Perception of urban retailing environments: An empirical analysis of consumer information and usage fields

This article reports on an empirical analysis of consumer information and usage fields in the city of Eindhoven. The main purposes of this study are to investigate the distance, sectoral and directional biases of these fields, to analyse whether the degree of biases is related to personal characteristics of consumers and to identify the factors of the basis on which a model which predicts the probability that a shopping centre will be known by consumers can be developed. The findings of the study suggest that strong distance, sectoral and directional biases are present in the information and usage fields of consumers and that no systematic relationships exist between these characteristics of information and usage fields and personal variables of consumers. Finally, the present studies suggests that a model which describes the formation of consumer choice sets should include spatial factors such as distance, size, intervening opportunities and direction towards the city centre.     

Theoretical organic geochemistry. I. The thermodynamic stability of several cholestane isomers calculated by molecular mechanics

The thermodynamic stabilities of thirteen cholestane isomers have been computed using molecular mechanics. The calculated composition of a mixture of these isomers at thermodynamic equilibrium is in agreement with the composition of a cholestane isomerate. From the calculated stabilities the extent to which isomerisation reactions can proceed during maturation can be predicted. The GLC retention order on non-polar phases of 20R/S isomeric pairs has been estimated from the preferred geometries of the molecules which are also obtained by molecular mechanics.     

Stratigraphy,pollen analysis,and paleoclimatic interpretation of Pulbeena Swamp,northwestern Tasmania

Sedimentary, palynologic, and ¹⁴C analysis of 480 cm of freshwater marl and swamp-peat deposits, formed under the influence of fluctuating artesian springs, provides a paleoenvironmental and paleoclimatic record of approximately 65,000 yr for northwestern Tasmania.The Holocene (Pollen Zone 1, 11,000-0 yr B.P.) climate was warm and moist, and forest vegetation was dominant throughout the area. During the later part of the last glacial stage (Pollen Zone 2, 35,000–11,000 yr B.P.) the climate was generally drier, and grassy open environments were widespread. The driest part of this period occurred between 25,000 to 11,000 yr B.P., when temperatures in western Tasmania were markedly reduced during the last major phase of glaciation. Prior to 35,000 yr B.P. (Pollen Zones 3–9) a long “interstadial complex” dating to the middle of the last glacial stage is recognized. During this period the climate was generally moist, and forest and scrub communities were more important than during the later part of the last glacial stage, except during Pollen Zone 5 when high Gramineae plus Compositae values suggest drier conditions. High Gramineae and Compositae values also occur in Pollen Zone 10 at the base of the diagram. They suggest that a phase of drier and cooler climatic conditions occurred during the early part of the last glacial stage.     

Instrumental Neutron Activation Analysis Of 37 Geochemical Reference Samples

37 geochemical reference samples, issued mostly by the U.S. Geological Survey and the "Centre de Recherches Pétrographiques et Géochi-miques", have been analysed for more than twenty trace elements using instrumental neutron activation technique. The results are compared with published data; in most oases, the agreement is good.     

Holocene lagoonal silts (formerly called “sloef”) from the Zuiderzee

This publication forms the introduction to a series of papers that will be presented in the near future. They will all deal with the “sloef” (also called Almere deposits), a Holocene lagoonal silt that has been deposited in the former Zuiderzee (The Netherlands).The silt formed between about 375 and 2000 years ago and shows a typical grain-size distribution. The percentage of particles from 0 to 2 μm is abnormally low, whereas the percentage of particles from 2 to 50 μm is high.Over large areas the “sloef” contains abundant sedimentary structures, among which metasedimentary faults and flow structures are frequently present.     

