Effect of degassing on sulfur contents and δ34S values in Somma-Vesuvius magmas

Sulfur contents and δ³⁴S values of Somma-Vesuvius magmas are consistent with syneruptive, open-system degassing at temperatures of 800–850°C for Plinian pumices and 1100–1200°C for lavas. The extent of degassing appears to be greater in lavas than in pumices. The key parameter controlling the ³⁴S/³²S ratio of Somma-Vesuvius volcanics is the average magma oxidation state, which generally varies from 0.85 to 1.20 Δ NNO units for lavas and from 1.20 to 1.40 Δ NNO units for pumices. Consequently, S contents and δ³⁴S values of magmas constitute a potentially valuable tool in estimating their average redox conditions. The results of this study may help in risk mitigation when the Vesuvius magmatic system evolves toward eruptive conditions. Received: 20 January 1998 / Accepted: 5 May 1998     

Effective run‐off flow length over biological soil crusts on silty loam soils in drylands

Surface hydrological behaviour is important in drylands because it affects the distribution of soil moisture and vegetation and the hydrological functioning of slopes and catchments. Microplot scale run‐off can be relatively easily measured, i.e. by rainfall simulations. However, slope or catchment run‐off cannot be deduced from microplots, requiring long‐time monitoring, because run‐off coefficients decrease with increasing drainage area. Therefore, to determine the slope length covered by run‐off (run‐off length) is crucial to connect scales. Biological soil crusts (BSCs) are good model systems, and their hydrology at slope scale is insufficiently known. This study provides run‐off lengths from BSCs, by field factorial experiments using rainfall simulation, including two BSC types, three rain types, three antecedent soil moistures and four plot lengths. Data were analysed by generalized linear modelling, including vascular plant cover as covariates. Results were the following: (i) the real contributing area is almost always much smaller than the topographical contributing area; (ii) the BSC type is key to controlling run‐off; run‐off length reached 3 m on cyanobacterial crust, but hardly over 1 m on lichen crust; this pattern remained through rain type or soil moisture; (iii) run‐off decreased with BSC development because soil sealing disappears; porosity, biomass and roughness increase and some changes occur in the uppermost soil layer; and (iv) run‐off flow increased with both rain type and soil moisture but run‐off coefficient only with soil moisture (as larger rains increased both run‐off and infiltration); vascular plant cover had a slight effect on run‐off because it was low and random. Copyright © 2014 John Wiley & Sons, Ltd.     

Detritus Rolling Down a Vertical Cliff of the Ligurian Sea (Italy): The Écological Role in Hard Bottom Communities

Abstract. The detritus rolling down a vertical cliff was studied at Portofino Promontory (Ligurian Sea, Italy) at 16 m depth (January 1988- January 1989). The large amount of collected sediment is mainly due to the position of the traps; they collected not only the sedimenting material, but also the detritus rolling down along the cliff. The amount of sediment matter is 7 times greater in winter than in summer, showing a good correlation with rough seas and rain that cause a "mechanical cleaning" of animal and plant debris (Sérpulid tubes, shells, exuvias. leaves) along the cliff.
The Total Suspended Matter (TSM) in the water column shows maximum values in March and September. The organic fraction has an average concentration of 0.81 mg 1^-l. The phytoplanktonic biomass, measured as Chi a , shows an annual cycle with a peak in spring (1–2.7μg·l^-1). while in other periods of the year the value is about 0.3-0.5 μg·1^-1. A significant relationship was found between organic detritus in the collected sédiments and the Chi a in the water column. The great influence of the rocky wall detritus on the normal trend of the TSM in the coastal water column is pointed out.     

