Electrical conductivity of some rocks from the Indian subcontinent

Summary Results on electrical conductivity, chemical analysis and age of the rock samples from the Indian Subcontinent are presented. The old Precambrian Indian rocks tend to be less conductive than characteristic rocks of crustal and upper mantle structures.

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Evaluation of ferrous and ferric Mössbauer fractions

The Mössbauer fractions f for various ferrous- and/or ferric-containing oxides and oxyhydroxides, silicates and carbonates were evaluated from the experimental temperature dependence of their center shifts, using the Debye approximation for the second-order Doppler shift. It is concluded that ferrous ions exhibit a lower fraction as compared to ferric ions. Using standard mixtures of -Fe₂O₃ with selected Fe²⁺ or Fe³⁺ compounds, it is found that the calculated Fe³⁺ f values are somewhat overestimated with respect to those of Fe²⁺. Possible explanations for this shortcoming are discussed and it is suggested that a different temperature dependence of the intrinsic isomer shift is the most likely reason. This suggestion is corroborated by analyses of hematite and hedenbergite data which are available for temperatures up to 900 K and 800 K respectively.     

Al hematites prepared by homogeneous precipitation of oxinates: material characterization and determination of the Morin transition

A novel method for synthesis of aluminium hematites, based upon the homogeneous precipitation of Fe and Al oxinates in various proportions, is presented. The precursor precipitates are heated in air at 700?°C. X-ray diffraction, thermal analyses, BET, FTIR, optical reflection analysis, TEM and Mössbauer spectroscopy at room temperature and 80?K of the resulting products indicate that single-phase hematites are formed with structural Al substitution of up to 10 at%. Interestingly, the particle size (>100?nm) is not substantially reduced by the Al content. Although it remains difficult to obtain a homogeneously distributed Al substitution in the final hematite, this processing line offers a unique opportunity to separate the effects of grain size and Al substitution on the Morin transition temperature (T _M) of Al hematite. From the comparison between the present hematites and a series of Al-substituted hematites with lepidocrocite as precursor, it could be shown that the effect on T _M, associated with a change of a factor 10 in grain size, is about 1/3 of the effect caused by a change of 10 in the degree of substitution. Finally, it is suggested that proper thermal treatments under different conditions of the same precursors are likely to produce spinel phases.     

Impact of the 11 March 2011, Great East Japan earthquake and tsunami on the chemical industry

The Great East Japan earthquake and tsunami damaged or destroyed many industrial facilities housing or processing hazardous substances, such as refineries, petrochemical facilities and other types of chemical industry. This showed that also generally well prepared countries are at risk of suffering natural hazard triggered technological (Natech) accidents. An analysis of data collected from open sources and through interviews with authorities was performed to understand the main reasons for the industrial damage and downtime as well as the extent of hazardous-materials releases and the associated impact on society. The analysis of the data set confirmed the findings from other studies with respect to main damage and failure modes, as well as hazardous-materials release paths. In addition, gaps in Natech risk management were identified. Based on the data analysis and interviews lessons learned in support of a more far-reaching Natech risk management are presented.     

琼西抱板群变质沉积岩地球化学研究

琼西中元古代抱板群变质沉积岩可分为白云母石英片岩组和石英二云母片岩组,其原岩为砂岩质泥质沉积岩夹火山物质。白云母石英片岩组和石英二云母片岩组在地球化学成分上的差异是原始沉积化学分异作用的结果。对主元素、微量元素（含稀土元素）及Sm-Nd同位素的综合研究表明,海南岛存在古元古代或更早的古老基底,抱板群变质沉积岩一部分来源于成熟度较低的古老地壳物质,另一部分来源于含地幔火山物质较多的初生地壳,或与研究区大规模造山运动、构造－岩浆活动所伴生的地幔物质加入有关。初步研究显示,琼西抱板群变质沉积岩可能是造山带岛弧和活动大陆边缘区（扩张弧后或弧间盆地）大地构造环境下的沉积产物。     

