Removal of river-stage fluctuations from well response using multiple regression

Many contaminated unconfined aquifers are located in proximity to river systems. In groundwater studies, the physical presence of a river is commonly represented as a transient-head boundary that imposes hydrologic responses within the intersected unconfined aquifer. The periodic fluctuation of river-stage height at the boundary produces associated responses within the adjacent aquifer system, the magnitude of which is a function of the existing well, aquifer, boundary conditions, and characteristics of river-stage fluctuations. The presence of well responses induced by the river stage can significantly limit characterization and monitoring of remedial activities within the stress-impacted area. This article demonstrates the use of a time-domain, multiple-regression, convolution (superposition) method to develop well/aquifer river response function (RRF) relationships. Following RRF development, a multiple-regression deconvolution correction approach can be applied to remove river-stage effects from well water-level responses. Corrected well responses can then be analyzed to improve local aquifer characterization activities in support of optimizing remedial actions, assessing the area-of-influence of remediation activities, and determining mean groundwater flow and contaminant flux to the river system.     

Formation of syngenetic and early diagenetic iron minerals in the late Archean Mt. McRae Shale, Hamersley Basin, Australia: New insights on the patterns, controls and paleoenvironmental implications of authigenic mineral formation

A section through the late Archean Mt. McRae Shale comprising, in ascending order, a lower shale interval (LSI), a banded iron formation (BIF), an upper shale (USI) and a carbonate (C1) has been analyzed for total Fe and Al contents and authigenic Fe present as carbonate, oxide, sulfide and silicate phases. The authigenic mineralogy is controlled by the episodic addition of Fe from hydrothermal activity and removal of Fe by sulfide, relative to rates of clastic sedimentation. The LSI and BIF have mean Fe_T/Al values of 2 and 5, respectively, that record iron enrichment from hydrothermal sources. Iron was precipitated primarily as siderite accompanied by Fe-rich chlorite from anoxic bottom waters rich in dissolved Fe. Pyrite formation was probably limited by the availability of sulfate, which was present at low concentrations and became rapidly depleted. The USI has generally lower Fe_T/Al values (0.6-1.3), similar to those found in Paleozoic shales, with the exception of one interval where enrichment may reflect either a weak hydrothermal source or the operation of an iron shuttle. This interval contains authigenic Fe predominantly as pyrite, where high values for DOP (>0.8) indicate the existence of a water column that became rich in dissolved sulfide (euxinic) when sulfate concentrations increased due to a transient or secular increase in ocean/atmosphere oxygenation. High concentrations of dissolved sulfide maintained low concentrations of dissolved Fe, which allowed only minor amounts of Fe to be precipitated as carbonates and silicates. The USI also has elevated concentrations of organic matter that most probably reflect increased productivity and likely limited euxinia to midportions of the water column on the basin margin. The carbonate C1 represents a basinal chemistry where sulfide has been removed and Fe_T/Al values are ∼1 indicating that hydrothermal activity again produced dissolved Fe-rich bottom waters. Detailed iron speciation of the Mt. McRae Shale can be used to recognize spatial and temporal variations in iron and sulfur inputs to the late Archean Hamersley Basin, just prior to the Paleoproterozoic rise in atmospheric oxygenation, and our refined methods have relevance to all Fe-rich deposits.     

Timing of Variscan HP-HT metamorphism in the Moldanubian Zone of the Bohemian Massif: U-Pb SHRIMP dating on multiply zoned zircons from a granulite from the Dunkelsteiner Wald Massif, Lower Austria

In an attempt to better constrain the timing of Variscan HP-HT metamorphism in the SE Bohemian Massif we have dated zoned zircons from a garnet-kyanite granulite of granitic composition from the Dunkelsteiner Wald Massif, Lower Austria, by means of sensitive high-resolution ion microprobe (SHRIMP) technique. In order to combine isotopic information with crystal growth textures, CL and BSE images were systematically taken from the dated zircons. A characteristic threefold concentric zoning was found in many zircons. This involves pre-Variscan protolithic cores followed by two distinct metamorphic/anatectic overgrowth shells of Variscan age. The inner overgrowth shell is characterized by a weak CL but bright BSE signal, and yields high contents of uranium (0.1 to 0.2 wt.%). A pooled U-Pb Concordia age for this zone is 342.0?±?3.0?Ma (n?=?11, MSWD?=?0.12). The second, outer, overgrowth shell is always bright in the CL image, dark in the BSE image, and has generally low uranium contents (mostly <500?ppm). A pooled U-Pb Concordia age for this zone is 337.1?±?2.7?Ma (n?=?11, MSWD?=?0.22). These results imply that the Variscan HT crystallisation history of the Moldanubian granulites took place over a period of a few million years and was not an extremely rapid subduction-exhumation process. SHRIMP measurements in the protolithic cores yield a cluster of (sub)concordant ages between ??390 and 460?Ma and a few outliers at higher ages mostly represented by cores in cores. Core domains, which are large, homogeneous and with undisturbed igneous oscillatory zoning, yielded preferentially ages between 430 and 460?Ma. We therefore consider that granitic protolith formation took place at that time. The still older inner cores are interpreted as inherited into the granitic melt.     

A tree-ring reconstruction of East Anglian (UK) hydroclimate variability over the last millennium

We present an annually resolved reconstruction of spring-summer precipitation variability in East Anglia, UK (52–53°N, 0–2°E) for the period AD 900–2009. A continuous regional network of 723 living (AD 1590–2009) and historical (AD 781–1790) oak (Quercus sp.) ring-width series has been constructed and shown to display significant sensitivity to precipitation variability during the March-July season. The existence of a coherent common growth signal is demonstrated in oaks growing across East Anglia, containing evidence of near-decadal aperiodic variability in precipitation throughout the last millennium. Positive correlations are established between oak growth and precipitation variability across a large region of northwest Europe, although climate-growth relationships appear time transgressive with correlations significantly weakening during the early twentieth century. Examination of the relationship between oak growth, precipitation, and the North Atlantic Oscillation (NAO), reveals no evidence that the NAO plays any significant role in the control of precipitation or tree growth in this region. Using Regional Curve Standardisation to preserve evidence of low-frequency growth variability in the East Anglian oak chronology, we produce a millennial length reconstruction that is capable of explaining 32–35% of annual-to-decadal regional-scale precipitation variance during 1901–2009. The full length reconstruction indicates statistically significant anomalous dry conditions during AD 900–1100 and circa-1800. An apparent prolonged wetter phase is estimated for the twelfth and thirteen centuries, whilst precipitation fluctuates between wetter and drier phases at near centennial timescales throughout the fourteenth to seventeenth centuries. Above average precipitation reconstructed for the twenty-first century is comparable with that reproduced for the 1600s. The main estimated wet and dry phases reconstructed here appear largely coherent with an independent tree-ring reconstruction for southern-central England.     

SCUBA observations of the sources detected in the MAMBO 1200-μm survey

We have observed 23 sources from the Max-Planck Millimetre Bolometer (MAMBO) array 1200-μm survey with SCUBA at 850 μm, detecting 19 of the sources. The sources generally have low values for the ratio of 850- to 1200-μm flux. Two possible explanations for the low values are either that the sources are at very high redshifts or that the global properties of the dust in the MAMBO sources are different from the global properties of dust in low-redshift galaxies. If the former explanation is correct, we estimate that 15 of the MAMBO sources lie at   z > 3  .