Development of Intermediate Microfabric in Kaolin Clay and Its Consolidation Behaviour

The effect of microfabric on the mechanical behaviour of clays has been explored previously based on the response of dispersed and flocculated microfabrics only. However, the natural clays often have the geometric arrangement of particles between these two extreme cases which can be termed as intermediate microfabric. This paper explores the formation of intermediate microfabric of kaolin clay and its impact on soil’s consolidation behaviour by performing self-weight consolidation, slurry consolidation and 1-D consolidation tests. The effect of calgon content (dispersing agent) on geometric arrangement of the particles has been evaluated through cluster size distribution by performing double hydrometer tests. Then these clay slurries have been used to perform the AFM (Atomic Force Microscopy) test to obtain the variation in average angle of particle orientation with respect to the calgon content present in the slurry. AFM technique provides 3D image of the clay sample and 2D image with Z-information with the potential of measuring intermediate microfabric of clayey soil quantitatively including dispersed and flocculated microfabrics. Other traditional techniques such as SEM, TEM & XRD are limited to only qualitative analysis of soil’s microfabric, thus, having no capability to measure intermediate microfabric of clay. A methodology of preparing bulk specimens of clay with intermediate microfabric has been developed using slurry consolidation technique; and then these specimens have been consolidated under 1-D loading to evaluate the effect of intermediate microfabric on compressibility and permeability of clay. In this study, all the experiments reports that the dispersed type geometric arrangement increases with the increase in calgon content in soil up to 2 % and then the reverse behaviour is observed at 3 %; which may depend on the required amount of sodium cations to neutralize the negatively charged faces of the clay platelets present in the slurry.     

Effects of Spatiotemporal Constraints on Geostatistical Analysis of Groundwater Depth

Geostatistical evaluation of the groundwater depth (GWD) in California's South Coast hydrologic region, and its sensitivity to different spatiotemporal assumptions, is presented in this paper. We obtain a pseudo-stationary representation of the groundwater depth, using the publicly available, online database from the GAMA GeoTracker project, while tracking the associated uncertainty throughout the process. We create nine different sub-datasets, using different temporal constraints, such as seasonal partitioning and different long-term variability filtering criteria. The geostatistical analysis and comparison between the different maps highlight the trade-off between spatial and temporal accuracy. For example, when moving to stricter filtering criteria, despite removing a large number of sites from the interpolation, the root mean squared error (RMSE) calculated in the analysis either decreased or only slightly increased. This suggests that the long-term variability filter is a good representation of the GWD accuracy and that the cross-validation RMSE captures both the stability effect as well as spatial density of the measurement points. We further find that the point-specific standard error is strongly correlated with the associated GWD prediction and that the mean relative error is approximately 60% of the prediction. Hence, it is highly recommended to account for such error in a forward-engineering application, by introducing a GWD distribution rather than a single value into the analysis. Finally, we analyze seasonal fluctuations in the study region and find that they are on average 2.5 m with a standard deviation of 8 m.     

Mantle-driven geodynamo features – Effects of compositional and narrow D″ anomalies

Lower mantle heterogeneity could cause deviations from axial symmetry in geodynamo properties. Global tomography models are commonly used to infer the pattern of core–mantle boundary heat flux via a linear relation that corresponds to a purely thermal interpretation of lower mantle seismic anomalies, ignoring both non-thermal origins and non-resolved small scales. Here we study the possible impact on the geodynamo of narrow thermal anomalies in the base of the mantle, originating from either compositional heterogeneity or sharp margins of large-scale features. A heat flux boundary condition composed of a large-scale pattern and narrow ridges separating the large-scale positive and negative features is imposed on numerical dynamos. We find that hot ridges located to the west of a positive large-scale core–mantle boundary heat flux anomaly produce a time-average narrow elongated upwelling, a flow barrier at the top of the core and intensified low-latitudes magnetic flux patches. When the ridge is located to the east of a positive core–mantle boundary heat flux anomaly, the associated upwelling is weaker and the homogeneous dynamo westward drift leaks, precluding persistent intense low-latitudes magnetic flux patches. These signatures of the core–mantle boundary heat flux ridge are evident in the north–south component of the thermal wind balance. Based on the pattern of lower mantle seismic tomography (Masters et al., 2000), we hypothesize that hot narrow thermal ridges below central Asia and the Indian Ocean and below the American Pacific coast produce time-average fluid upwelling and a barrier for azimuthal flow at the top of the core. East of these ridges, below east Asia and Oceania and below the Americas, time-average intense geomagnetic flux patches are expected.     

