Reviewing pre-TRANSALP DSS models

The interpretation of DSS (deep seismic soundings) profiles in Central and Eastern Alps is recalled in the paper and the models of the lower crust and Moho proposed several years ago are compared to the results of the TRANSALP seismic reflection profile. This evaluation highlights a good agreement as far as the geometry of the deep crustal structure is concerned. Therefore, the reliability of the interpretative models, previously exclusively based on DSS profiles, becomes improved. The deep structure beneath the whole Alpine range is examined reconsidering the map of the Moho boundary and the structural model already proposed for the central-eastern sector. Five main interpretative transects are put side by side, starting from the Western Alps and moving eastwards to the Swiss–Lombardian Central Alps (“European Geotraverse”), to the cross section from southern Bavaria to the Euganei Hills, to the TRANSALP profile, and finally to the easternmost profile available so far (southern Bavaria–Trieste). The comparison outlines lateral variations of the deep crustal structure as well as a sharp contrast between the Adria and the European lower crust and Moho. The transition from the Adria plate to the Dinaric domain remains, up to now, undefined.     

Uranium(6+) sorption on montmorillonite: Experimental and surface complexation modeling study

Sorption interactions with montmorillonite and other clay minerals in soils, sediments, and rocks are potentially important mechanisms for attenuating the mobility of U(6+) and other radionuclides through the subsurface environment. Batch experiments were conducted (in equilibrium with atmospheric % MathType!MTEF!2!1!+-% feaafeart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXafv3ySLgzGmvETj2BSbqefm0B1jxALjhiov2D% aebbfv3ySLgzGueE0jxyaibaiiYdd9qrFfea0dXdf9vqai-hEir8Ve% ea0de9qq-hbrpepeea0db9q8as0-LqLs-Jirpepeea0-as0Fb9pgea% 0lrP0xe9Fve9Fve9qapdbaqaaeGacaGaaiaabeqaamaabaabcaGcba% acbiGaiWiG-bfadaWgaaWcbaacbaGaa43qaiaa+9eadaWgaaqaaiaa% +jdaaWqabaaaleqaaaaa!400D!\[P_{CO_2 } \])to determine the effects of varying pH (2 to 9), solid-mass to solution-volume ratio (M/V = 0.028 to 3.2 g/L), and solution concentration (2 × 10^?7 and 2 × 10^?6 M ²³³U) on U(6+) sorption on SAz-1 montmorillonite. The study focused on U(6+) surface complexation on hydroxylated edge sites as the sorption mechanism of interest because it is expected to be the predominant sorption mechanism at pHs typical of natural waters (pH ≈6 to ≈9). Thus, the experiments were conducted with a 0.1 M NaNO₃ matrix to suppress ion-exchange between U(6+) in solution and interlayer cations. The results show that U(6+) sorption on montmorillonite is a strong function of pH, reaching a maximum at near-neutral pH (≈6 to ≈6.5) and decreasing sharply towards more acidic or more alkaline conditions. A comparison of the pH-dependence of U(6+) sorption with that of U(6+) aqueous speciation indicates a close correspondence between U(6+) sorption and the predominance field of U(6+)-hydroxy complexes. At high pH, sorption is inhibited due to formation of aqueous U(6+)-carbonate complexes. At low pH, the low sorption values indicate that the 0.1 M NaNO₃ matrix was effective in suppressing ion-exchange between the uranyl (UO₂ ²⁺) species and interlayer cations in montmorillonite. At pH and carbonate concentrations typical of natural waters, sorption of U(6+) on montmorillonite can vary by four orders of magnitude and can become negligible at high pH. The experimental results were used to develop a thermodynamic model based on a surface complexation approach to permit predictions of U(6+) sorption at differing physicochemical conditions. A Diffuse-Layer model (DLM) assuming aluminol (>AlOH^?) and silanol (>SiOH^?) edge sites and two U(6+) surface complexation reactions per site effectively simulates the complex sorption behavior observed in the U(6+)-H₂O-CO₂-montmorillonite system at an ionic strength of 0.1 M and pH > 3.5. A comparison of model predictions with data from this study and from published literature shows good agreement and suggests that surface complexation models based on parameters derived from a limited set of data could be useful in extrapolating radionuclide sorption over a range of geochemical conditions. Such an approach could be used to support transport modeling by providing a better alternative to the use of constant K _d s in transport calculations.     

