Contributions to atmospheric methane by natural seepages on the U.K. continental shelf [Mar. Geol. 137 (1997) 165–189]

Natural gas seepages occur on the United Kingdom's continental shelf and although published reports suggest that they are very rare, the petroleum industry has identified, but not publicly reported, many more. There is also very little data on the flux of gas from seabed seepages, and even less on the contribution of seepages to atmospheric concentrations of gases such as methane.

Potential gas source rocks include Quaternary and Tertiary peats as well as petroliferous source rocks such as the Carboniferous Coal Measures and the Upper Jurassic Kimmeridge Clays. There are also other organic-rich sediments which are potential source rocks. Together these cover a considerable part of the U.K. continental shelf.

Analogue seismic reflection (pinger) profiles acquired during the British Geological Survey's regional mapping programme have been reviewed to identify water column targets including fish and plumes of gas bubbles. The ability to distinguish targets is critical to an assessment of the distribution of gas seepages. Both theoretical predictions of target identity and the habits of shoaling fish have been investigated in order to identify a method of distinction.

Data from seabed seepages and measurements of seepage rates have been used to establish likely ranges of gas flux rates and the sizes of gas bubbles. The likelihood that a rising bubble will survive and escape into the atmosphere is determined primarily by bubble size and water depth; methane, the principal constituent of seepage gas, is relatively unreactive and sparingly soluble.

The studies have enabled a new estimate of the distribution of gas seepages on the U.K. continental shelf, and of the contribution to atmospheric methane levels. The results suggest that natural gas seepages are significantly more important as a source of methane than had hitherto been established. It is estimated that between 120,000 and 3.5 mtonnes of methane per year come from a continental shelf area of about 600,000 km². This represents between 2% and 40% of the total United Kingdom methane emission. It is suggested that similar contributions arise from other continental shelf areas worldwide, and that geological sources of atmospheric methane are more significant than is generally acknowledged.     

Marine geology in the environs of Bouvet Island and the South Atlantic triple juction

It is suggested that Bouvet Island is the surface manifestation of a mantle plume which has resulted in the creation of a chain of seamounts in the South Atlantic and a general shoaling of the region.The strike of two newly defined large fracture zones borth and south of the Bouvet Island pedestal have been utilized to determine a pole of rotation at 12.5°S, 12.5°W for the Africa-Antarctica motion. A pole at 75°S, 13°E has been calculated for the South America-Antarctica motion. At the triple junction the South America-Africa relative motion is 3.3 cm yr^-1 (whole rate) at 075°. The Africa-Antarctica motion is 1.7 cm yr^-1 at 065° and the South America-Antarctica motion is 1.6 cm yr^-1 at 085.     

Oxidative stress in two populations of killifish (Fundulus heteroclitus) with differing contaminant exposure histories

A population of killifish (Fundulus heteroclitus) inhabiting a creosote-polluted inlet of the Elizabeth River demonstrates tolerance to the acute toxic effects exerted by contaminated sediments on reference site killifish. Previous data have suggested that upregulated antioxidant defenses contribute to short-term tolerance in killifish exposed to Elizabeth River sediments. This study investigated population differences in antioxidant defenses from wild caught Elizabeth River and reference population killifish in different seasons, and after being held in the laboratory. Parameters measured in the killifish were total glutathione concentrations (GSH(T)), activities of glutathione reductase (GR), glutathione peroxidase (GPx), and lipid peroxidation (LPO), all in adult hepatic tissues. The Elizabeth River population exhibited greater GSH(T), higher GPx activities, and increased LPO as compared to the reference population. Sex specific population differences were also observed in GSH(T) and GPx. Both populations displayed decreased GSH(T) and increased GR from early to late summer, as well as after being held in the laboratory. This study indicates that there are many factors that may contribute to differences in levels of antioxidant defenses in addition to exposure to contaminants, including reproductive status and environmental conditions.     

Neashore auto-suspending turbidity flows

A class of turbidity flows is investigated in which sediment is entrained sufficient to balance losses and an equilibrium flow is sustained. The analytical models for predicting equilibrium flow configurations are surveyed. These are found to differ by two orders of magnitude in the required flow speeds. Five field observations of self-sustaining turbidity flows are investigated as a test for the analytical models. The model of Bagnold (1962) is found to have skill in predicting all of the field observations. The significance of these flows to the reliability of pipelines, cables and other engineering structures on continental shelves is considered. Circumstantial evidence is presented that suggests that these flows may be a mechanism for offshore flows of sand from beaches during major storms.     

