Sample treatment with focused ultrasound and bath sonication as a powerful tool for the evaluation of cadmium pollution in estuarine waters

A new sample treatment was developed for the determination of dissolved cadmium in Tagus estuarine waters, based on focused ultrasound in conjunction with small volumes in the extraction steps for Cd pre-concentration. Cadmium was first pre-concentrated using a classical approach (APDC as the complexing agent and MIBK as the organic phase) and then back-extracted into HNO₃ with the aid of focused ultrasound, which reduced the acid concentration by more than one order of magnitude (from 4 to 0.1 mol L^− 3). This sample treatment was accomplished in less than 5 min, using low sample volume (20 mL), and low-volume, low-concentration reagents. The pre-concentration factor used in this work was 25, but different sample/organic volume ratios may be used in order to increase that value. The limit of detection and the limit of quantification in Tagus water samples were 0.03 nmol L^− 1 and 0.1 nmol L^− 3, respectively. Recoveries from spiked Tagus water were higher than 90%. The procedure was validated using the reference estuarine water NRC-SLEW-3. In the solubilization of Cd particulate, bath ultrasonication was used in conjunction with HNO₃ + HCl, followed by H₂O₂, which took about 2 instead of the usual 12 h (cooling included) when high-pressure microwave digestion is used.     

Light curve analysis of the short period eclipsing binary RT and

We have analysed the 1978 UBV photoelectric observations of the short-period (RS CVn type) binary system RT And, using the rectifiable methods of Russell and Merrill (1952) and Kitamura (1965). The primary minimum is a transit. The solutions allow us to classify the system as a detached one, but a certain disagreement results with respect to solutions of previous epochs. A graphical test of the reliability of the solution is given.     

Theoretical wind wave frequency spectra in deep water——Ⅰ. Form of spectrum

In this part ot the paper theoretical wind-wave spectra nave been derived oy (I) expressing the spectrum in series composed of exponential terms; (2) assuming that the spectrum satisfies a high order linear ordinary differential equation; (3) introducing proper parameters in the spectrum; and (4) making use of some known charateristics of wind-wave spectrum, for instance, the law governing the equilibrium range. The spectrum obtained contains the zero order moment of the spectrum m0, the peak frequency ω0 and the ratio R =ω/ω0 (ω being the mean zero-crossing frequency) as parameters. The shape of the nondimensional spectrum S(ω) = ω0S(ω)/m0(ω=ω/ω0) changes with R and theoretically reduces to a Dirac delta function δ(ω-1) when R = 1. A spectrum of simplified form is given for practical uses, in which R is replaced by a peakness factor P=S(1).     

Seismic bearing capacity of shallow strip footings

Seismic bearing capacity of shallow strip footings in soil has been obtained in the form of pseudo-static seismic bearing capacity factors N_cd, N_qd and N_d, denoting the cohesion, surcharge and unit weight components, respectively, by an extensive numerical iteration technique. Limit equilibrium method of analysis with composite failure surface is assumed. The validity of the principle of superposition is examined. Effects of both the horizontal and vertical seismic acceleration coefficients have been found to always reduce the ultimate bearing capacity significantly. Results obtained by the present method of analysis are compared with the available results and are found to be the least in the seismic case.     

The Stress–Strain State of Recent Structures in the Northeastern Sector of the Russian Arctic Region

Doklady Earth Sciences - Complex research to determine the stress–strain state of the Earth’s crust and the types of seismotectonic destruction for the northeastern sector of the...     

Geology of the Acropolis prospect,South Australia,constrained by high-precision CA-TIMS ages

Abstract

Acropolis is an Fe-oxide–copper–gold prospect ～20?km from Olympic Dam, South Australia, and marked by near-coincident gravity and magnetic anomalies. Prospective Fe-oxide–apatite?±?sulfide veins occur in Mesoproterozoic and Paleoproterozoic volcanic and granitoid host units beneath unmineralised sedimentary formations. We have produced a geological map and history of the prospect using data from 16 diamond drill holes, including LA-ICPMS and high-precision CA-TIMS ages. The oldest unit is megacrystic granite of the Donington Suite (ca 1850?Ma). A non-conformity spanning ca 250 My separates the Donington Suite and felsic lavas and ignimbrites of the Gawler Range Volcanics (GRV; 1594.03?±?0.68?Ma). The GRV were intruded by granite of the Hiltaba Suite (1594.88?±?0.50?Ma) and felsic dykes (1593.88?±?0.56?Ma; same age as the Roxby Downs Granite at Olympic Dam). The felsic dykes are weakly altered and lack Fe-oxide–apatite–sulfide veins, suggesting that they post-date the main hydrothermal event. If correct, this relationship implies that the main hydrothermal event at Acropolis was ca 1594?Ma and pre-dated the main hydrothermal event at Olympic Dam. The GRV at Acropolis are the same age as the GRV at Olympic Dam and ca 3–7 My older than the GRV exposed in the Gawler Ranges. The gravity and magnetic anomalies coincide with sections through the GRV, Hiltaba Suite and Donington Suite that contain abundant, wide, Fe-oxide veins. The GRV, Hiltaba Suite and Donington Suite are unconformably overlain by the Mesoproterozoic Pandurra Formation or Neoproterozoic Stuart Shelf sedimentary formations. The Pandurra Formation shows marked lateral variations in thickness related to paleotopography on the underlying units and post-Pandurra Formation pre-Neoproterozoic faults. The Stuart Shelf sedimentary formations have uniform thicknesses.