The hard solar X-ray burst of 18 September 1963

A hard solar X-ray burst was observed by J-P. Legrand on 18 September 1963, 13:56 UT, at balloon altitude. It lasted a few minutes; a steep increase was followed by an exponential decay. During its declining phase a weak radio burst was observed on 3 and 10 cm, not on longer wavelengths.Maximum radio intensity occurred two minutes after that of the X-ray burst. The X-ray and radio bursts ended almost simultaneously. Optically a small shortlived (some minutes) flare point occurred simultaneously with the X-ray burst in a magnetically interesting part of the active region of September 1963. The X-burst photons seem to have had an energy of about 0.5 MeV. The burst was therefore of a fairly rare type, since very few other bursts with similar photon energies have been detected up to now.It is suggested that a mass of gas, magnetically confined to a volume of about 5·10²⁵ cm³ in the low corona, containing about 3·10³⁵ electrons was accelerated to energies of about 0.5 MeV. The gas gradually expanded, partly also to higher levels. The gyro-synchrotron radiation, emitted by the plasma became observable after about two minutes. At the lower radio frequencies the radiation was absorbed by overlying undisturbed coronal matter. Quantitative computations justify this model. A detailed summary of the events, and some numerical data are given in the concluding Section 8 and in Table V.     

Weibull statistical analysis of granite bending strength

Summary  This paper describes and discusses the adequacy of Weibull statistical analysis to analyse the bending strength of granite. The experimental results show that strength variability is related with a specific origin of failure. This conclusion is based on analysing the influence of the surface condition (extrinsic defects) on the bending strength results treated by the Weibull statistics. The conclusions drawn from this study have been validated by analysing the results of the critical flaw dimension estimated by applying the linear elastic fracture mechanics (LEFM) formulae. Results obtained from fractographic examination also have been used to describe the location of the origin of the fracture and understand the distribution of defects; i.e., there is a unimodal distribution of defects (intrinsic defects), despite the fact that some outlier values are normally observed in the fractured surfaces. Correspndence: P. M. Amaral, Department of Materials Engineering, Instituto Superior Técnico, Technical University of Lisbon, Av. Rovisco Pais, 1049-001 Lisboa, Portugal     

海洋细菌抑菌活性菌株的筛选

从不同海区的海洋底质，生物样，水样中分离到480株海洋细菌，其中包括150株芽孢细菌和108株粪大肠杆菌，利用纸片法对其抑菌活性进行检测，结果表明：117株海洋细菌具有抑菌活性，占总分离菌株的24.4%；一般细菌，芽孢细菌，粪大肠杆菌的抑菌活性菌株分别占各供测菌株的17.1%,27.3%,35.2%；抑菌活性菌株的比例与样品来源密切相关，且各类海洋细菌的抗菌谱有很大的不同。     

Iodine chemistry in deep anoxic basins and overlying waters of the Mediterranean Sea

Iodate (IO₃⁻) is the predominant dissolved species of iodine in the oxygenated waters of the Mediterranean Sea. Iodide (I⁻) is present in significant quantities (up to 65 nM) in oxygenated waters in the photic zone and near the interface above the anoxic and saline Bannock Basin. Lesser quantities of I⁻ (< 10 nM) are found throughout the rest of the oxic water column. An additional unidentified dissolved iodine species is present immediately above the anoxic interface.Total dissolved iodine (ΣI) increases dramatically across the seawater/brine interface. Part of this increase is undoubtedly the result of the dissolution of iodine-rich evaporites during formation of the brine bodies at the Tyro and Bannock Basins. The vertical distribution of ΣI and other dissolved chemical species (particularly PO₄³⁻) in the Bannock Basin brine, however, suggests an additional, present-day, diagenetic source of dissolved iodine to the brine. Based on the increase in the concentration of the most soluble major ions across the seawater/brine interface, 5–7 μM of the 11.5-μM increase in ΣI concentration must be attributed to diagenesis.