Age and origin of the Nigerian mesozoic granites: A Rb-Sr isotopic study

Sixty-four Rb-Sr and two K-Ar isotopic measurements from seven ring complexes in central Nigeria provide evidence for a systematic age trend along a 200 km zone ranging from 174±5 m.y. in the north to 154±4 m.y. in the south. A peak of anorogenic magmatism occurred in the Jos Plateau region about 164±4 m.y. ago. Although a small syenitetrachyte complex at Zaranda, near Bauchi, gives an age of 190±15 m.y., unpublished ages of 290–330 m.y. for the southern Niger ring complexes confirm the existence of an overall southerly decreasing age trend in the Niger-Nigeria province of West Africa. Isotopic measurements on two small, oversaturated syenite intrusions at Zaranda and Pankshin suggest that syenitic liquids had initial ⁸⁷Sr/⁸⁶Sr ratios of 0.7048—not significantly different from the mantle range of values, but that related peralkaline silicic variants from the same complexes are depleted in total Sr and have higher ⁸⁷Sr/⁸⁶Sr initial ratios characteristic of the earth's crust. This variation of initial ⁸⁷Sr/⁸⁶Sr ratios in syenite-related granitic liquids of the peralkaline spectrum has also been noted at the Shere Hills, near Jos, and at Liruei, near Kano, and may be representative for all syenite-granite occurrences in the Nigerian Younger Granite province. Such isotopic variations in the initial ⁸⁷Sr/⁸⁶Sr ratio may be attributed to “crustal enrichment” of syenitic liquids whose source lies in the mantle. Coarse-grained, peraluminous biotite granites have consistently low initial ⁸⁷Sr/⁸⁶Sr ratios in the range 0.706–0.709 (similar to the ca. 600 m.y. Pan-African granites of the basement), and may represent further modifications of originally syenitic liquids in the crust, or the granites may have originated from an independent source within a “dioritio” lower crust. Although the magmatic trends show small variations in the initial ⁸⁷Sr/⁸⁶Sr ratio, much higher initial ratios are recorded in granites which have been modified within their roof zone by deuteric (autometamorphic) and/or metasomatic processes.     

Age of the rhyolites of the Lord Howe Rise and the evolution of the southwest Pacific Ocean

Drilling at site 207 (DSDP Leg 21), located on the broad summit of the Lord Howe Rise, bottomed in rhyolitic rocks. Sanidine concentrates from four samples of the rhyolite were dated by the⁴⁰Ar/³⁹Ar total fusion method and conventional K-Ar method, and yielded concordant ages of 93.7 ± 1.1my, equivalent to the early part of the Upper Cretaceous. At this time the Lord Howe Rise, which has continental-type structure, is thought to have been emergent and adjacent to the eastern margin of the Australian-antarctic continent. Subsequent to 94 my ago and prior to deposition of Maastrichtian (70-65 myBP) marine sediments on top of the rhyolitic basement of the Lord Howe Rise, rifting occurred and the formation of the Tasman Basin began by sea-floor spreading with rotation of the Rise away from the margin of Australia. Subsidence of the Rise continued until Early Eocene (about 50 myBP), probably marking the end of sea-floor spreading in the Tasman Basin. These large scale movements relate to the breakup of this part of Gondwanaland in the Upper Cretaceous.     

Manganiferous smectite from tirebolu (NE-Turkey)

A pink-colored (HUE 5R-7/4), predominantly calcium saturated, clay mineral from Tirebolu, NE-Turkey, is shown to be a dioctahedral, high-charge manganiferous smectite. It is probably an alteration product of volcanic tuffs of rhyodactitic composition. Ionic formula: (Si_7.71Al_0.29)^IV(Al_3.04Fe _0.12 ³⁺ Fe _0.02 ²⁺ Mg_0.92Mn _0.07 ²⁺ )^VI O₂₀ (OH)₄ 0.79 M⁺ Cation exchange capacity: 92 me/100 g (air dry sample). Unit cell parameters (ca. 20 ° C; ca. 40% RH): a₀9.02 Å b₀5.21 Å Mg⁺⁺... Mn-smectite: c₀14.65 Å Ca⁺⁺... Mn-smectite: c₀14.83 Å K⁺... Mn-smectite: c₀12.10 Å

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Zusammenfassung Ein rosa (HUE 5R-7/4), weitgehend Calcium-gesättigtes Tonmineral von Tirebolu (NO-Türkei) wurde als ein dioktaedrischer, hochgeladener manganhaltiger Smektit identifiziert. Er ist wahrscheinlich ein Umwandlungsprodukt eines rhyodazitischen Tuffs. Strukturformel: (Si_7.71Al_0.29)^IV(Al_3.04Fe _0.12 ³⁺ Fe _0.02 ²⁺ Mg_0.92Mn _0.07 ²⁺ )^VI O₂₀ (OH)₄ 0.79 M⁺ Kationaustauschkapazität: 92 me/100 g (luftgetrocknet). Gitterkonstanten (ca. 20° C; ca. 40% RF): a₀9.02 Å b₀5.21 Å Mg⁺⁺... Mn-Smektit: c₀14.65 Å Ca⁺⁺... Mn-Smektit: c₀14.83 Å K⁺... Mn-Smektit: c₀12.10 Å