Use of chemical tracing to study acquisition modalities of the mineralization and behaviour of unconfined groundwaters under a semi-arid climate: the case of the Souss plain (Morocco)

The chemical content of the Souss unconfined groundwater displays spatial variations in conductivity (between 400 and 6,000 µS cm^-1). The chemical tracers (Cl^-, SO₄^2-, Sr²⁺, Br^-), which characterize the different components of the groundwater, allowed the determination of the origin of water salinity. Cl^- and SO₄^2-, reaching respectively 2,000 and 1,650 mg L^-1, display localized salinity anomalies. Br^-/Cl^- ratio distinguishes marine-influenced impoverished zones versus the oceanic domain. Thus, salinity anomalies can be attributed: (1) downstream, to a currently existing salt-encroachment (with added waste water) and sedimentary palaeosalinity, (2) in the middle-Souss, to High Atlas evaporites and to irrigation water recycling. Sr²⁺/Ca²⁺ ratio (evaporites if >1‰), confirms the evaporitic origin of the anomalies along the right bank of oued Souss. Furthermore, it facilitates the distinction between the different aquifer contributions (Cretaceous, Jurassic and Triassic), and it highlights leakage from deep Turonian limestones in the groundwater recharge system. To the south, recharge is from the Anti Atlas (evaporite-free) waters. Oxygen-18 measurements confirm the groundwater recharge from the High and Anti Atlas as piezometric maps and chemical tracers suggested, plus from leakage from the Turonian and the marine aquifers.     

Petrogenesis of Early Neogene Magmatism in the Northern Puna; Implications for Magma Genesis and Crustal Processes in the Central Andean Plateau

New compositional data and petrogenetic models are presentedfor pre-Upper Miocene volcanism in the northern Puna of Argentina(22°S–24°S). Two phases of volcanism producedsmall dome complexes of mainly silicic andesite to low-SiO₂rhyolite. The Upper Oligocene–Lower Miocene phase (UOLM,20–17 Ma), produced two distinct groups of rocks. TheUOLM-1 group is metaluminous and mainly andesitic, with isotopiccompositions like those of the recent arc (⁸⁷Sr/⁸⁶Sr_T     

Crustal Evolution in the SW Part of the Baltic Shield: the Hf Isotope Evidence

The results of a laser ablation microprobe–inductivelycoupled plasma mass spectrometry Lu–Hf isotope study ofzircons in 0·93–1·67 Ga rocks from southNorway indicate that early Proterozoic protoliths of the BalticShield have present-day ¹⁷⁶Hf/¹⁷⁷Hf     

Rate of strike-slip motion on the Amanos Fault (Karasu Valley, southern Turkey) constrained by K–Ar dating and geochemical analysis of Quaternary basalts

The left-lateral Amanos Fault follows a 200-km-long and up to 2-km-high escarpment that bounds the eastern margin of the Amanos mountain range and the western margin of the Karasu Valley in southern Turkey, just east of the northeastern corner of the Mediterranean Sea. Regional kinematic models have reached diverse conclusions as to the role of this fault in accommodating relative motion between either the African and Arabian, Turkish and African, or Turkish and Arabian plates. Local studies have tried to estimate its slip rate by K–Ar dating Quaternary basalts that erupted within the Amanos Mountains, flowed across it into the Karasu Valley, and have since become offset. However, these studies have yielded a wide range of results, ranging from 0.3 to 15 mm a⁻¹, which do not allow the overall role and significance of this fault in accommodating crustal deformation to be determined. We have used the Cassignol K–Ar method to date nine Quaternary basalt samples from the vicinity of the southern part of the Amanos Fault. These basalts exhibit a diverse chemistry, which we interpret as a consequence varying degrees of partial melting of their source combined with variable crustal contamination. This dating allows us to constrain the Quaternary slip rate on the Amanos fault to 1.0 to 1.6 mm a⁻¹. The dramatic discrepancies between past estimates of this slip rate are partly due to technical difficulties in K–Ar dating of young basalts by isotope dilution. In addition, previous studies at the key locality of Hacılar have unwittingly dated different, chemically distinct, flow units of different ages that are juxtaposed. This low slip rate indicates that, at present, the Amanos Fault takes up a small proportion of the relative motion between the African and Arabian plates, which is transferred southward to the Dead Sea Fault Zone. It also provides strong evidence against the long-standing view that its slip continues offshore to the southwest along a hypothetical left-lateral fault zone located south of Cyprus.     

