Bioavailable iron in the Southern Ocean: the significance of the iceberg conveyor belt

Productivity in the Southern Oceans is iron-limited, and the supply of iron dissolved from aeolian dust is believed to be the main source from outside the marine reservoir. Glacial sediment sources of iron have rarely been considered, as the iron has been assumed to be inert and non-bioavailable. This study demonstrates the presence of potentially bioavailable Fe as ferrihydrite and goethite in nanoparticulate clusters, in sediments collected from icebergs in the Southern Ocean and glaciers on the Antarctic landmass. Nanoparticles in ice can be transported by icebergs away from coastal regions in the Southern Ocean, enabling melting to release bioavailable Fe to the open ocean. The abundance of nanoparticulate iron has been measured by an ascorbate extraction. This data indicates that the fluxes of bioavailable iron supplied to the Southern Ocean from aeolian dust (0.01–0.13 Tg yr^-1) and icebergs (0.06–0.12 Tg yr^-1) are comparable. Increases in iceberg production thus have the capacity to increase productivity and this newly identified negative feedback may help to mitigate fossil fuel emissions.     

Age assignment of a diatomaceous ooze deposited in the western Amundsen Sea Embayment after the Last Glacial Maximum

Reliable dating of glaciomarine sediments deposited on the Antarctic shelf since the Last Glacial Maximum (LGM) is challenging because of the rarity of calcareous (micro‐) fossils and the recycling of fossil organic matter. Consequently, radiocarbon (¹⁴C) ages of the acid‐insoluble organic fraction (AIO) of the sediments bear uncertainties that are difficult to quantify. Here we present the results of three different methods to date a sedimentary unit consisting of diatomaceous ooze and diatomaceous mud that was deposited following the last deglaciation at five core sites on the inner shelf in the western Amundsen Sea (West Antarctica). In three cores conventional ¹⁴C dating of the AIO in bulk samples yielded age reversals down‐core, but at all sites the AIO ¹⁴C ages obtained from diatomaceous ooze within the diatom‐rich unit yielded similar uncorrected ¹⁴C ages between 13 517 ± 56 and 11 543 ± 47 years before present (a BP). Correction of these ages by subtracting the core‐top ages, which probably reflect present‐day deposition (as indicated by ²¹⁰Pb dating of the sediment surface at one core site), yielded ages between ca. 10 500 and 8400 cal. a BP. Correction of the AIO ages of the diatomaceous ooze by only subtracting the marine reservoir effect (MRE) of 1300 a indicated deposition of the diatom‐rich sediments between 14 100 and 11 900 cal. a BP. Most of these ages are consistent with age constraints between 13.0 and 8.0 ka for the diatom‐rich unit, which we obtained by correlating the relative palaeomagnetic intensity (RPI) records of three of the sediment cores with global and regional reference curves. As a third dating technique we applied conventional radiocarbon dating of the AIO included in acid‐cleaned diatom hard parts extracted from the diatomaceous ooze. This method yielded uncorrected ¹⁴C ages of only 5111 ± 38 and 5106 ± 38 a BP, respectively. We reject these young ages, because they are likely to be overprinted by the adsorption of modern atmospheric carbon dioxide onto the surfaces of the diatom hard parts prior to sample graphitisation and combustion for ¹⁴C dating. The deposition of the diatom‐rich unit in the western Amundsen Sea suggests deglaciation of the inner shelf before ca. 13 ka BP. The deposition of diatomaceous oozes elsewhere on the Antarctic shelf around the same time, however, seems to be coincidental rather than directly related. Copyright © 2009 John Wiley & Sons, Ltd.     

Establishing rates of karst landscape evolution in the Tropics: a context for the formation of archaeological sites in western Flores,Indonesia

Tropical landscapes evolve at a rapid rate, creating stepped alluvial terraces, dense basin and cone topographies and multilevel cave systems. An understanding of the rate of landscape evolution is crucial for understanding how landscapes respond to tectonic instability and for reconstructing landscapes that have changed over archaeological timescales. The rate of landscape incision as a proxy for karst landscape evolution in Indonesia, a key region in the path of human dispersal, has been established using the rate of karstification – by estimating a chronology for stages of cave development using thermal ionisation mass spectrometry U‐series dating on flowstones, and the rate of downcutting – by establishing a chronology for a series of alluvial terraces using red thermoluminescence dating. Using these techniques we have determined that the estimated rate of karstification (113 ± 26 mm ka^?1) is slower than the average rate of downcutting (305 ± 24 mm ka^?1), and the combined rate of landscape incision (217 ± 18 mm ka^?1) is slower than the known rate of tectonic uplift for this region derived from raised coral terraces (450 ± 50 mm ka^?1). This suggests that rivers are quicker to respond to tectonic instability, but both cave and river systems display a slower rate of incision and karstification than uplift. Correlations between these components of the landscape system reveal a strong, interacting relationship where defined phases of uplift are reflected in the pattern of karstification and cycles of downcutting. An understanding of this relationship has been pivotal in reconstructing the formation and geomorphic history of archaeological caves such as Liang Bua. Copyright © 2010 John Wiley & Sons, Ltd.     

