Petrogenesis of olivine-phyric shergottite Larkman Nunatak 06319: Implications for enriched components in martian basalts

We report on the petrography and geochemistry of the newly discovered olivine-phyric shergottite Larkman Nunatak (LAR) 06319. The meteorite is porphyritic, consisting of megacrysts of olivine (?2.5 mm in length, Fo_77-52) and prismatic zoned pyroxene crystals with Wo₃En₇₁ in the cores to Wo_8-30En_23-45 at the rims. The groundmass is composed of finer grained olivine (<0.25 mm, Fo_62-46), Fe-rich augite and pigeonite, maskelynite and minor quantities of chromite, ulvöspinel, magnetite, ilmenite, phosphates, sulfides and glass. Oxygen fugacity estimates, derived from the olivine-pyroxene-spinel geo-barometer, indicate that LAR 06319 formed under more oxidizing conditions (QFM -1.7) than for depleted shergottites. The whole-rock composition of LAR 06319 is also enriched in incompatible trace elements relative to depleted shergottites, with a trace-element pattern that is nearly identical to that of olivine-phyric shergottite NWA 1068. The oxygen isotope composition of LAR 06319 (Δ¹⁷O = 0.29 ±0.03) confirms its martian origin.Olivine megacrysts in LAR 06319 are phenocrystic, with the most Mg-rich megacryst olivine being close to equilibrium with the bulk rock. A notable feature of LAR 06319 is that its olivine megacryst grains contain abundant melt inclusions hosted within the forsterite cores. These early-trapped melt inclusions have similar trace element abundances and patterns to that of the whole-rock, providing powerful evidence for closed-system magmatic behavior for LAR 06319. Calculation of the parental melt trace element composition indicates a whole-rock composition for LAR 06319 that was controlled by pigeonite and augite during the earliest stages of crystallization and by apatite in the latest stages. Crystal size distribution and spatial distribution pattern analyses of olivine indicate at least two different crystal populations. This is most simply interpreted as crystallization of megacryst olivine in magma conduits, followed by eruption and subsequent crystallization of groundmass olivine.LAR 06319 shows close affinity in mineral and whole-rock chemistry to olivine-phyric shergottite, NWA 1068 and the basaltic shergottite NWA 4468. The remarkable features of these meteorites are that they have relatively similar quantities of mafic minerals compared with olivine-phyric shergottites (e.g., Y-980459, Dho 019), but flat and elevated rare earth element patterns more consistent with the LREE-enriched basaltic shergottites (e.g., Shergotty, Los Angeles). This relationship can be interpreted as arising from partial melting of an enriched mantle source and subsequent crystal-liquid fractionation to form the enriched olivine-phyric and basaltic shergottites, or by assimilation of incompatible-element enriched martian crust. The similarity in the composition of early-trapped melt inclusions and the whole-rock for LAR 06319 indicates that any crustal assimilation must have occurred prior to crystallization of megacryst olivine, restricting such processes to the deeper portions of the crust. Thus, we favor LAR06319 forming from partial melting of an “enriched” and oxidized mantle reservoir, with fractional crystallization of the parent melt upon leaving the mantle.     

Amphibole—a key indicator mineral for petrogenesis of the Purulia carbonatite, West Bengal, India

The Purulia carbonatite of West Bengal, India is a dyke occurring within the 100 km long South Purulia Shear Zone (SPSZ), which marks the boundary between the Singhbhum Group of Rocks and the Chhotanagpur Granite Gneissic Complex (CGGC). It is composed essentially of calcite with apatite, amphibole, phlogopite, biotite, magnetite and ilmenite as common accessories. Based on optical properties and mineral chemistry two varieties of the amphibole are recognized: magnesiokatophorite and richterite. The latter is characterized by a relatively high content of Si and Na, while the former is enriched in Al and Ca. Such a composition of the amphibole is characteristic for the intermediate to the late stage carbonatite development. These two co-existing amphiboles reflect a sudden variation in total pressure within the magma chamber during the intrusion of the carbonatite dyke. It is inferred that the magnesiokatophorite started crystallizing first along with calcite and apatite. Subsequently, the ascent of carbonatitic magma to a more shallow depth (hypabyssal) resulted in the formation of the richterite. The difference in amphibole composition reflects a variation in the total pressure within the magma chamber that took place during the formation of the Purulia carbonatite. However, an alternative explanation, such as wallrock contamination, or liquid immiscibility, followed by carbonate magma segregation or magma mixing, may also be possible. There is, however, no evidence corroborating such an interpretation.     

