Model systems for anatexis of pelitic rocks

Subsolidus and melting reactions involving calcic plagioclase in pelitic assemblages in the K-Na-Ca model system occur at higher temperatures than their K-Na counterparts. For the most calcic plagioclase compositions observed in high-grade pelitic rocks (An₂₅-An₄₀) the equilibria are rarely extended by more than 30 ° C above those in KA1O₂-NaAlO₂-Al₂O₃-SiO₂-H₂O, although all discontinuities in facies inferred for the K-Na system are continuously displaced when they involve Ca-bearing plagioclase. The maximum pressure-temperature overlap between muscovite dehydration and initial melting reactions occurs in the pressure range of 4–6 kbar between about 640 ° and 720 ° C. This provides optimum conditions for anatectic melt generation in felsic rocks of the appropriate compositions progressively metamorphosed in kyanite-sillimanite facies series. Progressive regional metamorphism at pressures of 2–4 kbar, corresponding to andalusite-sillimanite facies series, shows little overlap between muscovite dehydration and initial melting reactions. Consequently anatectic melt generation in andalusite-sillimanite facies series would require the participation of biotite in dehydration-melting reactions. Felsic intrusive rock in andalusite-sillimanite terranes could have risen upward from their anatectic sites in high grade kyanite-sillimanite facies series at depth. Many andalusite-sillimanite facies series terranes culminating in migmatites could represent upward movement of kyanite-sillimanite facies series rocks to shallower depths with uplift rates faster than cooling rates.     

Symphurus civitatium (Pleuronectiformes: Cynoglossidae), a second estuarine-occurring tonguefish off the Southeastern United States and Northern Gulf of Mexico

Two species of tonguefishes,Symphurus plagiusa (Linnaeus 1766) andSymphurus civitatium Ginsburg 1951, occur sympatrically and sometimes syntopically in shallow water habitats in North Carolina and Louisiana estuaries. In North Carolina, approximately 2% of 430 small (<75 mm SL) tonguefishes collected wereS. civitatium, while in Barataria Bay, Louisiana, this species was more abundant and cosmopolitan in distribution than wasS. plagiusa, comprising over 82% of 3,564 tonguefishes collected with a small beam trawl over a 2-yr period. Historical literature has regardedS. plagiusa as the only tonguefish species inhabiting inshore waters in both regions. Presence of a secondSymphurus species in shallow estuaries has been overlooked, most probably due to difficulties in identifying early post-settlement juveniles because both species have similar morphologies and overlapping dorsal-fin and anal-fin ray counts. Juveniles can be readily recognized by differences in number of caudal-fin rays (10 inS. plagiusa versus 12 inS. civitatium), especially when used in combination with pigmentation patterns and posterior extent of the jaws relative to the posterior margin of the lower eye. The most distinctive pigmentation difference between juveniles of these two species (allowing for accurate identifications of over 98% of juveniles) is the absence inS. civitatium (12–61 mm SL) of a series of melanophores overlying pterygiophore regions of the dorsal and anal fins on the blind side. This feature contrasts markedly with that of juvenileS. plagiusa (12–65 mm SL), which are characterized by two interrupted, diagonal series of dark chromatophores converging, but not merging, with posterior tapering of the body. Occurrence of two sympatric species of tonguefishes in estuarine environments in the northcentral Gulf of Mexico and southeastern U.S. potentially compromises results of earlier ecological and distributional studies that assumed presence of only a single tonguefish species in these regions.     

