The double solid reactant method: II. An application to the shallow groundwaters of the Porto Plain,Vulcano Island (Italy)

This paper presents an example of application of the double solid reactant method (DSRM) of Accornero and Marini (Environmental Geology, 2007a), an effective way for modeling the fate of several dissolved trace elements during water–rock interaction. The EQ3/6 software package was used for simulating the irreversible water–rock mass transfer accompanying the generation of the groundwaters of the Porto Plain shallow aquifer, starting from a degassed diluted crateric steam condensate. Reaction path modeling was performed in reaction progress mode and under closed-system conditions. The simulations assumed: (1) bulk dissolution (i.e., without any constraint on the kinetics of dissolution/precipitation reactions) of a single solid phase, a leucite-latitic glass, and (2) precipitation of amorphous silica, barite, alunite, jarosite, anhydrite, kaolinite, a solid mixture of smectites, fluorite, a solid mixture of hydroxides, illite-K, a solid mixture of saponites, a solid mixture of trigonal carbonates and a solid mixture of orthorhombic carbonates. Analytical concentrations of major chemical elements and several trace elements (Cr, Mn, Fe, Ni, Cu, Zn, As, Sr and Ba) in groundwaters were satisfactorily reproduced. In addition to these simulations, similar runs for a rhyolite, a latite and a trachyte permitted to calculate major oxide contents for the authigenic paragenesis which are comparable, to a first approximation, with the corresponding data measured for local altered rocks belonging to the silicic, advanced argillic and intermediate argillic alteration facies. The important role played by both the solid mixture of trigonal carbonates as sequestrator of Mn, Zn, Cu and Ni and the solid mixture of orthorhombic carbonates as scavenger of Sr and Ba is emphasized.

The Late Holocene to Pleistocene tephrostratigraphic record of Lake Ohrid (Albania)

We present in this work a tephrostratigraphic record from a sediment piston core (JO 2004) from Lake Ohrid. Five tephra layers were recognised, all from explosive eruptions of southern Italy volcanoes. A multidisciplinary study was carried out, including stratigraphy, AMS ¹⁴C chronology and geochemistry. The five tephra layers were correlated with terrestrial proximal counterparts and with both marine and lacustrine tephra layers already known in the central Mediterranean area. The oldest is from Pantelleria Island (P11, 131 ka BP). Other three tephra layers are from Campanian volcanoes: X6, Campanian Ignimbrite-Y5 and SMP1-Y3 (107, 39 and 31 ka BP respectively). The youngest tephra layer corresponds to the FL eruption from Etna Volcano (3.4 ka BP). In three cases these recognitions confirm previous findings in the Balkans, while two of them were for the first time recognised in the area, with a significant enlargement of the previous assessed dispersal areas.     

Improvement of Nakamura technique by singular spectrum analysis

In this work we investigate the application of the Singular Spectrum Analysis to improve Nakamura Technique. The SSA has a wide and multidisciplinary range of applications; it allows a time series to be decomposed into different components, e.g. the signal itself, as well as various noise components, which can be subsequently removed from the data. Removal of the minor component of the data can lead to significant improvements in the identification of the system. In this paper the use of SSA Technique allows to optimize the signal to noise ratio before computing the classical Nakamura spectral ratios. A number of typical applications are also presented.     

Magma mixing and convective compositional layering within the Vesuvius magma chamber

