Use of Pitzer's equations to determine the media effect on the formation of lead chloro complexes

The spectrophotometric measurements of chloro complexes of lead in aqueous HCl, NaCl, MgCl₂ and CaCl₂ solutions at 25°C have been analyzed using Pitzer's specific interaction equations. Parameters for activity coefficients of the complexes PbCl⁺, PbCl₂⁰ and PbCl₃^? have been determined for the various media. Values of $\text{K}{}_1\text{= 30.0 ± 0.6}$, $\text{K}{}_2\text{= 106.7 ± 2.1}$ and $\text{K}{}_3\text{= 73.0 ± 1.5}$ were obtained for the cumulative formation constants. [$\text{Pb}{}^{\mathrm{2+}}\text{+ nCl}{}^{\mathrm{?}}\text{→ PbCl}{}_{\mathrm{n}}{}^{\mathrm{2?n}}\text{)}$]. These values are in reasonable agreement with literature data. The Pitzer parameters for the PbCl ion pairs in various media were used to calculate the speciation of Pb²⁺ in an artificial seawater solution.     

GIS diffusion in Uganda

Despite myriad studies having been carried out on the diffusion of geographical information systems (GIS) technology, only a limited number have been done within the context of developing countries. This paper addresses the research question, how did the diffusion of GIS technology occur in Uganda? Mixed methods were used for data collection, and analysis was performed using a theoretical framework called the diffusion of innovations (DOI). The results of the study showed that the adoption of GIS by institutions in Uganda occurred in a classic diffusion pattern consistent with diffusion theory. Adoption of GIS was promoted by its relative advantage over, and compatibility with, existing technologies. It was characterized by both heterophilous and homophilous communication channels, and influenced by change agents and champions. Its rate of adoption followed an S-shaped diffusion curve, and was hampered by bureaucracy, and patronage-based societal norms. This study makes a contribution to literature on GIS diffusion in developing countries.     

Dust injection into the Martian atmosphere

A mechanism for initiating global dust storms on Mars is proposed in which the diurnal variation of surface temperature results in the desorption of adsorbed CO₂, which under certain conditions can inject large amounts of fine (1–10 μm) dust into the atmosphere.     

The Spaces of Conservation and Development around Lake Nakuru National Park,Kenya

Geographically or sociologically defined resource management units, such as buffer zones or community resource management territories, seek to harmonize local land–use practices with protected–area management objectives. The geographically restricted nature of these models often results in simplistic representations of society–nature relations over time and space. Conservation areas are misrepresented as ecologically and socially homogeneous, as well as politically neutral. This study examines the limits of a spatially defined conservation and development project designed around the physical geographical unit of the watershed at Lake Nakuru National Park, Kenya. It argues that politically motivated violence that has plagued the area since the early 1990s has severely undermined the suitability of such narrowly defined conservation territories. Specifically, the case study points to the permeability of the Lake Nakuru watershed to national and regional political forces that ultimately constrain participation in conservation activities. The spaces of conservation and development must be enlarged to include these extralocal arenas and processes if environmental problems are to be effectively addressed.     

Aging in Activity Spaces: How Does Individual Accessibility Compare across Age Cohorts?

The proportion of individuals age sixty-five and over is growing at an astronomical rate in the United States, and some estimate that this demographic age group will double by the year 2025. Older adults and adults nearing retirement age tend to reside in suburban neighborhoods and rely heavily on personal vehicles. This study uses travel diary data on automobile trips to construct activity spaces to explore whether or not travel patterns across age groups result in differential access to particular goods and services in the Orlando Metropolitan Statistical Area (MSA). Using an approach based on time geographic density estimation, this research identifies activity spaces across different age cohorts to identify differences in the automobility of different age groups. Results indicate that the geographic dispersion of activities with the Orlando MSA currently favors younger adults. Adults age fifty to sixty-four had the lowest accessibility scores compared to other age cohorts. If this preretirement group has poor access now, holding other effects constant, their access might only get worse as they get older and stop commuting. Transportation is an important consideration in planning for aging populations, and analyzing differences in how older adults travel compared to their younger counterparts can offer insight into the diverse needs of this group. Key Words: accessibility, aging populations, mobility, time geography, transportation.     

A Synoptic Climatology of Severe Storms in Virginia*

A synoptic climatology is developed for Virginia using 21 years of late spring and summer surface and upper air observations. The climatology is produced by applying a combination of principal components analysis and cluster analysis such that each day is classified into one of a distinct number of synoptic situations. Days on which at least one severe storm occurred in Virginia are merged with the synoptic climatology. A majority of severe storms are associated with one synoptic situation distinguished by moderate instability and a high moisture content.