Bioremediation of petroleum hydrocarbons in anoxic marine sediments: Consequences on the speciation of heavy metals

We investigated the effects of biostimulation and bioagumentation strategies applied to harbor sediments displaying reducing conditions and high concentrations of petroleum hydrocarbons and heavy metals. We compared the microbial efficiency of hydrocarbon removal from sediments maintained for 60 days in anoxic conditions and inoculated with acetate, sulfate-reducing bacterial strains and acetate and sulfate-reducing bacteria. All treatments determined a significant increase in the microbial growth and significant decreases of hydrocarbon contents and of redox potential values. The addition of sulfate-reducing bacterial strains to the sediment was the most efficient treatment for the hydrocarbon removal. In all experiments, significant changes of the heavy metals’ phase repartition were observed. The results reported here suggest that the biodegradation of petroleum hydrocarbons in anoxic marine sediments may be enhanced by stimulating microbial anaerobic metabolism, but care should be applied to monitor the potential changes in the mobility and bioavailability of heavy metals induced by bio-treatments.     

Recent Near-surface Temperature Trends in the Antarctic Peninsula from Observed,Reanalysis and Regional Climate Model Data

This study investigates the recent near-surface temperature trends over the Antarctic Peninsula.We make use of available surface observations,ECMWF’s ERA5 and its predecessor ERA-Interim,as well as numerical simulations,allowing us to contrast different data sources.We use hindcast simulations performed with Polar-WRF over the Antarctic Peninsula on a nested domain configuration at 45 km(PWRF-45)and 15 km(PWRF-15)spatial resolutions for the period 1991?2015.In addition,we include hindcast simulations of KNMI-RACMO21P obtained from the CORDEX-Antarctica domain(~50 km)for further comparisons.Results show that there is a marked windward warming trend except during summer.This windward warming trend is particularly notable in the autumn season and likely to be associated with the recent deepening of the Amundsen/Bellingshausen Sea low and warm advection towards the Antarctic Peninsula.On the other hand,an overall summer cooling is characterized by the strengthening of the Weddell Sea low as well as an anticyclonic trend over the Amundsen Sea accompanied by northward winds.The persistent cooling trend observed at the Larsen Ice Shelf station is not captured by ERA-Interim,whereas hindcast simulations indicate that there is a clear pattern of windward warming and leeward cooling.Furthermore,larger temporal correlations and lower differences exhibited by PWRF-15 illustrate the existence of the added value in the higher spatial resolution simulation.     

Distrubution of Dissolved and Particulate Iron, copper and Manganese in the Shelf waters of the Ross sea (Antarctica)

Abstract. During the austral summer 1997–98, within the framework of the activities of the Climatic Long-term Interaction for the Massbalance in Antarctica (CLIMA) Project of the Italian National Program for Antarctic Research (PNRA) in the Ross Sea, measurements were conducted to focus on the role of dissolved iron, copper and manganese as micronutrients, and on their distribution in suspended particulate matter in different water masses. Sampling was carried out in two selected shelf areas, both important for formation and mixing processes of the water bodies.
Metal data were evaluated together with physical measurements and classical chemical parameters such as oxygen and nutrients.
In both the studied areas, the distribution of dissolved metals along the waste column confirmed their micronutrient behaviour, showing depletion where phytoplanktonic activities occurred.
The trend of particulate metals underlined the scavenging phenomena along the water column and presented an interesting correlation at intermediate depths with the amount and origin of suspended matter.     

On the estimation of mooring line characteristic resistance for reliability analysis

The main aim of this work is to derive a correct formulation for the characteristic resistance of a mooring line segment with lognormally distributed component resistances and substitute an equation proposed by Vazquez-Hernandez et al. [Vazquez-Hernandez AO, Ellwanger GB, Sagrilo LVS. Reliability-based comparative study for mooring lines design criteria. Appl Ocean Res 2006; 28(6):398–406] in a paper published in this journal, which is not correct. The mooring line is considered as a series system and the resistances of individual components of a line segment are statistically independent and identically distributed; furthermore, the case of normally distributed component resistances is also discussed. A comparison with the corresponding equation proposed by DNV-OS-E301 is given. Results show that the formula proposed by Vazquez-Hernandez et al. [Vazquez-Hernandez AO, Ellwanger GB, Sagrilo LVS. Reliability-based comparative study for mooring lines design criteria. Appl Ocean Res 2006; 28(6):398–406] overestimates quite significantly the characteristic resistance of a mooring line segment.     