Relation between alternations of uplift and subsidence revealed by Late Cenozoic fluvial sequences and physical properties of the continental crust

Reversals in vertical crustal motion, alternations between uplift and subsidence over time scales of hundreds of thousands of years or more, have been identified in Late Cenozoic fluvial sequences in many regions worldwide. They form a class of fluvial archive that is distinct from the extreme stability observed in Archaean cratons and the monotonic uplift or subsidence that is widely observed in other regions. Such alternations between uplift and subsidence are characteristic of regions of Early or Middle Proterozoic crust, where the initial crustal consolidation included the development of a thick ‘root’ of mafic material at the base of the crust; the present study focuses on localities with this crustal type in the USA and eastern Europe. It has previously been suggested on the basis of uplift modelling that this style of crustal behaviour occurs only in regions where the mobile lower‐crustal layer is relatively thin. This study supports this conclusion on the basis of independent geothermal calculations, which indicate that such alternations between uplift and subsidence occur where the mobile lower‐crustal layer is ≤～7 km thick. An understanding of this phenomenon, in relation to the understanding of vertical crustal motions induced by surface processes (and thus by climate change) in general, therefore requires analysis of the properties and dynamics of the mobile lower‐crustal layer; detailed analysis of fluvial sequences thus contributes unique information in this area.     

Late Quaternary landscape reconstruction and geochronology in the northern Pampas of Buenos Aires province,Argentina

This paper reports the main sedimentary characteristics, soil micromorphology and optically-stimulated luminescence (OSL) ages, and details the pedosedimentary reconstruction, of the Hudson site situated in the northern Pampas of Buenos Aires province. It also provides the OSL chronology and a reinterpretation of previously reported micromorphological features for the nearby site of Gorina. Finally, the stratigraphic records of both sites are compared and the main environmental events discussed in a regional context.At Hudson, situated at a low altitude environment close to the coastal plain, the basal fine-grained paludal deposits were unconformably covered by coastal marine sediments with an OSL age of ca. 128 ka supporting its correlation with the high stand of sea level of marine isotope stage 5e. A paleosol developed on the marine deposits and the underlying paludal sediments. OSL ages suggest that soil development and its subsequent erosion occurred over some period between ca. 128 and 54 ka. Fine sediment accumulation in a paludal environment continued until prior to ca. 23 ka when the accumulation of the uppermost loess mantle started. It continued until the early Holocene when present soil development began. At Gorina, OSL ages suggest that the upper part of the pedocomplex formed at some stage between ca. 194 and 56 ka. Loess then accumulated followed by an erosional phase; loess deposition restarted by ca. 29 ka and continued until the beginning of the Holocene (ca. 9 ka) when the present land surface was established.The stratigraphic and paleoenvironmental differences exhibited by the Hudson and Gorina records result from their contrasting geomorphological settings. The OSL geochronology suggests that the last interglacial (MIS 5) at Hudson is marked by the accumulation of marine deposits (MIS 5e) and the subsequent development of a paleosol. The equivalent soil-forming interval at Gorina is represented by the upper part of the buried pedocomplex. Both at Gorina and Hudson, loess accumulation was dominant especially during MIS 2. Loess accumulation continued during MIS 1 until the early Holocene with apparently somewhat higher sedimentation rates in Hudson. Pedogenesis has been predominant during the rest of the Holocene, resulting in the formation of the surface soil profiles.     

Deep-sea macrourid fishes scavenge on plant material: Evidence from in situ observations