Determination of the REE in Geological Reference Materials DTS-1 (Dunite) and PCC-1 (Peridotite) by Ultrasonic and Microconcentric Desolvating Nebulisation ICP-MS

Inductively coupled plasma-mass spectrometry is well suited for the precise, accurate and rapid determination of rare earth elements in most geological samples. However, determination of rare earth elements in certain mantle-derived materials, without applying preconcentration techniques, remains problematical due to low natural concentrations (generally < 1 ng g⁻¹). Consequently, USGS reference materials DTS-1 (a dunite) and PCC-1 (a partially serpentinized harzburgite) have only suggested rather than recommended values for the rare earth elements in reference material compilations. We compared results obtained using two ICP-MS instruments: a U-5000AT ultrasonic nebuliser coupled to a PQ2+ quadrupole ICP-MS and an ELEMENT sector field ICP-MS equipped with a MCN-6000 microconcentric desolvating nebuliser, with the suggested literature values for these two reference materials. Precision and accuracy of analytical methods employed by both instruments were demonstrated by excellent relative standard deviations (< 2%) and inter-laboratory agreement (< 5%) for numerous analyses of BHVO-1 and BIR-1, which are well established with rare earth elements contents at the μg g⁻¹ level. Repeat analyses of DTS-1 and PCC-1 at each laboratory indicate that each method is generally precise to better than 5% at sub-g g⁻¹ levels. Furthermore, values from both instruments generally agree to within 10%. Our DTS-1 and PCC-1 values agree reasonably well with selected data reported in the literature (except for Ce and Sm in DTS-1) but exhibit poorer agreement with reported compilation values. With the demonstrated level of precision and accuracy, we contend that these new values for DTS-1 and PCC-1, generated by two different instruments, are the best estimates of the true whole-rock composition of these samples reported to date.     

Holocene Foraminifera as Indicators of Relative Estuarine–Lagoonal and Oceanic Influences in Estuarine Sediments of the River Murray, South Australia: Volume 53, Number 3 (2000), pages 378–391

In southeastern South Australia, the River Murray debouches through a coastal barrier separating euryhaline estuarine-lagoonal waters from the Southern Ocean. Depending upon the relative freshwater outflow of the river and ingress of the ocean, water salinity varies greatly within the lower estuary. Ammonia beccarii and Elphidium articulatum are euryhaline species of foraminifera that characterize the estuary and back-barrier Coorong Lagoon. The inner-shelf marine environment hosts an assemblage in which Discorbis dimidiatus, E. crispum, E. macelliforme, and various cibicidid species predominate. In cored sediments recovered from the shallow lower estuary, the relative abundance of A. beccarii + E. articulatum was compared with that of D. dimidiatus + E. crispum + E. macelliforme + other species. These data, and AMS radiocarbon ages determined for foraminifera and ostracods, provide evidence of a change from maximum oceanic influence (5255 ± 60 yr B.P.) to maximum estuarine influence (3605 ± 70 yr B.P.). Over this same time interval, sea level fell relatively by about 2 m. However, the event was also contemporaneous with falling water levels in several Victorian lakes, and it is thus attributed to onset of climatic aridity. Reduced precipitation in the River Murray catchment and reduced freshwater outflow enhanced development of the flood-tide delta and constriction of the mouth.     

Environmental impact of salmon net-pen culture on marine benthic communities in Maine: A case study

The environmental impacts of salmon net-pen aquaculture on the benthic environment were investigated at a commercial fish farm located in coastal Maine waters. This site has a sandy mud bottom and low current velocities, is subjected to episodic sediment resuspension, and way in production for 3 yr prior to this study: We examined both the increase in carbon flux to the benthos caused by the net-pen and the effects of the elevated flux on sediment biogeochemistry and the microbenthic communities. The experimental design involved the establishment of two study sites, an ambient site ca. 100 m from the net-pen and a treatment site around the pen. Sediment traps deployed 1 m above the sediment-water interface indicated that carbon flux to the benthos was increased 1-fold to 6-fold (to a maximum of 5 g m^?2d^?1) at the edge of the net-pen with little or no increase in carbon flux 10 m from the pen. Unlike carbon flux rates, sediment organic matter inventories showed a complex pattern of change over time. Mineral surface area, organic carbon and nitrogen, digestible protein, and sterol content were initially (April 1991) lower beneath the pen than in ambient sediments. During 1991 ambient sediment accumulated organic matter until July after which it decreased, to a low during November. In contrast, organic matter inventories of sediment beneath the pen remained low until July and then increased to a high during November. These latter gains were associated with the development of bacterial mats at the sediment-water interface. Beneath the pen, microbial and macrofaunal communities were shifted toward those commonly associated with organic enrichment but seasonal trends and storm-related resuspension events also significantly affected these sediment communities. When abundant, most epibenthic organisms were more numerous near the pen than in adjacent ambient areas. These results suggest that net-pen aquaculture can alter the benthic ecosystem in Maine Coastal waters but indicate that the effects are spatially limited.     