The pumice-fall deposits of the last two Plinian eruptions of Vesuvius-a.d. 79 Pompei and 3700 b.p. Avellino-show a marked vertical compositional variation from white phonolite at the base to grey tephritic phonolite at the top. In both Avellino and Pompei sequences a compositional gap separates white from grey pumice. Grey and white pumice have distinct Sr and Nd isotopic compositions (grey pumice: ⁸⁷Sr/³⁶Sr=0.70749-56, ¹⁴³Nd/¹⁴⁴Nd=0.512507 for Pompei; 0.70760-69, 0.512504 for Avellino; white pumice: 0.70757-78 for Pompei; 0.70729-42 for Avellino). K-feldspar separated from both grey and white pumice has, in all cases, a white ⁸⁷Sr/⁸⁶Sr ratio (0.70766-79 for Pompei, 0.70728-33 for Avellino). The observed variations are interpreted as reflecting a pre-eruptive zonation of the magma chamber. Although mineralogical evidence of interaction between magma and calcareous country rocks exists in both eruptions, crustal contamination has not significantly modified the isotopic signatures of the erupted products. Petrographic and isotopic evidence of syneruptive magma mingling occur in Pompei grey pumice as well as in Avellino white and grey pumice, but they do not fully explain all the observed geochemical and isotopic variations. These variations are related to the complex refilling history of the magmatic system and result by fractional crystallization and mixing processes acting within the magma chamber. Preliminary data from other Plinian and subplinian sruptions of the Somma-Vesuvius point out the repeticive behaviour of ⁸⁷Sr/⁸⁶Sr variation in the last 25 000 years, hence suggesting a single magma chamber and continuity of the feeding system.     

Passive seismic control of cable-stayed bridges with damped resonant appendages

A study is conducted to investigate the effectiveness of attaching to cable-stayed bridges resonant appendages with a relatively small mass and a high damping ratio as a means to reduce their response to earthquake excitations. The study is based on a previously developed formulation that shows that the use of these appendages may increase the inherent damping of building structures and, as a result, may reduce their response to seismic disturbances. It includes numerical and experimental tests that are conducted to assess the validity of such a formulation for the case of cable-stayed bridges and the extent to which such appendages can reduce their seismic response. In the numerical study, an actual cable-stayed bridge is modelled with finite elements and analysed with and without the proposed appendages under different earthquake ground motions. Appendages with damping ratios of 10, 15, 20 and 30 per cent and masses that, respectively, represent 0.67, 1.5, 2.7 and 6.0 per cent of the total mass of the bridge are considered. In the experimental test, a 3.7 m long cable-stayed bridge and an appendage consisting of a small mass, a small spring and a small viscous damper are built and the bridge tested, without and with the appendage, on a pair of shaking tables which are set to reproduce ground acceleration records from past earthquakes. The damping ratio of the appendage in this test is 32 per cent and its mass represents about 8 per cent of the total mass of the bridge model. In the numerical test, it is found that the appendages reduce the longitudinal response of the bridge deck up to 88 per cent. Similarly, in the experimental test it is found that the appendage reduces the longitudinal bridge deck response by about 41 per cent. From these studies, it is concluded that the suggested appendages may indeed be effective in reducing the seismic response of cable-stayed bridges as they are for building structures.     

Multi-refractor imaging with stacked refraction convolution section

Multi‐refractor imaging is a technique for constructing a single two‐dimensional image of a number of refractors by stacking multiple convolved and cross‐correlated reversed shot records. The method is most effective with high‐fold data that have been obtained with roll‐along acquisition programs because the stacking process significantly improves the signal‐to‐noise ratios. The major advantage of the multi‐refractor imaging method is that all the data can be stacked to maximize the signal‐to‐noise ratios before the measurement of any traveltimes. However, the signal‐to‐noise ratios can be further increased if only those traces that have arrivals from the same refractor are used, and if the correct reciprocal times or traces are employed. A field case study shows that multi‐refractor imaging can produce a cross‐section similar to the familiar reflection cross‐section with substantially higher signal‐to‐noise ratios for the equivalent interfaces.     

Hypogeal geological survey in the “Grotta del Re Tiberio” natural cave (Apennines, Italy): a valid tool for reconstructing the structural setting