Mid-Holocene evolution and paleoenvironments of the shoreface–offshore transition, north-eastern Argentina: New evidence based on benthic microfauna

A sedimentary record spanning 5792–5511 cal yr BP and 3188–2854 cal yr BP was recovered at 36° 45′ 43″ S–56 ° 37′ 13″ W, south-west South Atlantic. The sedimentological features and micropaleontological (benthic foraminifera and ostracoda) content were analyzed in order to reconstruct paleoenvironmental conditions. Considerable environmental fluctuations are indicated by all these proxies. Five different stages were distinguished: Stage 1 (ca. 5800–5000 cal yr BP) consists of muddy sand with abundant microfossils. In this interval, species typical for inner marine shelf environments maintained a high abundance. Stage 2 consists of plastic light greenish grey clays barren of microfossils, and probably represents fluvial input from the de la Plata River to the shelf contemporaneous of a lowering of sea level. Stage 3 is composed of brownish yellow sandy silts, and represents increasing marine conditions in the area as reflected by higher faunal diversity and typical foraminifera of inner shelf environments. Stage 4 is made of homogeneous mud, barren of microfossil, which represents a new pulse of fluvial input to the shelf in consequence of a new fall in sea level. The final part of the core (Stage 5) is a coarsening upward sequence, grading from greeny brown clayey sandy silts to coarse shelly sands and represents the modern sedimentation in the area. This interpretation strengthens the stepped model of late-Holocene sea-level fall between 5511–5792 cal yr BP and 2854–3188 cal yr BP in Buenos Aires coast, and agrees with the relative sea-level history previously proposed by some authors from western South Atlantic coasts.     

Weathering of ordinary chondrites from the Atacama Desert,Chile, by Mössbauer spectroscopy and synchrotron radiation X‐ray diffraction

Some terrestrial areas have climatic and geomorphologic features that favor the preservation, and therefore, accumulation of meteorites. The Atacama Desert in Chile is among the most important of such areas, known as DCA. This desert is the driest on Earth, one of the most arid, uninhabitable localities with semiarid, arid, and hyper‐arid conditions. The meteorites studied here were collected from within the DCA of San Juan and Pampa de Mejillones, located, respectively, in the Central Depression and the Coastal Range of the Atacama Desert. ⁵⁷Fe Mössbauer spectroscopy was used for quantitative analysis of the degree of weathering of the meteorites, through the determination of the proportions of the various Fe‐bearing phases and in particular the amount of oxidized iron in terrestrial alteration products. The abundance of ferric ions in weathered chondrites can be related to specific precursor compositions and to the level of terrestrial weathering. The aim of the study was the identification, quantification, and differentiation of the weathering products in the ordinary chondrites found in the San Juan and the Pampa de Mejillones areas of the Atacama Desert. The ⁵⁷Fe Mössbauer spectroscopy study was complemented by synchrotron radiation X‐ray diffraction and magnetic susceptibility measurements. The results allow a clear differentiation of the rate of weathering in meteorite samples collected from the San Juan versus the Pampa de Mejillones areas of the Atacama Desert.     

New doubly-symmetric families of comet-like periodic orbits in the spatial restricted (N + 1)-body problem

For any positive integer N ≥ 2 we prove the existence of a new family of periodic solutions for the spatial restricted (N +1)-body problem. In these solutions the infinitesimal particle is very far from the primaries. They have large inclinations and some symmetries. In fact we extend results of Howison and Meyer (J. Diff. Equ. 163:174–197, 2000) from N = 2 to any positive integer N ≥ 2.      

Vertical Distribution of Meiobenthos in Bathyal Sediments of the Eastern Mediterranean Sea: Relationship with Labile Organic Matter and Bacterial Biomasses

Abstract. Quantitative information on the vertical distribution of meiofaunal abundances and biomass were obtained from samples collected at 3 bathyal stations in the Eastern Mediterranean Sea located at the same depth but characterized by different food supply. Vertical distribution patterns of nieiofauna were investigated in relation to the biochemical composition of the sediment organic matter (proteins, carbohydrates, and lipids) and compared to benthic bacterial standing stocks. No significant relationship between bacteria and meiofauna was found, whereas a significant relationship between protein and lipid concentrations and total meiofauna density was observed. These data suggest that labile organic matter. considered as material readily aVdihbk to benthic consumers, may be an important factor regulating meiofaunal abundance and vertical distribution in deep-sea sediments.     

Element sets for high-order Poincaré mapping of perturbed Keplerian motion

The propagation and Poincaré mapping of perturbed Keplerian motion is a key topic in Celestial Mechanics and Astrodynamics, e.g., to study the stability of orbits or design bounded relative trajectories. The high-order transfer map (HOTM) method enables efficient mapping of perturbed Keplerian orbits using the high-order Taylor expansion of a Poincaré or stroboscopic map. The HOTM is only accurate close to the expansion point and therefore the number of revolutions for which the map is accurate tends to be limited. The proper selection of coordinates is of key importance for improving the performance of the HOTM method. In this paper, we investigate the use of different element sets for expressing the high-order map in order to find the coordinates that perform best in terms of accuracy. A new set of elements is introduced that enables extremely accurate mapping of the state, even for high eccentricities and higher-order zonal perturbations. Finally, the high-order map is shown to be very useful for the determination and study of fixed points and center manifolds of Poincaré maps.