The MED-SUV virtual research environment for enabling the GEO Geohazard supersites in Italy

This paper presents the Virtual Research Environment (VRE) enabling two European GEO Geohazard Supersites in Italy. According to GEO (Group on Earth Observation) vision, Geohazard Supersites provide access to spaceborne and in-situ geophysical data and models for selected sites prone to natural hazards –noticeably, earthquakes and volcano eruptions. The VRE was implemented in the framework of the Mediterranean Supersite Volcanoes (MED-SUV) project, funded by the European Commission. MED-SUV realized one of the European supersite demonstrators covering the two Permanent Supersites selected in Italy: Mt. Etna and Campi Flegrei/Vesuvius. The MED-SUV VRE provides advanced services for heterogeneous data and information management and sharing. MED-SUV started identifying the main supersite requirements including: the interoperability with existing data/information supply systems, the support of policy-based access control, the access to processing capabilities provided by external platforms, the management resources for publishing and sharing new products, the integration with significant global systems such as GEOSS and EPOS. MED-SUV adopted a System of Systems (SoS) approach to address interoperability with the identified heterogeneous systems supplying data and information. The SoS approach is based on a brokering architecture, where a specialized component (i.e the MED-SUV Broker: MSB) connects the existing and next-coming data sources leaving them autonomous. MSB carries out all the necessary mediation and harmonization tasks exposing standard interfaces enabling the interconnection with external systems like GEOSS and EPOS. In addition, MSB is accessible via a JavaScript library implementing Web APIs to facilitate the development of Web and mobile applications.     

Regional assessment of long-term hypolimnetic oxygen changes in Ontario (Canada) shield lakes using subfossil chironomids

Subfossil chironomid assemblages were used to infer long-term water quality changes in south-central Ontario shield lakes, which are currently being impacted by anthropogenic eutrophication, acid rain, and recent climate change. Using a transfer function developed to infer average end-of-summer volume-weighted hypolimnetic oxygen (avg VWHO), a top-bottom paleolimnological approach was used to reconstruct pre-industrial (pre-1850) deepwater oxygen conditions. Comparison with present-day (top surface sediments) chironomid-based inferences of avgVWHO results suggest that hypolimnetic oxygen levels are presently similar to natural, pre-industrial (bottom sediments) levels in most lakes. Approximately half of the study lakes recorded an increase in hypolimnetic oxygen since the 19th century. Inferred changes in avgVWHO correlate well with our results from another chironomid-based oxygen model which reconstructs the Anoxic Factor (AF). When study lakes are separated according to their hydrological status (i.e., natural versus managed), lakes with a dam at their outlet and seasonally managed lake levels had significantly different changes in avgVWHO compared to lakes with natural hydrology. Lakes with a dam at their outlet generally recorded increases in avgVWHO, while natural hydrology lakes mostly recorded declines. There was no relationship between inferred changes in avgVWHO and the density of cottage and resort development along the shorelines of lakes. Changes in dissolved organic carbon (DOC) possibly related to recent climate changes may also be affecting deepwater oxygen, however patterns of change are very subtle.     

