Mid-Paleocene event at Gabal Nezzazat,Sinai, Egypt: planktonic foraminiferal biostratigraphy,mineralogy and geochemistry

The Qreiya Beds that record the ‘mid-Paleocene event’ at Gabal Nezzazat occur within the Igorina albeari (P3b) Zone and constitute part of a 14-m thick shale succession that ranges in age from Early to Late Paleocene. They are composed of four alternating dark grey and brown shale beds, which are thinly laminated, phosphatic, organic-rich and extremely sulphidic. They are characterized by distinct enrichment and high peak anomalies in chalcophiles (Zn, Co, Ni, Cu and Pb) and organic association elements (V and Cr), especially within the brown organic-rich beds. It is concluded that these elements are incorporated into the phosphatic debris, sulphides and organic matter. In contrast, the grey beds are enriched in clay minerals and quartz. Clay mineral assemblages indicate alternating periods of warm/humid climate (high kaolinite) and dry climate (low kaolinite) during the formation of the grey and brown beds, respectively. The sediments of the Qreiya Beds yield lithological, biotic, geochemical and mineralogical data indicative of suboxic/anoxic marine environments as a result of high productivity and/or upwelling. The top metre of the succession below the Qreiya Beds is characterized by a progressive change from faunas dominated by praemurcurids to faunas dominated by Morozovilids, and by a progressive upward decrease in δ¹³C_carb and δ¹⁸O_carb values. The foraminiferal faunal change may reflect shallowing and warming preceding deposition of the Qreiya Beds. The change in isotopic values is inferred to be the result of surface weathering, fluvial input and diagenesis with no evidence of any primary change that could support presence of a hyperthermal event.     

RECONSTRUCTING THE SOLAR CORONAL MAGNETIC FIELD AS A FORCE-FREE MAGNETIC FIELD

We present some preliminary results on different mathematical problems encountered in attempts to reconstruct the coronal magnetic field, assumed to be in a force-free state, from its values in the photosphere. We discuss the formulations associated with these problems, and some new numerical methods that can be used to get their approximate solutions. Both the linear constant- and the nonlinear cases are considered. We also discuss the possible use of dynamical 3D MHD codes to construct approximate solutions of the equilibrium force-free equations, which are needed for testing numerical extrapolation schemes.     

Igneous dykes and associated scour hollows of the North Channel,Irish Sea

A side-scan sonar survey with complete ground coverage has revealed the presence of numerous, straight, narrow ridges of NNW and NE trends in the North Channel, Irish Sea. They are interpreted as igneous dykes, probably of Tertiary age. The topographic expression of the dykes and their appearance on the sonographs provide indications of considerable erosion by tidal-current scour.     

Power law relating 10.7 cm flux to sunspot number

To investigate the relation between observations of the 10.7 cm flux and the international sunspot number so that a physical unit may be ascribed to historical records, both polynomial and power law models are developed giving the radio flux as a function of sunspot number and vice versa. Bayesian data analysis is used to estimate the model parameters and to discriminate between the models. The effect on the parameter uncertainty and on the relative evidence of normalizing the measure of fit is investigated. The power law giving flux as a function of sunspot number is found to be the most plausible model and may be used to estimate the radio flux from historical sunspot observations.     

Environmental impact of salmon net-pen culture on marine benthic communities in Maine: A case study