The climatic and physiographic controls of the eastern Mediterranean over the late Pleistocene climates in the southern Levant and its neighboring deserts

Modern-day synoptic-scale eastern Mediterranean climatology provides a useful context to synthesize the diverse late Pleistocene (60–12 ka) paleohydrologic and paleoenvironmental indicators of past climatic conditions in the Levant and the deserts to its south and east. We first critically evaluate, extract, and summarize paleoenvironmental and paleohydrologic records. Then, we propose a framework of eastern Mediterranean atmospheric circulation features interacting with the morphology and location of the southeast Mediterranean coast. Together they strongly control the spatial distribution of rainfall and wind pattern. This cyclone–physiography interaction enforces the observed rainfall patterns by hampering rainfall generation south and southeast of the latitude of the north Sinai coast, currently at 31°15′.The proposed framework explains the much-increased rains in Lebanon and northern Israel and Jordan as deduced from pollen, rise and maintenance of Lake Lisan, and speleothem formation in areas currently arid and semiarid. The proposed framework also accounts for the southward and eastward transition into semiarid, arid, and hyperarid deserts as expressed in thick loess accumulation at the deserts' margins, dune migration from west to east in the Sinai and the western Negev, and the formation of hyperarid (< 80 mm yr^− 1) gypsic–salic soils in the southern Negev and Sinai. Our climatic synthesis explains the hyperarid condition in the southern Negev, located only 200–250 km south of the much-increased rains in the north, probably reflecting a steeper rainfall gradient than the present-day gradient from the wetter Levant into its bordering southern and eastern deserts.At present, the rainiest winter seasons in Lebanon and northern and central Israel are associated with more frequent (+ 20%), deeper Cyprus Lows traversing the eastern Mediterranean at approximately the latitude of southern Turkey. Even these wettest years in northern Israel do not yield above average annual rainfall amounts in the hyperarid southern Negev. This region is mainly influenced by the Active Red Sea Troughs that produce only localized rains. The eastern Mediterranean Cyprus Lows also produce more dust storms and transport higher amounts of suspended dust to the loess area than any other atmospheric pattern. Concurrent rainfall and dust are essential to the late Pleistocene formation of the elongated thick loess zone along the desert northern margin. Even with existing dust storms, the lack of rain and very sparse vegetation account for the absence of late Pleistocene loess sequences from the southern Negev and the formation of hyperarid soils.When the north Sinai coast shifted 30–70 km northwest due to last glacial global sea level lowering, the newly exposed coastal areas supplied the sand and dust to these active eastern Mediterranean cyclones. This enforced the latitude of the northern boundary of the loess zone to be directly due east of the LGM shoreline. This shift of coast to the northwest inhibited rainfall in the southern Levant deserts and maintained their hyperaridity. Concurrently, frequent deep eastern Mediterranean Cyprus Lows were funneled along the northern Mediterranean increasing (probably doubling) the rains in central and northern Israel, Lebanon, southwestern Syria and northern Jordan. These storms and rains formed lakes, forests, and speleothems only a short distance north of the deserts in the southern Levant.     

