Description and interpretation of the composition of fluid and alteration mineralogy in the geothermal system,at Svartsengi,Iceland

The bulk composition and mineralogy of hydrothermally altered tholeiite, along with the composition and speciation of fluid, have been determined for a well-defined alteration zone at 240°C and 110 bars at Svartsengi, Iceland. Mass balances between the geothermal fluid and altered tholeiite, relative to a seawater/fresh water mixture and unaltered tholeiite, indicate the overall reaction per 1000 cm³ is: 1325 gm plagioclase + 1228 gm pyroxene + 215 gm oxide-minerals break down to form 685 gm chlorite + 636 gm albite + 441 gm quartz + 249 gm epidote + 266 gm calcite + 201 gm oxide-minerals + 15 gm pyrite, requiring an influx of 123 gm CO₂, 10 gm H₂S and 4 gm Na₂O and a release of 57 gm SiO₂, 35 gm FeO, 21 gm CaO, 8 gm MgO and 4 gm K₂O.Principal reactions, deduced from textural evidence, include Na-Ca exchange in plagioclase, precipitation of quartz, calcite and anhydrite, and formation of chlorite and epidote by reactions between groundmass minerals and fluid.Thermodynamic analyses of authigenic minerals and downhole fluid indicate that the fluid maintains a state close to equilibrium with the secondary mineral phases chlorite, epidote, albite, quartz, calcite, prehnite, anhydrite, pyrite and magnetite, whereas remnant primary labradorite and augite are out of equilibrium with the fluid.Water/rock ratios for the system are determined under a variety of assumptions. However, the open nature of the system makes comparisons with experimental and theoretical closed system studies ambiguous.     

Stratigraphic framework of gas accumulations in the Ría de Pontevedra (NW Spain)

Knowledge of marine geological environments in which shallow gas is accumulating is becoming increasingly important in global studies of climate change because a measurable proportion of the total methane source comes from continental margins. Previous studies have revealed that coastal environments represent important geological environments where microbial methane is being generated, is accumulating, and is being released. In the Ría de Pontevedra, at least 4.5 km² of seafloor in the innermost part of the ría is underlain by sediments containing natural gas. Seismic interpretation contributes new findings for the definition of periods and geological environments in which the gas could have been generated, and is accumulating and released in the Ría de Pontevedra. Groundtruthing the seismic data (facies, environments) makes it possible to identify favourable geological environments for gas generation in the sedimentary infill of the Ría de Pontevedra. Sequence stratigraphy based on high-resolution seismic profiles and post-Last Glacial Maximum sea-level records makes it possible to establish the stratigraphic architecture of the ría and to define the periods in which gas could have been generated. The results of this study show that the sedimentary infill is composed of a fifth-order sequence developed since the Last Glacial Maximum. Within this sequence, gas appears to have accumulated in the Holocene deposits associated with the latest transgressive and highstand system tracts. Seismic analysis shows that gas could have been generated in different geological environments in the Ría de Pontevedra. If coastal environments at times of lower sea level were similar to those of the present, organic-rich mud deposits (deposited mainly in lakes, estuaries and floodplains) could have survived transgression and remained buried as potential gas sources in the inner part of the ría.     

Geodynamic Evolution of the Eastern Segment of the Azores-Gibraltar Zone: The Gorringe Bank and the Gulf of Cadiz Region

Detailed structural interpretation of the recently acquired deep seismic multichannel profiles along the Iberian Atlantic Margins (IAM Project) provides new results on the geodynamic evolution of the eastern part of the Azores-Gibraltar plate boundary. Thrusting and folding of the oceanic basement and of Mesozoic and Cenozoic sedimentary cover of the Gorringe Bank region are consistent with the N–S convergence of Iberia and Africa. Compressive structures in the Gorringe Bank region are spread over a wide area. Deformation under compression took place mainly in Tertiary times, as is evidenced by a basal unconformity and several discontinuities in Tertiary sediments, although some deformation has also been recorded in Quaternary sediments. The compressive structures in the Gulf of Cadiz are E–W oriented thrusts, folds and related diapiric structures. N–S oriented transpressive deformation is likely to occur in the western Portuguese platform. There is no continuity of structures from the oceanic to the continental domain, suggesting that deformation transfers from one side to the other through a transcurrent fault zone. The fault contact between the two domains is located in the ocean-continent transition zone.     

Impacts of maintenance channel dredging in a northern Adriatic coastal lagoon. I: Effects on sediment properties,contamination and toxicity

Conservation and management of coastal lagoons envisage direct human intervention. To prevent siltation and to preserve the hydrodynamics features of the lagoon system, the inner channels undergo regular maintenance dredging.     

Conspicuous sediment structures in fossil beach deposits (southern Tenerife, Canary Islands, Spain): paleoliquefaction features versus biogenic origin

Tubular-shaped concretions and concretionary dykes occur in Holocene fossil beach deposits between the township of El Médano and Punta Roja in southern Tenerife, Canary Islands. These sediment structures have been interpreted either as the result of (a) the interaction between hot ignimbrites that overflowed wet beaches; (b) fast accumulation of beach sands on hot and degassing ignimbrites; (c) paleoliquefaction caused by an earthquake (seismites). Based on the interpretation as seismites, an intense paleoearthquake with a moment magnitude of M = 6.8 was proposed to be responsible for the generation of the paleoliquefaction structures. However, we here reinterpret the sedimentary structures in question using the general criteria diagnostic for rhizocretions and root tubules with respect to their orientation, size, branching system, and style of cementation and, thus, consider them, to be of biogenic origin.     