Probabilistic seismic hazard zonation of Syria

Earthquake hazard maps for Syria are presented in this paper. The Peak Ground Acceleration (PGA) and the Modified Mercalli Intensity (MMI) on bedrock, both with 90% probability of not being exceeded during a life time of 50, 100 and 200 years, respectively are developed. The probabilistic PGA and MMI values are evaluated assuming linear sources (faults) as potential sources of future earthquakes. A new attenuation relationship for this region is developed. Ten distinctive faults of potential earthquakes are identified in and around Syria. The pertinent parameters of each fault, such as theb-parameter in the Gutenberg-Richter formula, the annual rate ₄ and the upper bound magnitudem ₁ are determined from two sets of seismic data: the historical earthquakes and the instrumentally recorded earthquake data (AD 1900–1992). The seismic hazard maps developed are intended for preliminary analysis of new designs and seismic check of existing civil engineering structures.     

Cation disorder in garnets along the Mg3Al2Si3O12-Mg4Si4O12 join: an infrared,Raman and NMR study

We have obtained infrared and Raman spectra for garnets synthesized at high (static) pressures and temperatures along the join Mg₃Al₂Si₃O₁₂ (pyrope) — Mg₄Si₄O₁₂ (magnesium majorite). The vibrational spectra of Mg-majorite show a large number of additional weak peaks compared with the spectra of cubic pyrope garnet, consistent with tetragonal symmetry for the MgSiO₃ garnet phase. The Raman bands for this phase show no evidence for line broadening, suggesting that Mg and Si are ordered on octahedral sites in the garnet. The bands for the intermediate garnet compositions are significantly broadened compared with the end-members pyrope and Mg-majorite, indicating cation disorder in the intermediate phases. Solid state ²⁷Al NMR spectroscopy for pyrope and two intermediate compositions show that Al is present only on octahedral sites, so the cation disorder is most likely confined to Mg-Al-Si mixing on the octahedral sites. We have also obtained a Raman spectrum for a natural, shock-produced (Fe,Mg) majorite garnet. The sharp Raman peaks suggest little or no cation disorder in this sample.     

Transformation of dilative and contractive landslide debris into debris flows—An example from marin County, California

The severe rainstorm of January 3, 4 and 5, 1982, in the San Francisco Bay area, California, produced numerous landslides, many of which transformed into damaging debris flows. The process of transformation was studied in detail at one site where only part of a landslide mobilized into several episodes of debris flow. The focus of our investigation was to learn whether the landslide debris dilated or contracted during the transformation from slide to flow.

The landslide debris consisted of sandy colluvium that was separable into three soil horizons that occupied the axis of a small topographic swale. Failure involved the entire thickness of colluvium; however, over parts of the landslide, the soil A-horizon failed separately from the remainder of the colluvium.

Undisturbed samples were taken for density measurements from outside the landslide, from the failure zone and overlying material from the part of the landslide that did not mobilize into debris flows, and from the debris-flow deposits. The soil A-horizon was contractive and mobilized to flows in a process analogous to liquefaction of loose, granular soils during earthquakes. The soil B- and C-horizons were dilative and underwent 2 to 5% volumetric expansion during landslide movement that permitted mobilization of debris-flow episodes.

Several criteria can be used in the field to differentiate between contractive and dilative behavior including lag time between landsliding and mobilization of flow, episodic mobilization of flows, and partial or complete transformation of the landslide.