Structure of the lithosphere beneath the Eastern Alps (southern sector of the TRANSALP transect)

The interpretation of the seismic Vibroseis and explosive TRANSALP profiles has examined the upper crustal structures according to the near-surface geological evidences and reconstructions which were extrapolated to depth. Only the southern sector of the TRANSALP transect has been discussed in details, but its relationship with the whole explored chain has been considered as well. The seismic images indicate that pre-collision and deep collision structures of the Alps are not easily recognizable. Conversely, good records of the Neo-Alpine to present architecture were provided by the seismic sections.Two general interpretation models (“Crocodile” and “Extrusion”) have been sketched by the TRANSALP Working Group [2002]. Both illustrate the continental collision producing strong mechanical interaction of the facing European and African margins, as documented by giant lithosphere wedging processes. Arguments consistent with the “Extrusion” model and with the indentation of Adriatic (Southalpine) lithosphere underneath the Tauern Window (TW) are:

– According to the previous DSS reconstructions, the Bouguer anomalies and the Receiver Functions seismological data, the European Moho descends regularly attaining a zone south of the Periadriatic Lineament (PL). The Moho boundary and its geometry appear to be rather convincing from images of the seismic profile;

– the Tauern Window intense uplift and exhumation is coherent with the strong compression regime, which acted at depth, thus originating the upward and lateral displacement of the mobile and ductile Penninic masses according to the “Extrusion” model;

– the indentation of the Penninic mobile masses within the colder and more rigid Adriatic crust cannot be easily sustained. Wedging of the Adriatic stiffened lower crust, under high stresses and into the weaker Penninic domain, can be a more suitable hypothesis. Furthermore, the intrusion of the European Penninic crustal wedge underneath the Dolomites upper crust is not supported by any significant uplifting of the Dolomites. The total average uplift of the Dolomites during the Neogene appears to be 6−7 times smaller than that recognized in the TW. Markedly the northward dip of the PL, reaching a depth of approximately 20 km, is proposed in our interpretation;

– finally, the Adriatic upper crustal evolution points to the late post-collision change in the tectonic grow-up of the Eastern Alps orogenic chain. The tectonic accretion of the northern frontal zone of the Eastern and Central Alps was interrupted from the Late Miocene (Serravallian–Tortonian) onward, as documented by the Molasse basin evolution. On the contrary, the structural nucleation along the S-vergent tectonic belt of the eastern Southern Alps (Montello–Friuli thrust belt) severely continued during the Messinian and the Plio–Pleistocene. This structural evolution can be considered to be consistent with the deep under-thrusting and wedge indentation of the Adriatic lithosphere underneath the southern side of the Eastern Alps thrust-and-fold belt.

Similarly, the significance of the magmatic activity for the construction of the Southern Alps crust and for its mechanical and geological differentiation, which qualified the evolution of the thrust-and-fold belt, is highlighted, starting with the Permian–Triassic magmatism and progressing with the Paleogene occurrences along the Periadriatic Lineament and in the Venetian Magmatic Province (Lessini–Euganei Hills).     

Geospatial preparedness: Empirical study of the joint effort to provide geospatial support to disaster response

In a disaster aftermath in places lacking geospatial preparedness, the United Nations Office for the Coordination of Humanitarian Affairs creates a framework for cooperation with the Coordinated Data Scramble initiative, where Information Management Officers (IMOs) from different organizations work together in supporting the coordination of humanitarian aid. The perspective of these IMOs has been considered to identify the factors influencing the use of GIS in this context. The results show the requirement for a geodata management strategy, including geodata gathering, maintenance, and decision‐making processes based on those geodata. Geodata should be reliable and up‐to‐date. It requires consistent and useful metadata and the possibility of contacting the geodata source. Security and political issues limit information sharing. In this context, OpenStreetMap is often used as a source of information. Therefore, improving OpenStreetMap improves geospatial preparedness. Nevertheless, the use of this open platform highlights issues related to information privacy.     