As karst systems are natural windows to the underground, speleology, combined with geological surveys, can be useful tools for helping understand the geological evolution of karst areas. In order to enhance the reconstruction of the structural setting in a gypsum karst area (Vena del Gesso, Romagna Apennines), a detailed analysis has been carried out on hypogeal data. Structural features (faults, fractures, tectonic foliations, bedding) have been mapped in the ”Grotta del Re Tiberio” cave, in the nearby gypsum quarry tunnels and open pit benches. Five fracture systems and six fault systems have been identified. The fault systems have been further analyzed through stereographic projections and geometric-kinematic evaluations in order to reconstruct the relative chronology of these structures. This analysis led to the detection of two deformation phases. The results permitted linking of the hypogeal data with the surface data both at a local and regional scale. At the local scale, fracture data collected in the underground have been compared with previous authors’ surface data coming from the quarry area. The two data sets show a very good correspondence, as every underground fracture system matches with one of the surface fracture system. Moreover, in the cave, a larger number of fractures belonging to each system could be mapped. At the regional scale, the two deformation phases detected can be integrated in the structural setting of the study area, thereby enhancing the tectonic interpretation of the area (e.g., structures belonging to a new deformation phase, not reported before, have been identified underground). The structural detailed hypogeal survey has, thus, provided very useful data, both by integrating the existing information and revealing new data not detected at the surface. In particular, some small structures (e.g., displacement markers and short fractures) are better preserved in the hypogeal environment than on the surface where the outcropping gypsum is more exposed to dissolution and recrystallization. The hypogeal geological survey, therefore, can be considered a powerful tool for integrating the surface and log data in order to enhance the reconstruction of the deformational history and to get a three-dimensional model of the bedrock in karst areas.     

Simplified vibratory characterization of alluvial basins

For the analysis of seismic wave amplification, modal methods are interesting tools to study the modal properties of geological structures. Modal approaches mainly lead to information on such parameters as fundamental frequencies and eigenmodes of alluvial basins. For a specific alluvial deposit in Nice (France), a simplified modal approach involving the Rayleigh method is considered. This approach assumes a set of admissible shape functions for the eigenmodes and allows a fast estimation of the fundamental frequency of the basin. The agreement with other numerical results (Boundary Element Method) and experimental ones is fully satisfactory. The simplified modal method then appears as an efficient mean for the global vibratory characterization of geological structures towards resonance. To cite this article: J.-F. Semblat et al., C. R. Geoscience 335 (2003).     

Timing of deformation in the Norseman-Wiluna Belt, Yilgarn Craton, Western Australia

Establishing relative and absolute time frameworks for the sedimentary, magmatic, tectonic and gold mineralisation events in the Norseman-Wiluna Belt of the Archean Yilgarn Craton of Western Australia, has long been the main aim of research efforts. Recently published constraints on the timing of sedimentation and absolute granite ages have emphasized the shortcomings of the established rationale used for interpreting the timing of deformation events. In this paper the assumptions underlying this rationale are scrutinized, and it is shown that they are the source of significant misinterpretations. A revised time chart for the deformation events of the belt is established. The first shortening phase to affect the belt, D₁, was preceded by an extensional event D_1e and accompanied by a change from volcanic-dominated to plutonic-dominated magmatism at approximately 2685–2675 Ma. Later extension (D_2e) controlled deposition of the ca 2655 Ma Kurrawang Sequence and was followed by D₂, a major shortening event, which folded this sequence. D₂ must therefore have started after 2655 Ma—at least 20 Ma later than previously thought and after the voluminous 2670–2655 Ma high-Ca granite intrusion. Younger transcurrent deformation, D₃–D₄, waned at around 2630 Ma, suggesting that the crustal shortening deformation cycle D₂–D₄ lasted approximately 20–30 Ma, contemporaneous with low-volume 2650–2630 Ma low-Ca granites and alkaline intrusions. Time constraints on gold deposits suggest a late mineralisation event between 2640–2630 Ma. Thus, D₂–D₄ deformation cycle and late felsic magmatism define a 20–30 Ma long tectonothermal event, which culminated with gold mineralisation. The finding that D₂ folding took place after voluminous high-Ca granite intrusion led to research into the role of competent bodies during folding by means of numerical models. Results suggest that buoyancy-driven doming of pre-tectonic competent bodies trigger growth of antiforms, whereas non-buoyant, competent granite bodies trigger growth of synforms. The conspicuous presence of pre-folding granites in the cores of anticlines may be a result from active buoyancy doming during folding.