Fractionation of grain size in terrestrial sediment routing systems

Sediment is fractionated by size during its cascade from source to sink in sediment routing systems. It is anticipated, therefore, that the grain size distribution of sediment will undergo down‐system changes as a result of fluvial sorting processes and selective deposition. We assess this hypothesis by comparing grain size statistical properties of samples from within the erosional source region with those that have undergone different amounts of transport. A truncated Pareto distribution describes well the coarser half of the clast size distribution of regolith, coarse channel bed sediment and proximal debris flows (particularly their levees), as well as the coarser half of the clast size distribution of gravels that have undergone considerable amounts of transport in rivers. The Pareto shape parameter a evolves in response to mobilization, sediment transport and, importantly, the selective extraction of particles from the surface flow to build underlying stratigraphy. A goodness of fit statistic, the Kolmogorov–Smirnov vertical difference, illustrates the closeness of the observed clast size distributions to the Pareto, Weibull and log‐normal models as a function of distance from the depositional apex. The goodness of fit of the particle size distribution of regolith varies with bedrock geology. Bedload sediment at catchment outlets is fitted well by the log‐normal and truncated Pareto models, whereas the exponential Weibull model provides a less good fit. In the Eocene Escanilla palaeo‐sediment routing system of the south‐central Pyrenees, the log‐normal and truncated Pareto models provide excellent fits for distances of up to 80 km from the depositional apex, whereas the Weibull fit progressively worsens with increasing transport distance. A similar trend is found in the Miocene–Pliocene gravels of the Nebraskan Great Plains over a distance of >300 km. Despite the large fractionation in mean grain size and gravel percentage from source region to depositional sink, particle size distributions therefore appear to maintain log‐normality over a wide range of transport distance. Use of statistical models enables down‐system fractionation of sediment released from source regions to be better understood and predicted and is a potentially valuable tool in source‐to‐sink approaches to basin analysis.     

MaxEnt power spectrum estimation using the Fourier transform for irregularly sampled data applied to a record of stellar luminosity

The principle of maximum entropy is applied to the spectral analysis of a data signal with general variance matrix and containing gaps in the record. The role of the entropic regularizer is to prevent one from overestimating structure in the spectrum when faced with imperfect data. Several arguments are presented suggesting that the arbitrary prefactor should not be introduced to the entropy term. The introduction of that factor is not required when a continuous Poisson distribution is used for the amplitude coefficients. We compare the formalism for when the variance of the data is known explicitly to that for when the variance is known only to lie in some finite range. The result of including the entropic measure factor is to suggest a spectrum consistent with the variance of the data which has less structure than that given by the forward transform. An application of the methodology to example data is demonstrated.     

Evidence for zonally-trapped propagating waves in the eastern atlantic from satellite sea surface temperature observations

It has been hypothesized (Moore et al., 1978; O'Brien et al., 1978), that equatorial upwelling and subsequent coastal upwelling on the eastern boundary of the Atlantic Ocean are the result of eastward propagating equatorially trapped Kelvin waves in the Atlantic. Concurrent satellite and ship sea surface temperature observations taken during the GATE experiment permit validation of the satellite data as well as relating sea surface temperature (SST) variability to the local current dynamics. A method based on cross-correlations and cross-spectra of the SST field at various locations is utilized to test the Kelvin wave hypothesis. Significant periodic variation of time lags in the SST variability in the eastern Atlantic is observed by the spectral techniques. Satellite data for the 1974 summer show periodic variability which fits either eastward or westward propagating waves with 1 m s^-1 phase speed, i.e., SST supports the quasi-continuous presence of Kelvin or Yanai waves. We find no evidence for a seasonally solitary eastward propagating signal in the eastern Atlantic from SST.     

A dynamical model of the corona

The hydrodynamic equations for an ideal, inviscid, fully ionized hydrogen gas in a gravitational, but not magnetic, field are solved by an explicit Lax-Wendroff two-step technique using a one-dimensional slab symmetry. Radiation and thermal conductivity are included. The model spans 100000 km starting from the chromosphere-corona transition region. An initially isothermal gas is seen to evolve coronal properties in 4000 s, by which time it settles into dynamic equilibrium characterized by a 2000 km transition region, a temperature maximum of 1.6 × 10⁶ K at a height of 60000 km, and a solar wind mass flux of 10^-9 g cm^-2 s^-1.     

Dilemmas of development in Oceania: the political economy of the Tongan agro-export sector

This article critically engages with the recent diffusion of the orthodox development model in Oceania and highlights some evolving dilemmas. In particular, it explores the social, economic and ecological tensions arising from economic reforms that are exacerbating the fragility of already vulnerable nation-states and communities. In order to illustrate its arguments, a case study of the impacts of agro-export growth in Tonga is presented. Attention is drawn to the socially inequitable and ecologically unsustainable outcomes of rapid growth in this sector. In analyzing the political economy of the squash pumpkin sector, the authors point to the important role that culture plays in mediating and conditioning development outcomes. Reflecting on the Tongan case, it is argued that to better understand the implications of orthodox developmental reform in the region, research must seek to more explicitly incorporate distributional and ethical analysis.     