The Quaternary evolution of the Gulf of Corinth, central Greece: coupling between surface processes and flow in the lower continental crust

The Gulf of Corinth in central Greece is an active normal fault zone with particularly clear evidence of isostatic footwall uplift, constrained by Quaternary marine terraces, and hanging-wall subsidence and sedimentation. It is bounded to the south by a Pliocene to Early Pleistocene sedimentary basin, which is now eroding into the Gulf. Previous work has suggested that the relief across this region has increased dramatically since the Early Pleistocene, due to the isostatic response to increased rates of footwall erosion and hanging-wall sedimentation. It is indeed assumed here that incision accompanying the draw-down of global sea-level at 0.9 Ma, during the first major Pleistocene glaciation, initiated the erosion of the basin south of the Gulf of Corinth and so abruptly increased the sedimentation rate in the Gulf. The resulting transient thermal and isostatic response to these changes is modelled, with the subsiding depocentre and eroding sediment source coupled by flow in the lower continental crust. The subsequent enhancement of relief, involving an increase in bathymetry from near zero to 900 m and 500 m of uplift of the eroding land surface in the sediment source, is shown to be a direct consequence of this change. The model is sensitive to the effective viscosity of the lower crust, and can thus resolve this parameter by matching observations. A value of 6×10¹⁹ Pa s is indicated, suggesting a viscosity at the Moho no greater than 10¹⁸ Pa s. Similar transient topographic effects caused by increased rates of sedimentation and erosion are likely to be widespread within the geological record, suggesting that this coupling process involving flow in the weak lower crust may be of major geological and geomorphological importance.     

Microstructural observations on natural syntectonic fibrous veins: implications for the growth process

Syntectonic antitaxial and ataxial fibrous veins were investigated using SEM, microprobe, cathodoluminescence (CL) and optical microscopy. In antitaxial calcite veins, fibres and surrounding selvage grew simultaneously, with similar growth rates of crystallographically differently oriented grains. New material precipitated at the vein margin in antitaxial and bi-mineralic ataxial microstructures. Bridges of country rock material formed during vein growth in an initial en-echelon vein system. In our antitaxial and bi-mineralic ataxial samples, the spacing of solid inclusions does not reflect individual crack-seal openings.     

Paleoliquefaction study of the Clarendon–Linden fault system, western New York State

The lack of earthquake-induced liquefaction features in Late Wisconsin and Holocene sediments in Genesee, Wyoming, and Allegany Counties suggests that the Clarendon–Linden fault system (CLF) did not generate large, moment magnitude, M≥6 earthquakes during the past 12,000 years. Given that it was the likely source of the 1929 M 4.9 Attica earthquake, however, the Clarenden–Linden fault system probably is capable of producing future M5 events. During this study, we reviewed newspaper accounts of the 1929 Attica earthquake, searched for earthquake-induced liquefaction features in sand and gravel pits and along tens of kilometers of river cutbanks, evaluated numerous soft-sediment deformation structures, compiled geotechnical data and performed liquefaction potential analysis of saturated sandy sediments. We found that the 1929 M 4.9 Attica earthquake probably did not induce liquefaction in its epicentral area and may have been generated by the western branch of the Clarendon–Linden fault system. Most soft-sediment deformation structures found during reconnaissance did not resemble earthquake-induced liquefaction features, and even the few that did could be attributed to non-seismic processes. Our analysis suggests that the magnitude threshold for liquefaction is between M 5.2 and 6, that a large (M≥6) earthquake would liquefy sediments at many sites in the area, and that a moderate earthquake (M 5–5.9) would liquefy sediments at some sites but perhaps not at enough sites to have been found during reconnaissance. We conclude that the Clarendon–Linden fault system could have produced small and moderate earthquakes, but probably not large events, during the Late Wisconsin and Holocene.     