Diel and seasonal variability in the fish community structure of a mud‐bottom estuarine habitat in the Gulf of Mexico

We hypothesized that temporal variation in fish species composition and community structure in a low complexity habitat in the Pueblo Viejo Lagoon, Mexico, is influenced by diel light/dark cycles and tidal stage, and by seasonal changes in salinity and temperature. We collected a total of 17,661 individuals during 2‐h interval sampling over six bi‐monthly 24‐h sampling cycles representing 53 species, of which 11 (～20%) were previously unknown in the system. Diel variation indicated that significantly higher numbers of individuals and species were caught at night, whereas diversity and evenness were higher during the day. Species richness was significantly higher in July and January, whereas diversity and evenness peaked around May; both were correlated with temperature. Diel variation in species composition was influenced primarily by the light/dark cycle. Cluster analyses of each diel cycle separated fish assemblages from midday samples from those of nocturnal samples, separated by an extended wide transition period as fish moved at dawn and during the late afternoon/dusk. Significant shifts (as determined by MANOVA) in assemblage structure occurred between months. Canonical correspondence analysis showed that temperature and day/night effects were the most important environmental variables structuring the fish community. This constrained ordination also defined species with specific habitat preferences as follows: (i) diurnal, warm temperature species (mainly planktivores) (Brevoortia gunteri, Cetengraulis edentulus, Diapterus auratus, and Membras martinica); (ii) nocturnal, warm temperature species (mainly predators) (Citharichthys spilopterus, Cathorops melanopus, and Bairdiella spp.); and (iii) low temperature, diurnal species (Brevoortia patronus and Mugil curema) or those with twilight and nocturnal distributions (Anchoa mitchilli, the most numerically abundant species). Our results indicate that diel and seasonal changes in fish community structure were mainly related to day/night cycles and temperature regimes.     

The role of basement inheritance faults in the recent fracture system of the inner shelf around Alboran Island,Western Mediterranean

Fractures associated with volcanic rock outcrops on the inner shelf of Alboran Island, Western Mediterranean, were mapped on the basis of a side-scan sonar mosaic. Absolute maximum fracture orientation frequency is NW–SE to NNW–SSE, with several sub-maxima oriented NNE–SSW, NE–SW and ENE–WSW. The origin of the main fracture systems in Neogene and Quaternary rocks of the Alboran Basin (south Spain) appears to be controlled by older structures, namely NE–SW and WNW–ESE to NW–SE faults which cross-cut the basement. These faults, pre-Tortonian in origin, have been reactivated since the early Neogene in the form of strike-slip and extensional movements linked to the recent stress field in this area. Fracture analysis of volcanic outcrops on the inner continental shelf of Alboran Island suggests that the shelf has been deformed into a narrow shear zone limited by two NE–SW-trending, sub-parallel high-angle faults, the main orientation and density of which have been influenced by previous WNW–ESE to NW–SE basement fractures.     

Diagnosis of trace metal contamination in sediments: the example of Ensenada and El Sauzal, two harbors in Baja California, Mexico

Total metal concentrations in sediments from within Ensenada and El Sauzal Harbors are generally higher than at the mouths. Grain-size analyses suggested that this enrichment could be due to the presence of fine-grained sediments in the inner part of the harbors rather than to anthropogenic perturbations. The (Me/Al)(sample) ratios for Pb, Co, Ni and Fe were significantly higher for Ensenada Harbor relative to El Sauzal Harbor, whereas the ratios for Cd, Mn, Zn and Cu were statistically equivalent for both harbors. Calculated enrichment factors [EF(Me)=(Me/Al)(sample)/(Me/Al)(shale)] indicated that the metals showing slight enrichment were those associated with anthropogenic contamination (Pb, Zn), or probably related to primary productivity in the water column (Cd, Co). The levels of most of the metals were not greatly enriched, a consideration that is of the utmost importance when contamination issues are at stake.     

Habitat continuity effects on gradients of fish biomass across marine protected area boundaries

Marine protected areas (MPAs) could be useful as fisheries management tools for the exportation of pelagic eggs, larvae and adult fish. A decreasing gradient of fish biomass across MPAs boundary may indicate export. We determine whether gradients of decreasing biomass of fish assemblage occurred in Tabarca Marine Reserve over two habitats with different continuity across the boundaries, to test if the patchy nature of the marine environment might act as a barrier for the fish export. In general, significant decreasing gradients in total fish biomass and biomass of some species were observed on P. oceanica and rocky substrates, independently of their different continuity through the reserve boundaries. Changes in the multivariate structure of the fish assemblage were correlated with the distance from integral reserve. All of these results support the hypothesis that the exportation of adult fish from Tabarca Marine Reserve occurs, and this process may influence the surrounding fished areas.     

Sediment resuspension events induced by the wake wash of deep-draft vessels

Hydrodynamics and sediment resuspension events, induced at the shoreline by a deep-draft vessel passing nearby, are described. Measurements (pressure, currents and turbidity) were obtained at 4 Hz, on a lower beach ~50 m from a channel where large car ferries operate in Wootton Creek, Isle of Wight. The study focuses on a representative 8-min 32-s-long record, during which two large vessels passed the channel section. At the shore, the passage of each vessel induced a long-period water-level drawdown, followed by a water-level oscillation (seiche) of similar period, and the short-period waves of the wake. Both drawdowns were the main constituents of the prevailing wave pattern. The second drawdown was the largest in amplitude, in response to a higher speed of the ferry, and the influence of the seiche which had been activated during the preceding event. Two successive peaks of turbidity were observed shortly after this drawdown. Analyses of current velocity and direction indicate that the sediments resuspended originated from the shallower upper beach. Anthropogenically induced erosion of the foreshore is predicted at Wootton Creek.