Spatially resolved methane band photometry of Saturn: I. Absolute reflectivity and center-to-limb variations in the 6190-, 7250-, and 8900-Å bands

We present spatially resolved measurements of Saturn's absolute reflectivity in methane bands at 6190, 7250, and 8900 Å and in nearby continuum regions. Images were obtained through narrow-band interference filters with a 500 × 500-pixel charge-coupled device. Band/continuum ratios were measured to high accuracy by referencing to the ring brightness in each image. Several data processing techniques enhanced the quality of the observations. These are the use of the ring symmetry to find center position and orientation, accurate subtraction of ring light, and constrained image deconvolution. Uncertainty in the continuum absolute reflectivity is ±10%. Uncertainties in band/continuum ratios are from one to several percent. The Equatorial Zone was much brighter than any other latitude in the strong 8900 band image. Northern mid-latitudes were brighter than southern mid-latitudes. The latter observation indicates fewer high-altitude aerosols in the south, a possible result of atmospheric dynamics or seasonal sublimation of NH₃ crystals. The data are tabulated and presented in a form suitable for quantitative scattering model analyses.     

Titan's atmospheric chemistry: Photolysis of gas mixtures containing hydrogen cyanide and carbon monoxide at 185 and 254 nm

The formation of organic compounds in the atmosphere of Titan is an ongoing process of the generation of complex organics from the simplest hydrocarbon, methane. Solar radiation and magnetosphere electrons are the main energy sources that drive the reactions in Titan's atmosphere. Since energy from solar radiation is 200 times greater than that from magnetosphere electrons, we have investigated the products formed by the action of UV radiation (185 and 254 nm) on a mixture of gases containing nitrogen, methane, hydrogen, acetylene, ethylene, and cyanoacetylene, the basic gas mixture (BGM) that simulates aspects of Titan's atmosphere using a flow reactor [Tran, B.N., Ferris, J.P., Chera, J.J., 2003a. Icarus 162, 114-124; Tran, B.N., Joseph, J.C., Force, M., Briggs, R.G., Vuitton, V., Ferris, J.P., 2005. Icarus 177, 106-115]. The present research extends these studies by the addition of carbon monoxide and hydrogen cyanide to the BGM. Quantum yields for the loss of reactants and the formation of volatile products were determined and compared with those measured in the absence of the hydrogen cyanide and carbon monoxide. The GCMS analyses of the volatile photolysis products from the BGM, with added hydrogen cyanide, had a composition similar to that of the BGM while the photolysis products of the BGM with added carbon monoxide contained many oxygenated compounds. The infrared spectrum of the corresponding solid product revealed the absorption band of a ketone group, which was probably formed from the reaction of carbon monoxide with the free radicals generated by photolysis of acetylene and ethylene. Of particular interest was the observation that the addition of HCN to the gas mixture only resulted in a very small change in the C/N ratio and in the intensity of the CN frequency at 2210 cm⁻¹ in the infrared spectrum suggesting that little HCN is incorporated into the haze analog. The C/N ratio of the haze analogs was found to be in the 10-12 range. The UV spectra of the solid products formed when HCN or CO added to the BGM is similar to the UV absorption formed from the BGM alone. This result is consistent with absence of additional UV chromophores to the solid product when these mixtures are photolyzed. The following photoproducts, which were not starting materials in our photochemical studies, have been observed on Titan: acetonitrile, benzene, diacetylene, ethane, propene, propane, and propyne.     

Paleoclimatic changes in southern Africa during the intensification of Northern Hemisphere glaciation: evidence from ODP Leg 175 Site 1085

Pliocene age sediments from Ocean Drilling Program Leg 175, Site 1085-A and B in the Cape Basin were analyzed to investigate the impact of the intensification of Northern Hemisphere glaciation (INHG) on the South Atlantic Benguela Current system from 4 to 2 Ma. Proxies for productivity (concentrations and mass accumulation rates of total organic carbon, carbon to nitrogen ratios, percent calcium carbonate, and percent biogenic silica) as well as weight percent sand (a proxy for preservation or winnowing) peak at 3.2, 3.0, 2.4, and 2.25 Ma. Normative calculations of allied trace and major elemental determinations indicate synchronous increases in productivity peaks, as well as high concentrations and accumulations of terrigenous sediments. Coeval increases in hemipelagic sedimentation and productivity indicators could be the result of enhanced eolian sedimentation resulting from strengthened winds, leading to elevated rates of upwelling and enhanced productivity. However, rapid burial, as indicated by high sedimentation rates, could also enhance preservation. The very high concentrations (>30%) and accumulations (up to 60 g/cm²/kyr) limit the likelihood that eolian sedimentation was the only transport mechanism, invoking an additional fluvial source. Rapid burial by either eolian or fluvial transport links these intervals of enhanced preservation and productivity with continental climate changes resulting from (1) increased winds and/or dust availability due to higher aridity in the Namibia/northern South Africa region; (2) lowered sea-level related to increased ice volume; (3) increased sediment load due to wetter conditions in the continental interior; or (4) some combination. Peaks at 3.2, 2.4 and 2.25 Ma are coincident with maximum precession, suggesting a link between hemipelagic sedimentation and enhanced monsoonal circulation over southern Africa. The Site 1085 sedimentary record during the INHG seems to be controlled by low-latitude processes linked to precession rather than hig-latitude processes.