Ethiopian Rift sector, passing from a direction of extension roughly orthogonal to the rift shoulders, to oblique rifting related to an east-west trending extension. In this framework the change in the style of volcanism observed in the Nazret-Dera and Asela-Ziway areas can be related to the change of the stress field. A new geodynamic model is presented for the Late Pliocene to Recent evolution of this sector of the Main Ethiopian Rift. According to this model, a large volume of rhyolitic products was erupted during an oblique rifting phase, following a previous period of pure extension. The change in the tectonic regime favoured partial melting of the underplated basalts as a decrease in the pressure and an elevation of isotherms occurred.     

On gamma-ray emission from CYG X-2

We discuss the importance of hard X- and gamma-ray emission from thermal X-ray sources to obtain a more realistic picture of these objects.In particular, we show that the inverse Compton effect is a possible mechanism of gamma-ray emission from sources of this kind and apply our consideration to the specific case of Cyg X-2.     

An audio-magnetotelluric investigation in Terceira Island (Azores)

Ten audio-magnetotelluric soundings have been carried out along a profile crossing the Serra do Cume caldera in the eastern part of the Terceira Island (Azores). The main objectives of this investigation were to detect geoelectrical features related with tectonic structures and to characterize regional hydrological and hydrothermal aspects mainly those related to geothermal fluid dynamics.Three-dimensional numerical investigation showed that the data acquired at periods shorter than 1 s are not significantly affected by ocean effect. The data was analysed using the Smith's decomposition method in order to investigate possible distortions caused by superficial structures and to estimate a global regional strike. The results suggest that in general the soundings were not distorted. A regional N55°W strike was chosen for the two-dimensional data inversion.The low-resistivity zones (10–30 ohm-m) displayed in the central part of the 2-D geoelectrical model have been interpreted as caused by hydrothermal circulation. The low-resistivity anomalies at the ends of the profile might be attributed to alteration zones with interaction of seawater intrusion. High-resistivity (> 300 ohm-m) values have been related with less permeable zones in the SW of Cinco Picos and Guilherme Moniz caldera walls.     

Improvement of Nakamura technique by singular spectrum analysis

In this work we investigate the application of the Singular Spectrum Analysis to improve Nakamura Technique. The SSA has a wide and multidisciplinary range of applications; it allows a time series to be decomposed into different components, e.g. the signal itself, as well as various noise components, which can be subsequently removed from the data. Removal of the minor component of the data can lead to significant improvements in the identification of the system. In this paper the use of SSA Technique allows to optimize the signal to noise ratio before computing the classical Nakamura spectral ratios. A number of typical applications are also presented.     

The relation between rigorous and Helmert’s definitions of orthometric heights

Following our earlier definition of the rigorous orthometric height [J Geod 79(1-3):82–92 (2005)] we present the derivation and calculation of the differences between this and the Helmert orthometric height, which is embedded in the vertical datums used in numerous countries. By way of comparison, we also consider Mader and Niethammer’s refinements to the Helmert orthometric height. For a profile across the Canadian Rocky Mountains (maximum height of ~2,800 m), the rigorous correction to Helmert’s height reaches ~13 cm, whereas the Mader and Niethammer corrections only reach ~3 cm. The discrepancy is due mostly to the rigorous correction’s consideration of the geoid-generated gravity disturbance. We also point out that several of the terms derived here are the same as those used in regional gravimetric geoid models, thus simplifying their implementation. This will enable those who currently use Helmert orthometric heights to upgrade them to a more rigorous height system based on the Earth’s gravity field and one that is more compatible with a regional geoid model.     

European winter precipitation extremes and large-scale circulation: a coupled model and its scenarios

Summary The physical coupling between the occurrence of winter heavy precipitation in Europe and the surface large-scale circulation is studied by isolating their coupled modes with a singular value decomposition technique. The leading mode is a clear manifestation of the North Atlantic Oscillation forcing. The second mode reflects the influence of a centre-of-action in the pressure field westward of the British Isles. The Hadley Centre Coupled Model (3^rd generation) is skilful in reproducing these two modes and an eastward extension of the North Atlantic Oscillation towards the Mediterranean Basin is projected under two future climatic scenarios. This extension yields an increase in the North Atlantic Oscillation forcing over the occurrence of heavy precipitation in several regions of Southern Europe, which is corroborated by the changes in the coupling of the daily precipitation. A combination of the first six coupled modes of the daily precipitation revealed that its amounts in some parts of Western Europe and the Mediterranean are effectively governed by the large-scale circulation. The model is still reasonably skilful in reproducing this large-scale coupling. The projected modifications, both in the strength and in the patterns of the coupled modes, explain important fractions of the projected changes in variance, which ultimately have implications in the occurrence of heavy precipitation in several European areas. Therefore, the ability of a model in reproducing the large-scale forcing over the daily precipitation is important for the reliability of its projections of the occurrence of heavy precipitation in Europe.