Temperature and precipitation projections for the Antarctic Peninsula over the next two decades: contrasting global and regional climate model simulations

This study presents near future (2020–2044) temperature and precipitation changes over the Antarctic Peninsula under the high-emission scenario (RCP8.5). We make use of historical and projected simulations from 19 global climate models (GCMs) participating in Coupled Model Intercomparison Project phase 5 (CMIP5). We compare and contrast GCMs projections with two groups of regional climate model simulations (RCMs): (1) high resolution (15-km) simulations performed with Polar-WRF model forced with bias-corrected NCAR-CESM1 (NC-CORR) over the Antarctic Peninsula, (2) medium resolution (50-km) simulations of KNMI-RACMO21P forced with EC-EARTH (EC) obtained from the CORDEX-Antarctica. A further comparison of historical simulations (1981–2005) with respect to ERA5 reanalysis is also included for circulation patterns and near-surface temperature climatology. In general, both RCM boundary conditions represent well the main circulation patterns of the historical period. Nonetheless, there are important differences in projections such as a notable deepening and weakening of the Amundsen Sea Low in EC and NC-CORR, respectively. Mean annual near-surface temperatures are projected to increase by about 0.5–1.5 \(^{\circ }\)C across the entire peninsula. Temperature increase is more substantial in autumn and winter (\(\sim \) 2 \(^{\circ }\)C). Following opposite circulation pattern changes, both EC and NC-CORR exhibit different warming rates, indicating a possible continuation of natural decadal variability. Although generally showing similar temperature changes, RCM projections show less warming and a smaller increase in melt days in the Larsen Ice Shelf compared to their respective driving fields. Regarding precipitation, there is a broad agreement among the simulations, indicating an increase in mean annual precipitation (\(\sim \) 5 to 10%). However, RCMs show some notable differences over the Larsen Ice Shelf where total precipitation decreases (for RACMO) and shows a small increase in rain frequency. We conclude that it seems still difficult to get consistent projections from GCMs for the Antarctic Peninsula as depicted in both RCM boundary conditions. In addition, dominant and common changes from the boundary conditions are largely evident in the RCM simulations. We argue that added value of RCM projections is driven by processes shaped by finer local details and different physics schemes that are introduced by RCMs, particularly over the Larsen Ice Shelf.

     

New evidences of hydrothermal fluids circulation at the Devonian Kess Kess mounds,Hamar Laghdad (eastern Anti‐Atlas,Morocco)

New evidences based on a combination of field and laboratory investigations reinforce the hypotheses that the circulation of warm fluids has remarkably contributed to the origin and development of the Devonian Kess Kess mounds of the Hamar Laghdad Ridge (eastern Anti‐Atlas, Morocco). The limestones of the Hamar Laghdad Ridge were deposited above a structural high generated by calc‐alkaline volcanic activity that has probably fuelled the circulation of warm fluids throughout the overlying carbonate units. The geological and palaeontological attributes described throughout the succession of the Hamar Laghdad Ridge (from the Lochkovian to Frasnian intervals) are interpreted as the result of hydrothermal processes related to a volcanic system. In particular, these attributes seem consistent with a chemo‐physical environment fuelled by the circulation of warm and late magmatic fluids. These attributes include a very low oxygen stable isotope signature (δ¹⁸O ~ −10‰) for carbonates. Evidences for a late magmatic fluid circulation consist of volcanic glass and pyroclasts replacement with hydrothermal minerals such as quartz, anatase and clinochlore. Fluids circulating through veins and pores into sediments, and venting to the seafloor, probably induced the formation of cavities where monospecific trilobite communities were detected. The partially silicified trilobite remains are associated with traces of goethite. This iron‐bearing oxide mineral is also present in the upper part of the Hamar Laghdad Ridge. All these attributes are here interpreted as possible evidences for a low‐temperature hydrothermal venting system active during the Lochkovian–Frasnian time span. This study combines an updated revision with new petrographic, geological and geochemical results aimed at providing an overall framework on the origin and early diagenesis of the Devonian succession of Hamar Laghdad. Copyright © 2014 John Wiley & Sons, Ltd.     