Oldest Asian Record of Snapping Shrimps (Malacostraca: Alpheidae) from the Kutch Basin, Western India and Associated Biota: Biostratigraphic, Paleoenvironmental and Paleoecological Significance

The oldest Asian record of alpheid shrimps, assigned to genus Alpheus, based on snapping claw fingertips from the Miocene Khari Nadi Formation in the Kutch Basin, western India reported herein, extends the fossil record of the family Alpheidae from Asia by ~22 million years. An early Miocene (Aquitanian) age is estimated based on the associated assemblage of calcareous nannofossils, Sphenolithus disbelemnos, Cyclicargolithus floridanus, and Reticulofenestra haqii. The co-occurring microbiota includes bony fish otolith remains, identified as “genus Gobiidarum”, isolated teeth of Dasyatis rays, Sphyrna sharks, and teleosts, ctenoid and placoid scales, ostracods, belonging to the genera Paractinocythereis, Alocopocythere, Ruggieria? Aglaiocypris, Bairdoppilata, and echinoid spines. Taken together, the microfossil assemblage and data from chemical analyses using Energy Dispersive Spectroscopy, X-Ray Diffraction and Wavelength Dispersive X-Ray Fluorescence of host and associated lithologies suggests prevalence of a shallow (neritic) to coastal marine (intertidal) depositional paleoenvironment.     

Use of shredded tyre waste in improving the geotechnical properties of expansive black cotton soil

In recent years, geotechnical engineers are using tyre waste to alter the properties of soil for providing sustainable solutions to complex engineering problems. It is noted that black cotton soil, which is expansive in nature, covers a major portion of the Indian sub-continent, such as the Deccan plateau, Malwa plateau and a portion of Gujarat and poses challenging problems to infrastructural development in the region. In the present study, authors have characterised the geotechnical properties of black cotton soil, which is partially replaced with 4.75 mm passing – 2 mm retained (coarse fraction) and 2.0 mm passing - 75 micron retained (fine fraction) shredded tyre waste. The results of the experimental studies clearly show that partial replacement of black cotton soil with shredded tyre waste alters the geotechnical properties favourable to engineering applications and greatly reduces the swelling potential of the black cotton soil. It is noted that instead of fine fraction (2.0–0.075 mm), replacement with coarse fraction (4.75–2.00 mm) of shredded tyre waste can better be used for light weight fill behind the retaining walls as well as for embankment construction as it helps in reducing swelling pressure as well as improving the strength properties.     

Using temperature to test models of flow near Yucca Mountain,Nevada

Ground water temperatures in the fractured volcanic aquifer near Yucca Mountain, Nevada, have previously been shown to have significant spatial variability with regions of elevated temperatures coinciding roughly with near-vertical north-south trending faults. Using insights gained from one-dimensional models, previous investigators have suggested upwelling along faults from an underlying aquifer as a likely explanation for this ground water temperature pattern. Using a three-dimensional coupled flow and heat-transport model, we show that the thermal high coinciding with the Paintbrush fault zone can be explained without significant upwelling from the underlying aquifer. Instead, the thermal anomaly is consistent with thermal conduction enhanced slightly by vertical ground water movement within the volcanic aquifer sequence. If more than approximately 400 m3/day of water enters the volcanic aquifer from below along a 10 km fault zone, the calculated temperatures at the water table are significantly greater than the measured temperatures. These results illustrate the potential limitations in using one-dimensional models to interpret ground water temperature data, and underscore the value in combining temperature data with fully coupled three-dimensional simulations.     