The environmental impacts of salmon net-pen aquaculture on the benthic environment were investigated at a commercial fish farm located in coastal Maine waters. This site has a sandy mud bottom and low current velocities, is subjected to episodic sediment resuspension, and way in production for 3 yr prior to this study: We examined both the increase in carbon flux to the benthos caused by the net-pen and the effects of the elevated flux on sediment biogeochemistry and the microbenthic communities. The experimental design involved the establishment of two study sites, an ambient site ca. 100 m from the net-pen and a treatment site around the pen. Sediment traps deployed 1 m above the sediment-water interface indicated that carbon flux to the benthos was increased 1-fold to 6-fold (to a maximum of 5 g m^?2d^?1) at the edge of the net-pen with little or no increase in carbon flux 10 m from the pen. Unlike carbon flux rates, sediment organic matter inventories showed a complex pattern of change over time. Mineral surface area, organic carbon and nitrogen, digestible protein, and sterol content were initially (April 1991) lower beneath the pen than in ambient sediments. During 1991 ambient sediment accumulated organic matter until July after which it decreased, to a low during November. In contrast, organic matter inventories of sediment beneath the pen remained low until July and then increased to a high during November. These latter gains were associated with the development of bacterial mats at the sediment-water interface. Beneath the pen, microbial and macrofaunal communities were shifted toward those commonly associated with organic enrichment but seasonal trends and storm-related resuspension events also significantly affected these sediment communities. When abundant, most epibenthic organisms were more numerous near the pen than in adjacent ambient areas. These results suggest that net-pen aquaculture can alter the benthic ecosystem in Maine Coastal waters but indicate that the effects are spatially limited.     

Non-tidal changes in the length of the day: 700 BC to AD 1982

Occultations and eclipses from ancient times down to the present are analysed to determine changes in the length of the day. By subtracting the expected tidal contribution from the observed changes, the non-tidal variations are obtained. The non-tidal varations are shown to occur on time-scales of decades and millennia.     

Elasticity of polycrystalline stishovite

Ultrasonic data for the velocities of SiO₂-stishovite have been determined as a function of pressure to 10 kbar at room temperature for polycrystalline specimens hot-pressed at pressures P = 120kbar and temperatures T = 900°C. These cylindrical specimens are 2 mm in diameter and 0.9–1.4 mm long and have a grain size less than 10 μm. Compressional and shear wave velocities were measured both parallel and perpendicular to the axis of pressing and were found to be isotropic at 10 kbar with ν_p = 11.0 ± 0.2km/sec andν_s = 6.9 ± 0.3km/sec; this shear velocit is substantially higher than that of Mizutani et al. (1972) perhaps due to the presence of crack orientations in their specimen which affected ν_s but not ν_p. The Murnaghan P-V trajectories calculated from the ultrasonic data [bulk modulus K_s = 2.5 ± 0.3Mbar and assuming (?K_s/?P)_T = 6 ± 2] are consistent with recent hydrostatic compression data and with the shock wave compression data above 600 kbar. The combined evidence from the data of the ultrasonic and hydrostatic compression techniques suggests that the most probable value of the bulk modulus of stishovite at zero pressure is close to the upper limit of the uncertainty of our ultrasonically determined value, K₀ = 2.7?2.8Mbar. Elasticity data for rutile-type oxides are not compatible with normal K_s-V₀ systematics perhaps due to the neglect of non-central forces in the lattice model. These new stishovite data would make it impossible to satisfy the elasticity-density data of the lower mantle using an oxide mixture with either olivine or pyroxene stoichiometry.     

Contemporary 14C radiocarbon levels of oxygenated polybrominated diphenyl ethers (O-PBDEs) isolated in sponge-cyanobacteria associations

Considerable debate surrounds the sources of oxygenated polybrominated diphenyl ethers (O-PBDEs) in wildlife as to whether they are naturally produced or result from anthropogenic industrial activities. Natural radiocarbon (¹⁴C) abundance has proven to be a powerful tool to address this problem as recently biosynthesized compounds contain contemporary (i.e. modern) amounts of atmospheric radiocarbon; whereas industrial chemicals, mostly produced from fossil fuels, contain no detectable ¹⁴C. However, few compounds isolated from organisms have been analyzed for their radiocarbon content. To provide a baseline, we analyzed the ¹⁴C content of four O-PBDEs. These compounds, 6-OH-BDE47, 2′-OH-BDE68, 2′,6-diOH-BDE159, and a recently identified compound, 2′-MeO-6-OH-BDE120, were isolated from the tropical marine sponges Dysidea granulosa and Lendenfeldia dendyi. The modern radiocarbon content of their chemical structures (i.e. diphenyl ethers, C₁₂H₂₂O) indicates that they are naturally produced. This adds to a growing baseline on, at least, the sources of these unusual compounds.