Calculations of the temperature dependence of the NO2 photodissociation coefficient in the atmosphere

The photodissociation coefficient, J _NO2 of NO₂ in the atmosphere was calculated at 235 and 298 K using the measured temperature dependences of the absorption cross-sections and quantum yields. These calculations gave a ratio J _NO2(298 K)/J _NO2(235 K)=1.155±0.010 which is only weakly dependent on altitude, surface albedo and solar zenith angle.     

An indirect lead isotope age determination of gold mineralization at the Corinthia mine,Yilgarn Block,Western Australia

The Corinthia lode‐gold deposit in amphibolite‐facies greenstone belt rocks in the Southern Cross Province of the Archaean Yilgarn Block contains a largely undeformed pegmatite dyke emplaced during the last phases of movement along the Fraser's‐Corinthia shear zone. Gold mineralization and shear zone development were synchronous, and a Pb‐Pb isochron age of 2620 ±6 Ma for pegmatite emplacement either indirectly dates mineralization, or places a minimum age constraint on the timing of mineralization. This age is in accord with a broadly synchronous dominant episode of Archaean lode‐gold mineralization throughout the Yilgarn Block.     

Measurement of nitric oxide in the stratosphere between 17·4 and 22·9 km

On 16 March 1973, the York U./U.S.U. chemiluminescent nitric oxide instrument was flown successfully from Hollomon Air Force Base, New Mexico, 32° 50·1′ N lat. The instrument was operated between 17:40 and 22:05UT. Most of the measurements were carried out during three ascent, float and descent cycles between 17·4 and 22·9 km. Within the uncertainty of the measurements no differences were seen among results obtained during ascent, float and descent mode, which indicated that there were no major sampling problems resulting from contamination of the atmosphere. The NO mixing ratio was found to be 0·1 ppb v/v with an accuracy of 60 per cent. No change was observed within this accuracy over the small altitude range investigated.     

Diapirism synchronous with regional deformation and gold mineralisation,a new concept for granitoid emplacement in the Southern Cross Province,Western Australia

The Southern Cross Province in the Archean Yilgarn Block of Western Australia comprises large dome-shaped granitoid bodies surrounded by narrow greenstone belts. Determination of the emplacement mechanism of these domes is fundamental for understanding the tectonic history of this region. Many structures in the greenstone belts show trends which reflect their tectonic relationships with the granitoid domes. Some of these structures host large gold occurrences. The domes have concentric foliation patterns, both within the granitoids themselves, and in the neighbouring greenstone belts. The smaller domes only have radial mineral lineation patterns in their wall rocks, but the largest dome, the Ghooli Dome, has also a tangential pattern. The prevailing gentle dip of the foliation in the centre of this dome and the abundance of greenstone xenoliths suggest that the present exposures are close to its roof. Geothermometry and geobarometry on mineral assemblages in the Ghooli granitoid and its xenoliths show that its crystallisation temperature was just above 700 °C at a relatively high pressure of 4.3 to 6.2 kbar. These P-T conditions are higher than those inferred for peak metamorphism in the greenstones. Therefore, this granitoid must have been emplaced initially at crustal levels deeper than the maximum burial of the greenstones which flank the dome. The Ghooli Dome has a SHRIMP U-Pb zircon age of 2691 ± 7 Ma. Diapiric rise of the granitoid plutons taking place in a regional compressive tectonic regime is considered to be the most likely mechanism for the final emplacement of these bodies into their host rock at about 2636–2620 Ma. This concept is preferred over the alternatives because it best reconciles the calculated P-T data, the observed structural patterns, the presence of pegmatites and aplites in the host rock, and the orientation of the mineral-bearing structures.     

Modelling the Gravitational Effects of Random Underground Density Variations

Mathematical Geosciences - A mathematical model for small-scale spatial variations in gravity above the Earth’s surface is presented. Gravity variations are treated as a Gaussian random...     

Archean lode-gold deposits: fluid flow and chemical evolution in vertically extensive hydrothermal systems

The range of conditions of formation of lode-gold deposits from the sub-greenschist to the lower-granulite facies in Archean greenstone belts, and the generally steeply plunging, vertically continuous pipe-like or tabular geometries of individual deposits, indicate long-distance hydrothermal fluid advection along well-defined channelways in the upper and middle crust. From presently available gold solubility data, destabilisation of gold-bisulphide complexes through H₂S loss from the fluid to the wallrock was the dominant gold precipitation mechanism within these hydrothermal systems as a whole. This inference is supported by the S:Au ratios of ores. Sulphur and Au precipitation in the hydrothermal system is estimated to be relatively inefficient, with only 10–50% of S or Au contained in the fluid precipitated over any kilometre length of fluid channelway. The relative inefficiency of gold precipitation allowed mineralisation over a significant depth range in a crustal profile.     

The high latitude circulation and temperature structure of the thermosphere near solstice

The neutral gas temperature and circulation of the thermosphere are calculated for December solstice conditions near solar cycle maximum using NCAR's thermospheric general circulation model (TGCM). High-latitude heat and momentum sources significantly alter the basic solar-driven circulation during solstice. At F-region heights, the increased ion density in the summer hemisphere results in a larger ion drag momentum source for the neutral gas than in the winter hemisphere. As a result there are larger wind velocities and a greater tendency for the neutral gas to follow the magnetospheric convection pattern in the summer hemisphere than in the winter hemisphere. There is about three times more Joule heating in the summer than the winter hemisphere for moderate levels of geomagnetic activity due to the greater electrical conductivity in the summer E-region ionosphere.

The results of several TGCM runs are used to show that at F-region heights it is possible to linearly combine the solar-driven and high-latitude driven solutions to obtain the total temperature structure and circulation to within 10–20%. In the lower thermosphere, however, non-linear terms cause significant departures and a linear superposition of fields is not valid.

The F-region winds at high latitudes calculated by the TGCM are also compared to the meridional wind derived from measurements by the Fabry-Perot Interferometer (FPI) and the zonal wind derived from measurements by the Wind and Temperature Spectrometer (WATS) instruments onboard the Dynamics Explorer (DE−2) satellite for a summer and a winter day. For both examples, the observed and modeled wind patterns are in qualitative agreement, indicating a dominant control of high latitude winds by ion drag. The magnitude of the calculated winds (400–500 m s⁻¹) for the assumed 60 kV cross-tail potential, however, is smaller than that of the measured winds (500–800 m s⁻¹). This suggests the need for an increased ion drag momentum source in the model calculations due to enhanced electron densities, higher ion drift velocities, or some combination that needs to be further denned from the DE−2 satellite measurements.     

Comments on: “The partitioning of nickel between olivine and silicate melt” by S.R. Hart and K.E. Davis

We study a set of very high-quality records of first-order overtone Rayleigh waves from the deep-focus earthquake of September 29, 1973, in the Japan Sea. Standard surface wave techniques are used with these overtones, treated as individual seismic phases, to retrieve radiation pattern, Q, moment and phase velocity. A figure of M₀ = (6.7 ± 1.4) × 10²⁷dyn-cm is obtained, in total agreement with published values computed from either P waves, or fundamental Rayleigh waves. We also demonstrate the feasibility of using overtones as individual seismic phases in order to investigate their dispersion and attenuation properties.