Evolution and degradation of flat‐top mesas in the hyper‐arid Negev,Israel revealed from 10Be cosmogenic nuclides

Mesas are ubiquitous landforms in arid and semiarid regions and are often characterized by horizontal stratified erodible rocks capped by more resistant strata. The accepted conceptual model for mesa evolution and degradation considers reduction in the width of the mesa flat‐top plateau due to cliff retreat but ignores possible denudation of the mesa flat‐top and the rates and mechanism of erosion. In this study we examine mesas in the northeastern hyperarid Negev Desert where they appear in various sizes and morphologies and represent different stages of mesa evolution. The variety of mesas within a single climatic zone allows examination of the process of mesa evolution through time. Two of the four sites examined are characterized by a relatively wide (200–230 m) flat‐top and a thick caprock whereas the other two are characterized by a much narrower remnant flat‐top (several meters) and thinner caprock. We use the concentration of the cosmogenic nuclide ¹⁰Be for: (a) determining the chronology of the various geomorphic features associated with the mesa; and (b) understanding geomorphic processes forming the mesa. The ¹⁰Be data, combined with field observations, suggest a correlation between the width of flat‐top mesa and the denudation and cliff retreat rates. Our results demonstrate that: (a) cliff retreat rates decrease with decreasing width of the flat‐top mesa; (b) vertical denudation rates increase with decreasing width of the flat‐top mesa below a critical value (~60 m, for the Negev Desert); (c) the reduction in the width of the flat‐top mesa is driven mainly by cliff retreat accompanied by extremely slow vertical denudation rate which can persist for a very long time (>10⁶ Ma); and (d) when the width of the mesa decreases below a certain threshold, its rate of denudation increases dramatically and mesa degradation is completed in a short time. Copyright © 2014 John Wiley & Sons, Ltd.     

Periodic orbits in the photogravitational restricted problem with the smaller primary an oblate body

In this paper, we have studied periodic orbits generated by Lagrangian solutions of the restricted three body problem when more massive body is a source of radiation and the smaller primary is an oblate body. We have determined periodic orbits for fixed values of μ, σ and different values of p and h (μ mass ratio of the two primaries, σ oblate parameter, p radiation parameter and h energy constant). These orbits have been determined by giving displacements along the tangent and normal to the mobile co-ordinates as defined by Karimov and Sokolsky (in Celest. Mech. 46:335, 1989). These orbits have been drawn by using the predictor-corrector method. We have also studied the effect of radiation pressure on the periodic orbits by taking some fixed values of μ and σ.     

Modeling of Stone Column-Supported Embankment Under Axi-Symmetric Condition

In the present work, a simplified model has been developed to study the behavior of stone column-supported embankment under axi-symmetric loading condition. The rate of consolidation of stone column-reinforced soft ground under axi-symmetric condition has also been presented in the paper. Mechanical model elements such as Pasternak shear layer, spring–dashpot system are used to model the different components such as granular layer, soft soil, stone columns etc. The governing differential equations are solved by finite difference technique. Parametric study has also been carried out to show the effect of different model variables on the settlement, stress concentration ratio of the foundation system. It is observed that for lower diameter ratio, at a particular time, the degree of consolidation predicted by the present method for axi-symmetric loading condition is almost same or lower than the degree of consolidation obtained by unit cell approach, but as the diameter ratio increases present analysis predicts higher degree of consolidation as compared to the unit cell approach. The maximum settlement decreases as the modular ratio increases and beyond the modular ratio value 30, the reduction rate of settlement decreases.     

Petrogenesis of olivine-phyric shergottite Larkman Nunatak 06319: Implications for enriched components in martian basalts

