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911.
Paul Duuring Stephen M. Rowins Bradley S. M. McKinley Jenni M. Dickinson Larry J. Diakow Young-Seog Kim Robert A. Creaser 《Mineralium Deposita》2009,44(4):463-496
The Toodoggone district comprises Upper Triassic to Lower Jurassic Hazelton Group Toodoggone Formation volcanic and sedimentary
rocks, which unconformably overlie submarine island-arc volcanic and sedimentary rocks of the Lower Permian Asitka Group and
Middle Triassic Takla Group, some of which are intruded by Upper Triassic to Lower Jurassic plutons and dikes of the Black
Lake suite. Although plutonism occurred episodically from ca. 218 to 191 Ma, the largest porphyry Cu–Au ± Mo systems formed
from ca. 202 to 197 Ma, with minor mineralization occurring from ca. 197 to 194 Ma. Porphyry-style mineralization is hosted
by small-volume (<1 km3), single-phase, porphyritic igneous stocks or dikes that have high-K calc-alkaline compositions and are comparable with volcanic-arc
granites. The Fin porphyry Cu–Au–Mo deposit is anomalous in that it is 16 m.y. older than any other porphyry Cu–Au ± Mo occurrence
in the district and has lower REEs. All porphyry systems are spatially restricted to exposed Asitka and Takla Group basement
rocks, and rarely, the lowest member of the Hazelton Group (i.e., the ca. 201 Ma Duncan Member). The basement rocks to intrusions
are best exposed in the southern half of the district, where high rates of erosion and uplift have resulted in their preferential
exposure. In contrast, low- and high-sulfidation epithermal systems are more numerous in the northern half of the district,
where the overlying Hazelton Group rocks dominate exposures. Cogenetic porphyry systems might also exist in the northern areas;
however, if they are present, they are likely to be buried deeply beneath Hazelton Group rocks. High-sulfidation epithermal
systems formed at ca. 201 to 182 Ma, whereas low-sulfidation systems were active at ca. 192 to 162 Ma. Amongst the studied
epithermal systems, the Baker low-sulfidation epithermal deposit displays the strongest demonstrable genetic link with magmatic
fluids; fluid inclusion studies demonstrate that its ore fluids were hot (>468°C), saline, and deposited metals at deep crustal
depths (>2 km). Sulfur, C, O, and Pb isotope data confirm the involvement of a magmatic fluid, but also suggest that the ore
fluid interacted with Asitka and Takla Group country rocks prior to metal deposition. In contrast, in the Shasta, Lawyers,
and Griz-Sickle low-sulfidation epithermal systems, there is no clear association with magmatic fluids. Instead, their fluid
inclusion data indicate the involvement of low-temperature (175 to 335°C), low-salinity (1 to 11 equiv. wt.% NaCl) fluids
that deposited metals at shallow depths (<850 m). Their isotope (i.e., O, H, Pb) data suggest interaction between meteoric
and/or metamorphic ore fluids with basement country rocks. 相似文献
912.
The Çalda? nickel laterite deposit located in the Aegean region of W. Turkey contains a reserve of 33 million tons of Ni ore with an average grade of 1.14% Ni. The deposit is developed on an ophiolitic serpentinite body which was obducted onto Triassic dolomites in the Late Cretaceous. The deposit weathering profile is both laterally and vertically variable. A limonite zone, which is the main ore horizon, is located at the base of the profile. A hematite horizon is located above the limonite, which in the south of the deposit is capped by Eocene freshwater limestones and in the north by a siliceous horizon. The deposit is unusual in lacking a significant saprolite zone with little development of Ni-silicates. The boundary between the limonite zone and serpentinite below is sharp with a marked decrease in concentrations of MgO from 13 to 1 wt.% over a distance of 2 mm representing the ‘Mg discontinuity’. Ni concentrations within goethite, the main ore mineral, reach a maximum of ~3 wt.% near the base of the limonite zone. Silica concentrations are high throughout most of the laterite with up to 80 wt.% silica in the upper portion of some profiles. The combination of a serpentinite protolith and a high water table at Çalda?, in association with an aggressive weathering environment in a tropical climate, resulted in the formation of an oxide-dominated deposit. The precipitation of silica may coincide with a change in climate with silica precipitation linked to an increase in seasonality. Additional variations within profile morphology are attributed to transportation during and after laterite development as a result of faulting, pocket type laterite formation and slumping, each of which produces a contrasting set of textural and geochemical features. 相似文献
913.
