Isotopic Tracing of Trophication Processes over the Last Millennia on Lake Chenghai

Multi-parameter studies (stable isotopes in carbonate and organic matter, pigment,organic carbon and nitrogen contents) from a 660-yr continuous sediment core from Lake Cheng-hai, a closed, eutropic lake in southern China, provide information on lake historical eutrophi-cation. During the last 660 years, great changes have taken place in productivity and eutrophi-cation of Lake Chenghai in response to human activities. In 1690, the productivity of the lakebegan to increase as Lake Chenghai became closed from agriculture in the lake‘‘ s watershed. In 1942, Lake Chenghai evolved to eutrophic state, marked by an increase in organic carbon, ni-trogen, CaC03, pigment contents and obvious negative values of stable isotopes, which is more or less simultaneous with the large-scale population immigration during the period. In 1984, in-tensive human activities induced modern lacustrine productivity and eutrophic level. Human-in-duced trophic changes during the past few decades have affected the Lake Chenghai ecosystem tosuch an extent that it has never experienced before in the last 660 years.     

The Role of Organic Matter During Metal Enrichment in Permian Kupferschiefer of the Rudna Mine,Southwest Poland

The bulk composition of organic matter and saturated and aromatic hydrocarbons extracted from 16 samples collected from two Kuperschiefer profiles in the Rudna mine,Southwest Poland has been analyzed to study the role of organic matter during base metal enrichment in the Kupferschiefer shale.The results indicated that the extract yields and saturated hydrocarbon yields decreased with increasing base metal contents.GC and GC/MS analyses indicated that n -alkanes and alkylated aromatic compounds were depleted and may have served as hydrogen donators for thermochemical sulfate reduction.The enrichment of base metal is closely connected with the destruction of hydrocarbons.     

Geochemical Characteristics of Gold Polymetallic Deposits as Exemplified by the Laozuoshan Deposit,Heilong jiang,China

From the studies of ore deposit geologic settings,sulfur isotopes,lead isotopes,carbon isotopes and oxygen isotopes,fluid inclusions and petrochemistry in this paper,the authors have drawn a conclusion that the ore-forming hydrothermal solutions are the high-temperature magmatic hydrothermal solutions for the gold ore deposit,and at the same time,the involvemety of crustal materials can not be ruled out .It is the first time that the authors have proposed that the Laozuoshan gold-ploymetallic ore deposit in Heilongjiang Province was formed in the calc-alkaline series environment at the margin of an active continent.     

Geology, Geochemistry and Genesis of the Hongshijing Gold Deposit in Ruoqiang,Xinjiang

1IntroductionTheHongshijinggolddepositislocatedinthenorthofLuobupouLakeofRuoqiang ,about 30 0kmsouthwestofHamiCity ,Xinjiang .ItwasdiscoveredbytheSixthGeologicalTeamofXinjiangduringgeo chemicalexploration .TheHongshijinggolddeposit,whichoccursinthegold bearingformationcomposedofMiddleandLateCarboniferousvolcanicandpyroclasticrocks ,isabrittle ductileshearzonetypegolddepositcontrolledbyariftbelt.TheHongshijinggolddepositislocatedinthesouthwestoftheHongshi jing -Maotoushanmineralizationb…     

Gneiss-Water Interaction and Water Evolution During the Early Stages of Dissolution Experiments at Room Temperature

Gneiss-distilled water interaction at room temperature was investigated with batch-reactors to study water-rock reaction and geochemical evolution of the aqueous phase with time. The ion concentrations in water were controlled not only by the dissolution of primary minerals, but also by the precipitation of secondary minerals. The decreasing fraction sizes of gneiss could favor dissolution and precipitation simultaneously. Ca^2 and K^ were the major cations, and HCO3^- was the major anion in water. All the ions except Ca^2 increased in concentration with time. The Ca^2 release from the rock to the aqueous phase was initially much faster than the release of K^ , Na^2 and Mg^2 . But after about 5 - 24 hours, the Ca^2 concentrations in water decreased very slowly with time and became relatively stable. During the experiment, the water varied from the Ca-( K)-HCO3-type water to the K-Ca-HCO3-type water, and then to the K-(Ca, Na)-HCO3-type water. The water-gneiss interaction was dominated by the dissolution of Kfeldspar in the solution. The remaining secondary minerals were mainly kaolinite, illite and K (Mg) -mica.     

Extracting flow structures from tracer data

A method of visualizing structures in closed chaotic flows out of homogenous particle distributions is presented in the example of models of a meandering jet. To this end, the system will be leaked or opened up by defining a region of the flow, so that a particle is considered to be escaped if it leaves this region. By applying this method to an ensemble of nonescaped tracers, we are able to characterize mixing processes by visualizing the converging and stretching filamentations (stable and unstable manifolds) in the flow without using additional mathematical tools. The possibility of applying the algorithm to analyze buoy data, and a comparison with the finite time manifolds are discussed.     