High‐pressure metamorphic evolution of eclogite and associated metapelite from the Chuacús complex (Guatemala Suture Zone): Constraints from phase equilibria modelling coupled with Lu‐Hf and U‐Pb geochronology

As is common in suture zones, widespread high‐pressure rocks in the Caribbean region reached eclogite facies conditions close to ultrahigh‐pressure metamorphism. Besides eclogite lenses, abundant metapelitic rocks in the Chuacús complex (Guatemala Suture Zone) also preserve evidence for high‐pressure metamorphism. A comprehensive petrological and geochronological study was undertaken to constrain the tectonometamorphic evolution of eclogite and associated metapelite from this area in central Guatemala. The integration of field and petrological data allows the reconstruction of a previously unknown segment of the prograde P–T path and shows that these contrasting rock types share a common high‐pressure evolution. An early stage of high‐pressure/low‐temperature metamorphism at 18–20 kbar and 530–580°C is indicated by garnet core compositions as well as the nature and composition of mineral inclusions in garnet, including kyanite–jadeite–paragonite in an eclogite, and chloritoid–paragonite–rutile in a pelitic schist. Peak high‐pressure conditions are constrained at 23–25 kbar and 620–690°C by combining mineral assemblages, isopleth thermobarometry and Zr‐in‐rutile thermometry. A garnet/whole‐rock Lu‐Hf date of 101.8 ± 3.1 Ma in the kyanite‐bearing eclogite indicates the timing of final garnet growth at eclogite facies conditions, while a Lu‐Hf date of 95.5 ± 2.1 Ma in the pelitic schist reflects the average age of garnet growth spanning from an early eclogite facies evolution to a final amphibolite facies stage. Concordant U‐Pb LA‐ICP‐MS zircon data from the pelitic schist, in contrast, yield a mean age of 74.0 ± 0.5 Ma, which is equivalent to a U‐Pb monazite lower‐intercept age of 73.6 ± 2.0 Ma in the same sample, and comparable within errors with a less precise U‐Pb lower‐intercept age of 80 ± 13 Ma obtained in post‐eclogitic titanite from the kyanite‐bearing eclogite. These U‐Pb metamorphic ages are interpreted as dating an amphibolite facies overprint. Protolith U‐Pb zircon ages of 167.1 ± 4.2 Ma and 424.6 ± 5.0 Ma from two eclogite samples reveal that mafic precursors in the Chuacús complex originated in multiple tectonotemporal settings from the Silurian to Jurassic. The integration of petrological and geochronological data suggests that subduction of the continental margin of the North American plate (Chuacús complex) beneath the Greater Antilles arc occurred during an Albian‐Cenomanian pre‐collisional stage, and that a subsequent Campanian collisional stage is probably responsible of the amphibolite facies overprint and late syncollisional exhumation.     

Temperature and precipitation projections for the Antarctic Peninsula over the next two decades: contrasting global and regional climate model simulations

This study presents near future (2020–2044) temperature and precipitation changes over the Antarctic Peninsula under the high-emission scenario (RCP8.5). We make use of historical and projected simulations from 19 global climate models (GCMs) participating in Coupled Model Intercomparison Project phase 5 (CMIP5). We compare and contrast GCMs projections with two groups of regional climate model simulations (RCMs): (1) high resolution (15-km) simulations performed with Polar-WRF model forced with bias-corrected NCAR-CESM1 (NC-CORR) over the Antarctic Peninsula, (2) medium resolution (50-km) simulations of KNMI-RACMO21P forced with EC-EARTH (EC) obtained from the CORDEX-Antarctica. A further comparison of historical simulations (1981–2005) with respect to ERA5 reanalysis is also included for circulation patterns and near-surface temperature climatology. In general, both RCM boundary conditions represent well the main circulation patterns of the historical period. Nonetheless, there are important differences in projections such as a notable deepening and weakening of the Amundsen Sea Low in EC and NC-CORR, respectively. Mean annual near-surface temperatures are projected to increase by about 0.5–1.5 \(^{\circ }\)C across the entire peninsula. Temperature increase is more substantial in autumn and winter (\(\sim \) 2 \(^{\circ }\)C). Following opposite circulation pattern changes, both EC and NC-CORR exhibit different warming rates, indicating a possible continuation of natural decadal variability. Although generally showing similar temperature changes, RCM projections show less warming and a smaller increase in melt days in the Larsen Ice Shelf compared to their respective driving fields. Regarding precipitation, there is a broad agreement among the simulations, indicating an increase in mean annual precipitation (\(\sim \) 5 to 10%). However, RCMs show some notable differences over the Larsen Ice Shelf where total precipitation decreases (for RACMO) and shows a small increase in rain frequency. We conclude that it seems still difficult to get consistent projections from GCMs for the Antarctic Peninsula as depicted in both RCM boundary conditions. In addition, dominant and common changes from the boundary conditions are largely evident in the RCM simulations. We argue that added value of RCM projections is driven by processes shaped by finer local details and different physics schemes that are introduced by RCMs, particularly over the Larsen Ice Shelf.