Jasper Moernaut Marc De Batist Katrien Heirman Maarten Van Daele Mario Pino Robert Brümmer Roberto Urrutia 《Sedimentary Geology》2009,213(3-4):121-135
A dense grid of very-high resolution seismic profiles on Lake Villarrica provides a quasi-3D view on intercalated lenses of low-amplitude reflections, which are connected by acoustic wipe-out patches and fractures to an underlying voluminous mass-wasting deposit. The lenses are interpreted as being created by earthquake-triggered liquefaction in this buried mass-wasting deposit and subsequent sediment fluidization and extrusion at the paleo-lake bottom. These sediment volcanoes are mapped in detail. They have a rather uniform circular geometry and show a linear relationship between apparent width and maximum thickness on a seismic section. The largest sediment volcanoes are up to 80 m wide and 1.9 m thick. Their slope angles designate a syn- to post-depositional sagging of most sediment volcanoes. Sediment volcano detection and mapping from nearby Lake Calafquén further strengthen the revealed geometrical relationships. Locally, some of the sediment/fluid escape structures extend to a higher position in the stratigraphy, which points to a polyphase escape process associated with multiple multi-century spaced strong earthquakes. Thickness and morphology of the source layer seem to exert a dominant control in the production of sediment/fluid extrusions. This study shows that reflection seismic profiling allowed recognizing 4 different seismic events in the studied stratigraphic interval, which are evidenced by mass-wasting deposits and/or fluidization features. 相似文献
914.
Exchange of carbon bound hydrogen has been observed when alkenes, saturated and aromatic hydrocarbons are heated at moderate temperatures on carbonaceous surfaces (activated carbon and coal). Isomerisation of alkenes and the formation of hydrogenated/dehydrogenated products from the saturated and aromatic reactants resulted. A suite of crude oils from the Carnarvon Basin (Western Australia) have been analysed with a view to comparing their relative abundances of structurally similar hydrocarbons. The consistent relationships between hydrocarbons in crude oils that are chemically related via hydrogenation/dehydrogenation reactions suggest that a hydrogen exchange process similar to that demonstrated in laboratory experiments occurs during crude oil formation in sedimentary rocks. 相似文献
915.
Osvaldo M. Rabbia Laura B. Hernández David H. French Robert W. King John C. Ayers 《Mineralium Deposita》2009,44(8):849-866
Mineralogical, textural, and chemical analyses (EPMA and PIXE) of hydrothermal rutile in the El Teniente porphyry Cu–Mo deposit
help to better constrain ore formation processes. Rutile formed from igneous Ti-rich phases (sphene, biotite, Ti-magnetite,
and ilmenite) by re-equilibration and/or breakdown under hydrothermal conditions at temperatures ranging between 400°C and
700°C. Most rutile nucleate and grow at the original textural position of its Ti-rich igneous parent mineral phase. The distribution
of Mo content in rutile indicates that low-temperature (∼400–550°C), Mo-poor rutile (5.4 ± 1.1 ppm) is dominantly in the Mo-rich
mafic wallrocks (high-grade ore), while high-temperature (∼550-700°C), Mo-rich rutile (186 ± 20 ppm) is found in the Mo-poor
felsic porphyries (low-grade ore). Rutile from late dacite ring dikes is a notable exception to this distribution pattern.
The Sb content in rutile from the high-temperature potassic core of the deposit to its low-temperature propylitic fringe remains
relatively constant (35 ± 3 ppm). Temperature and Mo content of the hydrothermal fluids in addition to Mo/Ti ratio, modal
abundance and stability of Ti-rich parental phases are key factors constraining Mo content and provenance in high-temperature
(≥550°C) rutile. The initial Mo content of parent mineral phases is controlled by melt composition and oxygen fugacity as
well as timing and efficiency of fluid–melt separation. Enhanced reduction of SO2-rich fluids and sulfide deposition in the Fe-rich mafic wallrocks influences the low-temperature (≤550°C) rutile chemistry.
The data are consistent with a model of fluid circulation of hot (>550°C), oxidized (ƒO2 ≥ NNO + 1.3), SO2-rich and Mo-bearing fluids, likely exsolved from deeper crystallizing parts of the porphyry system and fluxed through the
upper dacite porphyries and related structures, with metal deposition dominantly in the Fe-rich mafic wallrocks. 相似文献
916.
Paul C. Hackley Edgar H. Guevara Tucker F. Hentz Robert W. Hook 《International Journal of Coal Geology》2009,77(3-4):294-309
Thermal maturity was determined for about 120 core, cuttings, and outcrop samples to investigate the potential for coalbed gas resources in Pennsylvanian strata of north-central Texas. Shallow (< 600 m; 2000 ft) coal and carbonaceous shale cuttings samples from the Middle-Upper Pennsylvanian Strawn, Canyon, and Cisco Groups in Archer and Young Counties on the Eastern Shelf of the Midland basin (northwest and downdip from the outcrop) yielded mean random vitrinite reflectance (Ro) values between about 0.4 and 0.8%. This range of Ro values indicates rank from subbituminous C to high volatile A bituminous in the shallow subsurface, which may be sufficient for early thermogenic gas generation. Near-surface (< 100 m; 300 ft) core and outcrop samples of coal from areas of historical underground coal mining in the region yielded similar Ro values of 0.5 to 0.8%. Carbonaceous shale core samples of Lower Pennsylvanian strata (lower Atoka Group) from two deeper wells (samples from ~ 1650 m; 5400 ft) in Jack and western Wise Counties in the western part of the Fort Worth basin yielded higher Ro values of about 1.0%. Pyrolysis and petrographic data for the lower Atoka samples indicate mixed Type II/Type III organic matter, suggesting generated hydrocarbons may be both gas- and oil-prone. In all other samples, organic material is dominated by Type III organic matter (vitrinite), indicating that generated hydrocarbons should be gas-prone. Individual coal beds are thin at outcrop (< 1 m; 3.3 ft), laterally discontinuous, and moderately high in ash yield and sulfur content. A possible analog for coalbed gas potential in the Pennsylvanian section of north-central Texas occurs on the northeast Oklahoma shelf and in the Cherokee basin of southeastern Kansas, where contemporaneous gas-producing coal beds are similar in thickness, quality, and rank. 相似文献
917.