The presence, characteristics and earthquake implications of the St. Lawrence fault zone within and near Lake Ontario (Canada–USA)

Questions persist concerning the earthquake potential of the populous and industrial Lake Ontario (Canada–USA) area. Pertinent to those questions is whether the major fault zone that extends along the St. Lawrence River valley, herein named the St. Lawrence fault zone, continues upstream along the St. Lawrence River valley at least as far as Lake Ontario or terminates near Cornwall (Ontario, Canada)–Massena (NY, USA). New geological studies uncovered paleotectonic bedrock faults that are parallel to, and lie within, the projection of that northeast-oriented fault zone between Cornwall and northeastern Lake Ontario, suggesting that the fault zone continues into Lake Ontario. The aforementioned bedrock faults range from meters to tens of kilometers in length and display kinematically incompatible displacements, implying that the fault zone was periodically reactivated in the study area. Beneath Lake Ontario the Hamilton–Presqu'ile fault lines up with the St. Lawrence fault zone and projects to the southwest where it coincides with the Dundas Valley (Ontario, Canada). The Dundas Valley extends landward from beneath the western end of the lake and is marked by a vertical stratigraphic displacement across its width. The alignment of the Hamilton–Presqu'ile fault with the St. Lawrence fault zone strongly suggests that the latter crosses the entire length of Lake Ontario and continues along the Dundas Valley.The Rochester Basin, an east–northeast-trending linear trough in the southeastern corner of Lake Ontario, lies along the southern part of the St. Lawrence fault zone. Submarine dives in May 1997 revealed inclined layers of glaciolacustrine clay along two different scarps within the basin. The inclined layers strike parallel to the long dimension of the basin, and dip about 20° to the north–northwest suggesting that they are the result of rigid-body rotation consequent upon post-glacial faulting. Those post-glacial faults are growth faults as demonstrated by the consistently greater thickness, unit-by-unit, of unconsolidated sediments on the downthrown (northwest) side of the faults relative to their counterparts on the upthrown (southeast) side. Underneath the western part of Lake Ontario is a monoclinal warp that displaces the glacial and post-glacial sediments, and the underlying bedrock–sediment interface. Because of the post-glacial growth faults and the monoclinal warp the St. Lawrence fault zone is inferred to be tectonically active beneath Lake Ontario. Furthermore, within the lake it crosses at least five major faults and fault zones and coexists with other neotectonic structures. Those attributes, combined with the large earthquakes associated with the St. Lawrence fault zone well to the northeast of Lake Ontario, suggest that the seismic risk in the area surrounding and including Lake Ontario is likely much greater than previously believed.     

Thermal expansion and crystal structure of FeSi between 4 and 1173 K determined by time-of-flight neutron powder diffraction

The thermal expansion and crystal structure of FeSi has been determined by neutron powder diffraction between 4 and 1173?K. No evidence was seen of any structural or magnetic transitions at low temperatures. The average volumetric thermal expansion coefficient above room temperature was found to be 4.85(5)?×?10^?5?K^?1. The cell volume was fitted over the complete temperature range using Grüneisen approximations to the zero pressure equation of state, with the internal energy calculated via a Debye model; a Grüneisen second-order approximation gave the following parameters: θ_D=445(11)?K, V ₀=89.596(8)?ų, K ₀′=4.4(4) and γ′=2.33(3), where θ_D is the Debye temperature, V ₀ is V at T=0?K, K ₀′ is the first derivative with respect to pressure of the incompressibility and γ′ is a Grüneisen parameter. The thermodynamic Grüneisen parameter, γ_th, has been calculated from experimental data in the range 4–400?K. The crystal structure was found to be almost invariant with temperature. The thermal vibrations of the Fe atoms are almost isotropic at all temperatures; those of the Si atoms become more anisotropic as the temperature increases.