We report on the petrography and geochemistry of the newly discovered olivine-phyric shergottite Larkman Nunatak (LAR) 06319. The meteorite is porphyritic, consisting of megacrysts of olivine (?2.5 mm in length, Fo_77-52) and prismatic zoned pyroxene crystals with Wo₃En₇₁ in the cores to Wo_8-30En_23-45 at the rims. The groundmass is composed of finer grained olivine (<0.25 mm, Fo_62-46), Fe-rich augite and pigeonite, maskelynite and minor quantities of chromite, ulvöspinel, magnetite, ilmenite, phosphates, sulfides and glass. Oxygen fugacity estimates, derived from the olivine-pyroxene-spinel geo-barometer, indicate that LAR 06319 formed under more oxidizing conditions (QFM -1.7) than for depleted shergottites. The whole-rock composition of LAR 06319 is also enriched in incompatible trace elements relative to depleted shergottites, with a trace-element pattern that is nearly identical to that of olivine-phyric shergottite NWA 1068. The oxygen isotope composition of LAR 06319 (Δ¹⁷O = 0.29 ±0.03) confirms its martian origin.Olivine megacrysts in LAR 06319 are phenocrystic, with the most Mg-rich megacryst olivine being close to equilibrium with the bulk rock. A notable feature of LAR 06319 is that its olivine megacryst grains contain abundant melt inclusions hosted within the forsterite cores. These early-trapped melt inclusions have similar trace element abundances and patterns to that of the whole-rock, providing powerful evidence for closed-system magmatic behavior for LAR 06319. Calculation of the parental melt trace element composition indicates a whole-rock composition for LAR 06319 that was controlled by pigeonite and augite during the earliest stages of crystallization and by apatite in the latest stages. Crystal size distribution and spatial distribution pattern analyses of olivine indicate at least two different crystal populations. This is most simply interpreted as crystallization of megacryst olivine in magma conduits, followed by eruption and subsequent crystallization of groundmass olivine.LAR 06319 shows close affinity in mineral and whole-rock chemistry to olivine-phyric shergottite, NWA 1068 and the basaltic shergottite NWA 4468. The remarkable features of these meteorites are that they have relatively similar quantities of mafic minerals compared with olivine-phyric shergottites (e.g., Y-980459, Dho 019), but flat and elevated rare earth element patterns more consistent with the LREE-enriched basaltic shergottites (e.g., Shergotty, Los Angeles). This relationship can be interpreted as arising from partial melting of an enriched mantle source and subsequent crystal-liquid fractionation to form the enriched olivine-phyric and basaltic shergottites, or by assimilation of incompatible-element enriched martian crust. The similarity in the composition of early-trapped melt inclusions and the whole-rock for LAR 06319 indicates that any crustal assimilation must have occurred prior to crystallization of megacryst olivine, restricting such processes to the deeper portions of the crust. Thus, we favor LAR06319 forming from partial melting of an “enriched” and oxidized mantle reservoir, with fractional crystallization of the parent melt upon leaving the mantle.     

Amphibole—a key indicator mineral for petrogenesis of the Purulia carbonatite, West Bengal, India

The Purulia carbonatite of West Bengal, India is a dyke occurring within the 100 km long South Purulia Shear Zone (SPSZ), which marks the boundary between the Singhbhum Group of Rocks and the Chhotanagpur Granite Gneissic Complex (CGGC). It is composed essentially of calcite with apatite, amphibole, phlogopite, biotite, magnetite and ilmenite as common accessories. Based on optical properties and mineral chemistry two varieties of the amphibole are recognized: magnesiokatophorite and richterite. The latter is characterized by a relatively high content of Si and Na, while the former is enriched in Al and Ca. Such a composition of the amphibole is characteristic for the intermediate to the late stage carbonatite development. These two co-existing amphiboles reflect a sudden variation in total pressure within the magma chamber during the intrusion of the carbonatite dyke. It is inferred that the magnesiokatophorite started crystallizing first along with calcite and apatite. Subsequently, the ascent of carbonatitic magma to a more shallow depth (hypabyssal) resulted in the formation of the richterite. The difference in amphibole composition reflects a variation in the total pressure within the magma chamber that took place during the formation of the Purulia carbonatite. However, an alternative explanation, such as wallrock contamination, or liquid immiscibility, followed by carbonate magma segregation or magma mixing, may also be possible. There is, however, no evidence corroborating such an interpretation.