Deep-sea benthic communities primarily rely on an allochthonous food source. This may be in the form of phytodetritus or as food falls e.g. sinking carcasses of nekton or debris of marine macrophyte algae. Deep-sea macrourids are the most abundant demersal fish in the deep ocean. Macrourids are generally considered to be the apex predators/scavengers in deep-sea communities. Baited camera experiments and stable isotope analyses have demonstrated that animal carrion derived from the surface waters is an important component in the diets of macrourids; some macrourid stomachs also contained vegetable/plant material e.g. onion peels, oranges, algae. The latter observations led us to the question: is plant material an attractive food source for deep-sea scavenging fish? We simulated a plant food fall using in situ benthic lander systems equipped with a baited time-lapse camera. Abyssal macrourids and cusk-eels were attracted to the bait, both feeding vigorously on the bait, and the majority of the bait was consumed in <30 h. These observations indicate (1) plant material can produce an odour plume similar to that of animal carrion and attracts deep-sea fish, and (2) deep-sea fish readily eat plant material. This represents to our knowledge the first in situ documentation of deep-sea fish ingesting plant material and highlights the variability in the scavenging nature of deep-sea fishes. This may have implications for food webs in areas where macrophyte/seagrass detritus is abundant at the seafloor e.g. canyon systems and continental shelves close to seagrass meadows (Bahamas and Mediterranean).     

Evaluating roadside rockmasses for rockfall hazards using LiDAR data: optimizing data collection and processing protocols

Highways and railroads situated within rugged terrain are often subjected to the hazard of rockfalls. The task of assessing roadside rockmasses for potential hazards typically involves an on-site visual investigation of the rockmass by an engineer or geologist. At that time, numerous parameters associated with discontinuity orientations and spacing, block size (volume) and shape distributions, slope geometry, and ditch profile are either measured or estimated. Measurements are typically tallied according to a formal hazard rating system, and a hazard level is determined for the site. This methodology often involves direct exposure of the evaluating engineer to the hazard and can also create a potentially non-unique record of the assessed slope based on the skill, knowledge and background of the evaluating engineer. Light Detection and Ranging (LiDAR)–based technologies have the capability to produce spatially accurate, high-resolution digital models of physical objects, known as point clouds. Mobile terrestrial LiDAR equipment can collect, at traffic speed, roadside data along highways and rail lines, scanning continual distances of hundreds of kilometres per day. Through the use of mobile terrestrial LiDAR, in conjunction with airborne and static systems for problem areas, rockfall hazard analysis workflows can be modified and optimized to produce minimally biased, repeatable results. Traditional rockfall hazard analysis inputs include two distinct, but related sets of variables related to geological or geometric control. Geologically controlled inputs to hazard rating systems include kinematic stability (joint identification/orientation) and rock block shape and size distributions. Geometrically controlled inputs include outcrop shape and size, road, ditch and outcrop profile, road curvature and vehicle line of sight. Inputs from both categories can be extracted or calculated from LiDAR data, although there are some limitations and special sampling and processing considerations related to structural character of the rockmass, as detailed in this paper.     

ATLAS, and Wide-Angle Tail Galaxies in ATLAS

Using the Australia Telescope Compact Array (ATCA), ATLAS (Australia Telescope Large Area Survey) is imaging two fields totalling 7 square degrees down to 10 μJy beam^− 1 at 1.4 GHz. We have found 6 wide-angle tail galaxies (WATs), 4 of which have sufficient data to identify associated galaxy overdensities. The largest WAT, at a red-shift of 0.22, appears to be associated with an overdensity of galaxies that is spread over an unusually large extent of 12 Mpc, with a velocity range of 4500 km s^− 1. Here we present the WATs in ATLAS and discuss the implications of these observations for future large-scale radio surveys such as ASKAP-EMU.     

Distance parameterization for efficient seismic history matching with the ensemble Kalman Filter

The availability of multiple history matched models is essential for proper handling of uncertainty in determining the optimal development of producing hydrocarbon fields. The ensemble Kalman Filter in particular is becoming recognized as an efficient method for quantitative conditioning of multiple models to history data. It is known, however, that the ensemble Kalman Filter (EnKF) may have problems with finding solutions in history matching cases that are highly nonlinear and involve very large numbers of data, such is typical when time-lapse seismic surveys are available. Recently, a parameterization of seismic anomalies due to saturation effects was proposed in terms of arrival times of fronts that reduces both nonlinearity and the effective number of data. A disadvantage of the parameterization in terms of arrival times is that it requires simulation of models beyond the update time. An alternative distance parameterization is proposed here for flood fronts, or more generally, for isolines of arbitrary seismic attributes representing a front that removes the need for additional simulation time. An accurate fast marching method for solution of the Eikonal equation in Cartesian grids is used to calculate distances between observed and simulated fronts, which are used as innovations in the EnKF. Experiments are presented that demonstrate the functioning of the method in synthetic 2D and realistic 3D cases. Results are compared with those resulting from use of saturation data, as they could potentially be inverted from seismic data, with and without localization. The proposed algorithm significantly reduces the number of data while still capturing the essential information. It furthermore removes the need for seismic inversion when the oil-water front is only identified, and it produces a more favorable distribution of simulated data, leading to a very efficient and improved functioning of the EnKF.