In Pennsylvania, the Taconic Orogeny lasted from 461 to 443 Ma as Cambro-Ordovician slope deposits were deformed into mountains edging the Laurentian craton at the same time that materials from an adjacent deep-water basin were being transported 50 –70 km across a carbonate platform into foreland basins. This paper focuses on shelf-edge hinterland features, mostly the Martic Zone as a folded, stack of imbricate thrust sheets of slope materials that corresponds to Vermont's Taconic Mountains and Southern Quebec's zone of Taconic allochthons. Work of the last century is summarized, corrected, and combined with a new 450 Ma radiometric date and fluid inclusion data from the Pequea Mine within the Martic Zone. These and abundant new graptolite and conodont dates in the foreland paint a revised Pennsylvania picture differing from the northern Taconic areas. Differences are: (1) transport of very large allochthonous masses of deep-water material, the Dauphin Formation, far across the carbonate platform, and (2) deformation migrating progressively across that platform during a 15 –20 m.y. period, incorporating it and its foreland cover into alpine-scale, recumbent folds and thrusts. The scenario has many analogies to Italy's modern Apennine Mountains minus the Latian volcanics. 相似文献
918.
In groundwater studies, the numerical modeling of complex boundary conditions can be made easier by considering reservoirs and pipes as “reservoir” finite elements, which can store or release large volumes of water at almost constant hydraulic head. The numerical code to be used must solve the complete conservation equation with unlinked functions for the water retention curve and the unsaturated hydraulic conductivity, and the ability to describe these as step functions. Four examples illustrate the performance of the “reservoir” element: reservoir pumping, laboratory variable-head permeability test, vertical flow in an open borehole, and pumping test with well storage. 相似文献
919.
Alessandro Sandrin sa Edfelt Tod E. Waight Robert Berggren Sten-ke Elming 《Journal of Geochemical Exploration》2009,103(2-3):80-96
The Tjårrojåkka Fe–Cu-prospect in northern Sweden is considered an example of a Fe-oxide Cu–Au (IOCG) deposit and is hosted in metamorphosed Paleoproterozoic volcanic and intrusive rocks. Rock samples from 24 outcrops were collected for petrophysical analysis (magnetic susceptibility, remanent magnetization, variation of magnetic susceptibility with temperature, Curie temperature and density). The major Cu-prospect in the area has been studied by magnetic and electron microprobe analyses of four selected rock samples. The samples are from an exploration well that intersects the main Cu-mineralized body.The magnetic analyses show that magnetite is the dominant magnetic mineral, while hematite and other Fe-minerals are present in minor amounts. The electron microprobe observations confirm the presence of magnetite and further indicate that hematite is an alteration product of magnetite. Moreover, microprobe observations indicate that Fe-sulfides are present in negligible amounts in the samples from the Tjårrojåkka area. The strong spatial relationship of Cu-minerals (e.g., chalcopyrite) and the oxidation of magnetite to hematite suggest that the presence of rocks with low magnetic susceptibility in areas dominated by high susceptibility rocks may be a signal of related Cu-prospects. 相似文献
920.
Numerical simulations of the Mediterranean sea outflow: impact of the entrainment parameterization in an isopycnic coordinate ocean model 总被引:1,自引:0,他引:1
Gravity current entrainment is essential in determining the properties of the interior ocean water masses that result from marginal sea overflows. Although the individual entraining billows will be unresolvable in large-scale ocean models for the foreseeable future, some large-scale simulations are now being carried out that do resolve the intermediate scale environment which may control the rate of entrainment. Hallberg [Mon. Wea. Rev. 128 (2000) 1402] has recently developed an implicit diapycnal mixing scheme for isopycnic coordinate ocean models that includes the Richardson number dependent entrainment parameterization of Turner [J. Fluid Mech. 173 (1986) 431], and which may be capable of representing the gravity current evolution in large-scale ocean models. The present work uses realistic regional simulations with the Miami Isopycnic Coordinate Ocean Model (MICOM) to evaluate ability of this scheme to simulate the entrainment that is observed to occur in the bottom boundary currents downstream of the Mediterranean outflow. These simulations are strikingly similar to the observations, indicating that this scheme does produce realistic mixing between the Mediterranean outflow and the North Atlantic Central Water. Sensitivity studies identify the critical Richardson number below which vigorous entrainment occurs as a particularly important parameter. Some of these experiments also show meddies detaching from the Mediterranean undercurrent at locations that appear to be highly influenced by topographic features. 相似文献