     

Non-explosive magma–water interaction in a continental setting: Miocene examples from the Eastern Cordillera (central Andes; NW Argentina)

The Middle-Upper Miocene Las Burras–Almagro-El Toro (BAT) igneous complex within the Eastern Cordillera of the central Andes (∼24°S; NW Argentina) has revealed evidence of non-explosive interaction of andesitic magma with water or wet clastic sediments in a continental setting, including peperite generation. We describe and interpret lithofacies and emplacement mechanisms in three case studies. The Las Cuevas member (11.8 Ma) comprises facies related to: (i) andesite extruded in a subaqueous setting and generating lobe-hyaloclastite lava; and (ii) marginal parts of subaerial andesite lava dome(s) in contact with surface water, comprising fluidal lava lobes, hyaloclastite, and juvenile clasts with glassy rims. The Lampazar member (7.8 Ma) is represented by a syn-volcanic andesite intrusion and related peperite that formed within unconsolidated, water-saturated, coarse-grained volcaniclastic conglomerate and breccia. The andesite intrusion is finger-shaped and grades into intrusive pillows. Pillows are up to 2 m wide, tightly packed near the intrusion fingers, and gradually become dispersed in the host sediment ≥50 m from the parent intrusion. The Almagro A member (7.2 Ma) shows evidence of mingling between water-saturated, coarse-grained, volcaniclastic alluvial breccia and intruding andesite magma. The resulting intrusive pillows are characterized by ellipsoidal and tubular shape and concentric structure. The high-level penetration of magma in this coarse sediment was unconfined and irregular. Magma was detached in apophyses and lobes with sharp contacts and fluidal shapes, and without quench fragmentation and formation of a hyaloclastite envelope. The presence of peperite and magma–water contact facies in the BAT volcanic sequence indicates the possible availability of water in the system between 11–7 Ma and suggests a depositional setting in this part of the foreland basin of the central Andes characterized by an overall topographically low coastal floodplain that included extensive wetlands.     

Continental evaporites and the search for evidence of life on Mars

Continental evaporites are deposits that originate from the evaporation of saline waters in the low areas of saline lakes from all continents, except Europe, and mainly consist of chloride, sulphate and potash minerals. In recent years, the discovery on the Martian surface of hydrated salt minerals, including sulphates and chlorides, interpreted as deriving from the desiccation of preexisting large bodies of water, such as lakes, has provided further convincing evidence of liquid water activity on the surface of Mars and, consequently, it has reinforced the plausibility of finding life. Because evaporites require short‐term aqueous processes for their formation, they can trap and preserve over geologic times a biological record made up of halophilic extremophiles—such as microalgae, bacteria, and their remains—that recent research on Earth has shown to be characterized by unexpectedly high biodiversity. This record may consist of varying types of fossils, including morphological fossils, chemofossils and biominerals. As a consequence, continental evaporite environments and their saline deposits are now a primary target for the near future astrobiology missions devoted to the search for fossil Martian life. Lacustrine evaporite deposits and minerals have, therefore, been identified as primary targets for the NASA–ESA joint programme of the Mars sample return, planned for the end of the current decade. Copyright © 2011 John Wiley & Sons, Ltd.