The UV enigma of post-starburst galaxies

We have studied the panchromatic broad-band properties from the FUV to the MIR of a sample of 808 post-starburst galaxies. We find that in the optical and near-IR bands post-starburst galaxies (PSGs) form a remarkably uniform class of objects and that, on average, simple populations synthesis models (SSP) reproduce very well the SEDs of PSGs over a broad wavelength range, but not in the UV. We also find that, while the photometric variance in the optical and near-IR properties of the sample is small and comparable to the observational errors, both in the UV and the mid-IR the observed variance is much larger than the errors. We find a strong correlation between the UV fluxes and those in the mid-IR, indicating that the large variance in UV properties of PSGs could be related to a non-uniform distribution of dust covering the intermediate age populations. The disagreement between models and observations in the UV could be due to inadequate modelling; to the contribution of AGB and post-AGB stars; or to a non-uniform distribution of dust; possibly all three. Further progress in understanding this important class of galaxies, therefore, requires at the same time better modelling and better observations in the UV and mid-IR.     

Shallow-landslide susceptibility in the Costa Viola mountain ridge (southern Calabria,Italy) with considerations on the role of causal factors

The “Costa Viola” mountain ridge (southern Calabria), in the sector between Bagnara Calabra and Scilla, is particularly exposed to geo-hydrological risk conditions. The study area has repeatedly been affected by slope instability events in the last decades, mainly related to debris slides, rock falls and debris flows. These types of slope movements are among the most destructive and dangerous for people and infrastructures, and are characterized by abrupt onset and extremely rapid movements. Susceptibility evaluations to shallow landslides have been performed by only focusing on source activation. A logistic regression approach has been applied to estimating the presence/absence of sources in terms of probability, on the basis of linear statistical relationships with a set of territorial variables. An inventory map of 181 sources, obtained from interpretation of air photographs taken in 1954–1955, has been used as training set, and another map of 81 sources, extracted from 1990 to 1991 photographs, has been adopted for validation purposes. An initial set of 12 territorial variables (i.e. lithology, land use, soil sand percentage, elevation, slope angle, aspect, across-slope and down-slope curvatures, topographic wetness index, distance to road, distance to fault and index of daily rainfall) has been considered. The adopted regression procedure consists of the following steps: (1) parameterization of the independent variables, (2) sampling, (3) calibration, (4) application and (5) evaluation of the forecasting capability. The “best set” of variables could be identified by iteratively excluding one variable at a time, and comparing the ROC results. Through a sensitivity analysis, the role of the considered factors in predisposing shallow slope failures in the study area has been evaluated. The results obtained for the Costa Viola mountain ridge can be considered acceptable, as 98.1 % of the cells are correctly classified. According to the susceptibility map, the village of Scilla and its surroundings fall in the highest susceptibility class.     

Comet McNaught (260P/2012 K2): spin axis orientation and rotation period

Extensive observations of comet 260P/McNaught were carried out between August 2012 and January 2013. The images obtained were used to analyze the comet’s inner coma morphology at resolutions ranging from 250 to about 1000 km/pixel. A deep investigation of the dust features in the inner coma allowed us to identify only a single main active source on the comet’s nucleus, at an estimated latitude of ?50^°±15^°. A thorough analysis of the appearance and of the motion of the morphological structures, supported by graphic simulations of the geometrical conditions of the observations, allowed us to determine a pole orientation located within a circular spot of a 15^°-radius centered at RA=60^°, Dec=0^°. The rotation of the nucleus seems to occur on a single axis and is not chaotic, furthermore no precession effects could be estimated from our measurements. The comet’s spin axis never reached the plane of the sky from October 2012 to January 2013; during this period it did not change its direction significantly (less than 30^°), thus giving us the opportunity to observe mainly structures such as bow-shaped jets departing from the single active source located on the comet’s nucleus. Only during the months of August 2012 and January 2013 the polar axis was directed towards the Earth at an angle of about 45^° from the plane of the sky; this made it possible to observe the development of faint structures like fragments of shells or spirals. A possible rotation period of 0.340±0.01 days was estimated by means of differential photometric analysis.