The BEAM-project: prediction and assessment of mixture toxicities in the aquatic environment

Freshwater and marine ecosystems are exposed to various multi-component mixtures of pollutants. Nevertheless, most ecotoxicological research and chemicals regulation focus on hazard and exposure assessment of individual substances only, the problem of chemical mixtures in the environment is ignored to a large extent. In contrast, the assessment of combination effects has a long tradition in pharmacology, where mixtures of chemicals are specifically designed to develop new products, e.g. human and veterinary drugs or agricultural and non-agricultural pesticides. In this area, two concepts are frequently used and are thought to describe fundamental relationships between single substance and mixture effects: Independent Action (Response Addition) and Concentration Addition. The question, to what extent these concepts may also be applied in an ecotoxicological and regulatory context may be considered a research topic of major importance, as the concepts would allow to make use of already existing single substance toxicity data for the predictive assessment of mixture toxicities. Two critical knowledge gaps are identified: (a) There is a lack of environmental realism, as a huge part of our current knowledge about the applicability of the concepts is restricted to artificial situations with respect to mixture composition or biological effect assessment. (b) The knowledge on what exactly is needed for using the concepts as tools for the predictive mixture toxicity assessment is insufficient. Both gaps seriously hamper the necessary, scientifically sound consideration of mixture toxicities in a regulatory context.In this paper, the two concepts will be briefly introduced, the necessity of considering the toxicities of chemical mixtures in the environment will be demonstrated and the applicability of Independent Action and Concentration Addition as tools for the prediction and assessment of mixture toxicities will be discussed. An overview of the specific aims and approaches of the BEAM project to fill in the identified knowledge gaps is given and first results are outlined.     

New unspiked K–Ar ages of volcanic rocks of the central and western sector of the Aeolian Islands: reconstruction of the volcanic stages

A geochronological study of the Filicudi, Salina, Lipari and Vulcano Islands (Aeolian Archipelago) using the unspiked potassium–argon technique provides new age data which, combined with stratigraphic correlation, better constrain the temporal evolution of volcanism. The unspiked K–Ar age of the oldest exposed lavas on Filicudi, 219±5 ka, is significantly younger than the previous estimation of 1.02 Ma. In the general context of Aeolian volcanism, this new date suggests that the volcanism of the western sector of the Aeolian Archipelago is younger than previously thought. Geochronological data point out on the rapid transition from calc–alkaline to potassic volcanism. The distribution of the K–Ar ages within the Salina–Lipari–Vulcano group shows that the volcanism started on Lipari and propagated over time northward on Salina and southward on Vulcano. Geochronological and geophysical data suggest that the onset of volcanism in the central sector of the Aeolian Arc may be due to a mantle upwelling structure located below Lipari. A change in the style of the eruptions occurred in the Salina–Lipari–Vulcano system at about 100 ka from the present. Low-energy magmatic eruptions occurred between 188 and about 100 ka. From about 100 ka to the present, higher-energy eruptions and low-energy events due to magma–water interaction also occurred. This change in the style of activity, together with the appearance of evolved products (i.e. rhyolites) during the last 50 ka, is consistent with the formation of magmatic reservoirs located at shallower depth with respect to those of the 188–100-ka period. The new geochronological data and available petrological models reveal that a change in the deep source of the primary magmas occurred in a relatively short time interval.     

Contemporary crustal deformation of the Chinese continent and tectonic block model

We obtain the preliminary result of crustal deformation velocity field for the Chinese continent by analyzing GPS data from the Crustal Motion Observation Network of China (CMONOC), particularly the data from the regional networks of CMONOC observed in 1999 and 2001. We delineate 9 technically active blocks and 2 broadly distributed deformation zones out of a dense GPS velocity field, and derive block motion Euler poles for the blocks and their relative motion rates. Our result reveals that there are 3 categories of deformation patterns in the Chinese continent. The first category, associated with the interior of the Tibetan Plateau and the Tianshan orogenic belt, shows broadly distributed deformation within the regions. The third category, associated with the Tarim Basin and the region east of the north-south seismic belt of China, shows block-like motion, with deformation accommodated along the block boundaries only. The second category, mainly associated with the borderland of the Tibetan Plateau, such as the Qaidam, Qilian, Xining (in eastern Qinghai), and the Diamond-shaped (in western Sichuan and Yunnan) blocks, has the deformation pattern between the first and the third, i.e. these regions appear to deform block-like, but with smaller sizes and less strength for the blocks. Based on the analysis of the lithospheric structures and the deformation patterns of the regions above, we come to the inference that the deformation modes of the Chinese continental crust are mainly controlled by the crustal structure. The crust of the eastern China and the Tarim Basin is mechanically strong, and its deformation takes the form of relative motion between rigid blocks. On the other hand, the northward indentation of the Indian plate into the Asia continent has created the uplift of the Tibetan Plateau and the Tianshan Mountains, thickened their crust, and raised the temperature in the crust. The lower crust thus has become ductile, evidenced in low seismic velocity and high electric conductivity observed. The brittle part of the crust, driven by the visco-plastic flow of the lower crust, deforms extensively at all scales. The regions of the second category located at the borderland of the Tibetan Plateau are at the transition zone between the regions of the first and the third categories in terms of the crustal structure. Driven by the lateral boundary forces, their deformation style is also between the two, in the form of block motion and deformation with smaller blocks and less internal strength.