The development of a physiologically-based pharmacokinetic model using the distribution of 2,3,7,8-tetrachlorodibenzo-p-dioxin in the tissues of the eastern oyster (Crassostrea virginica)

A physiologically-based pharmacokinetic model (PBPK) was developed to describe the kinetics of 2,3,7,8-tetrachlorodibenzo-p-dioxin (TCDD) in the eastern oyster (Crassostrea virginica). The estimated t(1/2) of elimination for a bolus dose of TCDD in C. virginica is approximately 14-24 days based on both the experimental data and the PBPK model. The highest dioxin concentration reached during 28-days was in the digestive gland followed by the mantle, gonad, hemolymph, gill, adductor muscle, and the kidney/heart. A binding protein for 2,3,7,8-TCDD had been reported in the literature for both the digestive gland and gonad. Incorporating a binding component in the model resulted in a better fit for the data. The PBPK model predicted the distribution and the elimination concentrations for 2,3,7,8-TCDD within each of the tissue compartments. This model will serve as a useful tool for predicting the kinetics of other persistent organic pollutants as well as, allow for a more refined ecological risk assessment by estimating dioxin concentrations in sensitive tissues such as the gonad.     

Effectiveness and efficiency of climate change mitigation in a technologically uncertain World

Following a multi-scenario framework based on the technology assumptions proposed by the 27th Energy Modeling Forum (EMF-27), our analysis focuses on analyzing the impacts of key technology assumptions on climate policies, including the interdependencies of different technological options. Each scenario may be considered as either a possible state of nature upon which one has no influence, each scenario thus dictating the availability (or non availability) of some subset of the technology groups, or as an opportunity for society, by its own actions and policies, to influence the availability of said technology group. The main insights obtained from the assessment show the prominent role of bioenergy as a means to abate greenhouse gas emissions, irrespective of other technological developments, while the role of the other technologies (wind and solar, carbon capture and sequestration, nuclear) are more dependent of one another. It appears that CCS may play a sort of “backstop” role: it compensates for a lower contribution of solar and wind, or of nuclear. This means that an increased social acceptability of one (or all) of these three sets of technology should be at the heart of future climate policies. The costs caused by the adaptation of electricity networks to accommodate a high fraction of intermittent sources would deserve more attention in future research.     

Modeling Short-Term Spatial and Temporal Variability of Groundwater Level Using Geostatistics and GIS

Continuous depletion of groundwater levels from deliberate and uncontrolled exploitation of groundwater resources lead to the severe problems in arid and semi-arid hard-rock regions of the world. Geostatistics and geographic information system (GIS) have been proved as successful tools for efficient planning and management of the groundwater resources. The present study demonstrated applicability of geostatistics and GIS to understand spatial and temporal behavior of groundwater levels in a semi-arid hard-rock aquifer of Western India. Monthly groundwater levels of 50 sites in the study area for 36-month period (May 2006 to June 2009; excluding 3 months) were analyzed to find spatial autocorrelation and variances in the groundwater levels. Experimental variogram of the observed groundwater levels was computed at 750-m lag distance interval and the four most-widely used geostatistical models were fitted to the experimental variogram. The best-fit geostatistical model was selected by using two goodness-of-fit criteria, i.e., root mean square error (RMSE) and correlation coefficient (r). Then spatial maps of the groundwater levels were prepared through kriging technique by means of the best-fit geostatistical model. Results of two spatial statistics (Geary’s C and Moran’s I) indicated a strong positive autocorrelation in the groundwater levels within 3-km lag distance. It is emphasized that the spatial statistics are promising tools for geostatistical modeling, which help choose appropriate values of model parameters. Nugget-sill ratio (<0.25) revealed that the groundwater levels have strong spatial dependence in the area. The statistical indicators (RMSE and r) suggested that any of the three geostatistical models, i.e., spherical, circular, and exponential, can be selected as the best-fit model for reliable and accurate spatial interpolation. However, exponential model is used as the best-fit model in the present study. Selection of the exponential model as the best-fit was further supported by very high values of coefficient of determination (r ² ranging from 0.927 to 0.994). Spatial distribution maps of groundwater levels indicated that the groundwater levels are strongly affected by surface topography and the presence of surface water bodies in the study area. Temporal pattern of the groundwater levels is mainly controlled by the rainy-season recharge and amount of groundwater extraction. Furthermore, it was found that the kriging technique is helpful in identifying critical locations over the study area where water saving and groundwater augmentation techniques need to be implemented to protect depleting groundwater resources.