1. KEY POINTS

2. Fe-oxide–apatite?±?sulfide veins are hosted by the Gawler Range Volcanics (1594.03?±?0.68?Ma), the Hiltaba Suite granite (1594.88?±?0.50?Ma) and Donington Suite granite (ca 1850?Ma).

3. The age of felsic dykes (1593.88?±?0.56?Ma) interpreted to be post-mineralisation implies that the main hydrothermal event at Acropolis was ca 1594?Ma.

4. The Gawler Range Volcanics at Acropolis are the same age as the Gawler Range Volcanics at Olympic Dam and ca 3 to 7 My older than the Gawler Range Volcanics exposed in the Gawler Ranges.

     

Richtmyer-Meshkov Experiments on the Omega Laser

Observations of the interstellar medium reveal a dynamic realm permeated by shocks. These shocks are generated on a large range of scales by galactic rotation, supernovae, stellar winds, and other processes. Whenever a shock encounters a density interface, Richtmyer-Meshkov instabilities may develop. Perturbations along the interface grow, leading to structure formation and material mixing. An understanding of the evolution of Richtmyer-Meshkov instabilities is essential for understanding galactic structure, molecular cloud morphology, and the early stages of star formation. An ongoing experimental campaign studies Richtmyer-Meshkov mixing in a convergent, compressible, miscible plasma at the Omega laser facility. Cylindrical targets, consisting of a low density foam core and an aluminum shell covered by an epoxy ablator, are directly driven by fifty laser beams. The aluminum shell is machined to produce different perturbation spectra. Surface types include unperturbed (smooth), single-mode sinusoids, multi-mode (rough), and multi-mode with particular modes accentuated (specified-rough). Experimental results are compared to theory and numerical simulations.     

Photometric monitoring of 2060 Chiron''s brightness at perihelion

The results of photometric and spectroscopic observations of comet/asteroid 2060 Chiron carried on at the Observatório do Pico-dos-Dias (Brazil), at the European Southern Observatory (Chile) and at the Mauna Kea Observatory (Hawaii) during 1996 are presented. The analysis of the photometric data shows that even at a minimum of brightness 2060 Chiron presents some activity. The absolute magnitude, H_v, varied from 6.79 in February to 6.22 in March. Therefore 2060 Chiron is still in a minimum of activity close to that of 1983–1985 and of 1994–1995.     

Chemical and mineralogical characterization of the Mineo (Sicily,Italy) pallasite: A unique sample

The Mineo pallasite is characterized here for the first time. The only 42 g still available worldwide is part of the collection of the Department of Physics and Geology, University of Perugia. A multianalytical approach was used, joining field-emission scanning electron microscopy, Raman analysis, X-ray powder diffraction, electron-probe microanalysis, and laser ablation inductively coupled plasma mass spectrometry. Results highlighted that (1) the Mineo pallasite belongs to the Main Group pallasites; (2) the silicate component is essentially olivine, with no pyroxene component; (3) the olivine chemical composition varies in terms of both iron and trace elements; (4) the metal phase is essentially kamacite with the taenite mainly found in the plessite structure; (5) phosphide phases are present as schreibersite and barringerite. The observed compositional variability in olivines as well as their occurrence as both angular and rounded crystals suggest that the Mineo pallasite could have been derived from a large impact of a differentiated parent body with a larger solid body. The resulting pallasite conglomerate consists of the compositionally different olivines, likely coming from different areas of the same differentiated parent body, and the residual molten Fe-Ni.     

Sedimentary and tectonic evolution of Lake Ohrid (Macedonia/Albania)

Lake Ohrid, located on the Balkan Peninsula within the Dinaride–Albanide–Hellenide mountain belt, is a tectonically active graben within the South Balkan Extensional Regime (SBER). Interpretation of multichannel seismic cross sections and bathymetric data reveals that Lake Ohrid formed during two main phases of deformation: (1) a transtensional phase which opened a pull‐apart basin, and (2) an extensional phase which led to the present geometry of Lake Ohrid. After the initial opening, a symmetrical graben formed during the Late Miocene, bounded by major normal faults on each side in a pull‐apart type basin. The early‐stage geometry of the basin has a typical rhomboidal shape restricted by two sets of major normal faults. Thick undisturbed sediments are present today at the site where the acoustic basement is deepest, illustrating that Lake Ohrid is a potential target for drilling a long and continuous sediment core for studying environmental changes within the Mediterranean region. Neotectonic activity since the Pliocene takes place along the roughly N–S‐striking Eastern and Western Major Boundary Normal Faults that are partly exposed at the present lake floor. The tectono‐sedimentary structure of the basin is divided into three main seismic units overlying the acoustic basement associated with fluvial deposits and lacustrine sediments. A seismic facies analysis reveals a prominent cyclic pattern of high‐ and low‐amplitude reflectors. We correlate this facies cyclicity with vegetation changes within the surrounding area that are associated with glacial/interglacial cycles. A clear correlation is possible back to ca. 450 kyrs. Extrapolation of average sedimentation rates for the above mentioned period results in age estimate of ca. 2 Myrs for the oldest sediments in Lake Ohrid.