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701.
Amino acids comprise from 15 to 36% by weight of humic substances from carbonate and non-carbonate sediments. Humic and fulvic acids extracted from carbonate sediments are characterized by an amino acid composition consisting primarily of the acidic amino acids, aspartic and glutamic acid. Humic substances from non-carbonate sediments have a distinctly different amino acid composition consisting primarily of glycine and alanine. Amino acid analyses of various molecular weight fractions of fulvic acids extracted from carbonates show that lower molecular weight fractions have appreciably higher relative abundances of the acidic amino acids compared to higher molecular weight fractions. Based on typical values for carboxyl group content in humic substances, acidic amino acids may be a significant contributor of these functional groups. Carbonate surfaces appear to selectively adsorb aspartic acid-enriched organic matter while non-carbonates do not have this property. 相似文献
702.
J. W. LAVELLE D. J. P. SWIFT P. E. GADD W. L. STUBBLEFIELD F. N. CASE† H. R. BRASHEAR† K. W. HAFF† 《Sedimentology》1978,25(6):823-842
Both spring-summer and fall-winter sand transport have been observed on the Long Island, New York, inner shelf at water depths of 20-22 m using a radio-isotope sand tracer system. The extent of dispersal of the tagged, fine sand was measured at 3 week intervals in two 70 day experiments. In the late spring and early summer, movement was primarily diffusive in nature, extending 100 m around the line of tracer injection, while late fall-winter patterns had strong advective features, including an ellipsoidal outline extending approximately 1500 m westward of the injection points after the passage of several storms with strong northeasterly winds. Near-bottom current observations made with Savonius rotor sensors identify the event responsible for the bulk of the transport over the 135 day observation period as a storm flow of 2 days duration. Tracer and current observations together suggest that westward winter storm flow along the Long Island shelf is the major mechanism of sand transport at these depths on a yearly time scale. A least-squares fit of several of the observed winter patterns with a plume model yields average sediment mass flux lower bounds of 3.2 × 10?3 gm/cm/sec and 1.7 × 10?1 gm/cm/sec for ‘typical’ and extreme winter storm activity. 相似文献
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707.
Absolute spectrophotometric measurements of the Swan bands of two comets have been compared with computed synthetic spectra using modern Franck-Condon and Hönl-London factors, and varying rotational, vibrational, and electronic excitation temperatures. Rotational and vibrational temperatures were obtained for the comets. Although the electronic excitation temperature and the molecular column density cannot be separated, a relationship is found between these two quantities. A review is made of recent determinations of column densities for CN in comets. 相似文献
708.
A comparison is made between the plane-parallel approximation and the more realistic spherical shell approximation for the radiance reflected from a planetary atmosphere. In this paper we have considered a planet of radius 6371 km (the Earth) with a homogeneous, conservative, Rayleigh scattering atmosphere extending to a height of 100 km. We have found significant departures from the plane-parallel approximation. Radiance versus height distributions for both single and multiple scattering are presented. Results are presented for the fractional radiance from altitudes in the atmosphere which contribute to the total unidirectional reflected radiance at the top of the atmosphere. We have referred to this as the radiance versus height distribution in the sequel. These data will be very useful for both remote sensing applications and planetary spectroscopy. We have also found that gross violations of the principle of reciprocity do occur in the spherical shell approximation. 相似文献
709.
James B. Pollack Donald W. Strecker Fred C. Witteborn Edwin F. Erickson Betty J. Baldwin 《Icarus》1978,34(1):28-45
We have measured the shape and absolute value of Venus' reflectivity spectrum in the 1.2-to 4.0-μm spectral region with a circular variable filter wheel spectrometer having a spectral resolution of 1.5%. The instrument package was mounted on the 91-cm telescope of NASA Ames Kuiper Airborne Observatory, and the measurements were obtained at an altitude of about 41,000 feet, when Venus had a phase angle of 86°. Comparing these spectra with synthetic spectra generated with a multiple-scattering computer code, we infer a number of properties of the Venus clouds. We obtain strong confirmatory evidence that the clouds are made of a water solution of sulfuric acid in their top unit optical depth and find that the clouds are made of this material down to an optical depth of at least 25. In addition, we determine that the acid concentration is 84 ± 2% H2SO4 by weight in the top unit optical depth, that the total optical depth of the clouds is 37.5 ± 12.5, and that the cross-sectional weighted mean particle radius lies between 0.5 and 1.4 μm in the top unit optical depth of the clouds. These results have been combined with a recent determination of the location of the clouds' bottom boundary [Marov et al., Cosmic Res.14, 637–642 (1976)] to infer additional properties about Venus' atmosphere. We find that the average volume mixing ratio of H2SO4 and H2O contained in the cloud material both equal approximately 2× 10?6. Employing vapor pressure arguments, we show that the acid concentration equals 84 ± 6% at the cloud bottom and that the water vapor mixing ratio beneath the clouds lies between 6 × 10?4 and 10?2. 相似文献
710.
Observations of the April 8, 1976 occultation of ? Gem by Mars made at the Agassiz Station of the Harvard College Observatory have been analyzed to yield temperature profiles of the Martian atmosphere for number densities between 1013 and 1015 cm?3. Pronounced wavelike structure is evident in both immersion and emersion profiles, with a peak-tto-peak variation of up to 50°K and a vertical scale of 20 km. 相似文献