Patterns and controls of surface sediment distribution: west-central Florida inner shelf

The west-central Florida inner shelf represents a transition between the quartz-dominated barrier-island system and the carbonate-dominated mid-outer shelf. Surface sediments exhibit a complex distribution pattern that can be attributed to multiple sediment sources and the ineffectiveness of physical processes for large-scale sediment redistribution. The west Florida shelf is the submerged extension of the Florida carbonate platform, consisting of a limestone karst surface veneered with a thin unconsolidated sediment cover. A total of 498 surface sediment samples were collected on the inner shelf and analyzed for texture and composition. Results show that sediment consists of a combination of fine quartz sand and coarse, biogenic carbonate sand and gravel, with variable but subordinate amounts of black, phosphorite-rich sand. The carbonate component consists primarily of molluskan fragments. The distribution is patchy and discontinuous with no discernible pattern, and the transition between sediment types is generally abrupt. Quartz-rich sediment dominates the inner 15 km north of the entrance into Tampa Bay, but south of the Bay is common only along the inner 3 km. Elsewhere, carbonate-rich sediment is the predominate sediment type, except where there is little sediment cover, in which cases black, phosphorite-rich sand dominates. Sediment sources are likely within, or around the periphery of the basin. Fine quartz sand is likely reworked from coastal units deposited during Pleistocene sea-level high stands. Carbonate sand and gravel is produced by marine organisms within the depositional basin. The black, phosphorite-rich sand likely originates from the bioerosion and reworking of the underlying strata that irregularly crop out within the study area. The distribution pattern contains elements of both storm- and tide-dominated siliciclastic shelves, but it is dictated primarily by the sediment source, similar to some carbonate systems. Other systems with similar sediment attributes include cool-water carbonate, sediment-starved, and mixed carbonate/siliciclastic systems. This study suggests a possible genetic link among the three systems.     

Vertical migration and mortality of benthos in dredged material: Part II—crustacea

Benthic invertebrates have many characteristics which make them prime candidates for burial studies in dredged material. A major concern in dredging and disposal projects is the effect of burial on the survival of benthic invertebrates. The purpose of the research reported in this paper was to determine the ability of estuarine benthos—in particular three species of molluscs (Mercenaria mercenaria, Nucula proxima and Ilyanassa obsoleta)—to migrate vertically in natural and exotic sediments and to determine the survival of benthos when exposed to particular amounts of simulated dredged material.Mortalities generally increased with increased sediment depth, with increased burial time and with overlying sediments whose particle size distribution differed from that of the species native sediment. Temperature affected mortalities and vertical migration. It was concluded that vertical migration is a viable process which can significantly affect rehabilitation of a dredged disposal area. Under certain conditions, vertical migration should be considered, together with larval settling and immigration from outside impacted areas, as a mechanism of recruiting a dredgedump site.     

Major-element composition of the particulate matter in the near-bottom nepheloid layer of the gulf of Mexico

During cruises 71-A-12 and 73-A-3 of the R/V “Alaminos” eighty-six samples of suspended matter at eleven near-bottom stations in the Gulf of Mexico and northwestern Caribbean Sea were collected, and simultaneously, values for light scattering were measured. Selected samples of the suspended matter were analyzed for particulate aluminum, silicon, iron, calcium, magnesium, organic carbon and inorganic carbon. The results indicate that a permanent but highly variable near-bottom nepheloid layer exists in the Gulf of Mexico but not in the northwestern Caribbean Sea. Average total-suspended loads in the Gulf of Mexico nepheloid layer are two times higher than in the clear water above the nepheloid layer.Since there is a significant increase in the alumino-silicate fraction and a corresponding decrease in the organic fraction of the suspended matter in the nepheloid layer relative to the overlying water, it appears that sediments are the most probable source of the increased concentrations of suspended matter in the nepheloid layer. This hypothesis is supported by X-ray diffraction analyses on the nepheloid material collected at one station which show the same mineral assemblages as the underlying sediments.Time studies over periods of one week and one and one-half years showed large total-suspended-matter variations which indicate that non steady-state processes, primarily vertical eddy diffusion and possibly advection, are controlling the distribution of suspended matter in the nepheloid layer.     

Solar flares: The impulsive phase

Only during the previous solar cycle have systematic observations begun to be made with the sensitivity and time resolution, and the continuous coverage required to catch the impulsive phase and measure the rapid variations present in many wavelength ranges. Observations in X-rays, gamma-rays, UV, H, and radio wavelengths all reveal rapid variations during the impulsive phase and have contributed to our understanding of the different phenomena involved. Results have been obtained from several spacecraft, from rocket and balloon flights, and from ground-based observations. These are reviewed in the context of a simple single loop flare model with a view to showing what results are consistent with this model and what the major problems are in our understanding of the impulsive phase. New instrumentation planned for observations during the present Cycle 22 will provide a concerted attack on the impulsive phase as part of the Max '91 program.     

Is the ‘superhot’ hard x-ray component in solar flares consistent with a thermal source?

It has been shown by Brown and Emslie (1988) that any optically thin thermal bremsstrahlung source must emit an energy spectrumL () (keV s^–1 keV^–1) which has the property that higher derivatives alternate in sign, i.e., (–) ^j L(^j)() > 0 for allj. In this short note, we apply this test to the superhot component discussed by Linet al. (1981) in order to determine whether a strictly thermal interpretation of this component is valid. We find that all statistically significant higher derivatives do indeed have the correct sign; this strengthens the identification of this component as due to a thermal source.Presidential Young Investigator.     

An early estimate for the size of cycle 23

Two features are found in the modern era sunspot record (cycles 10–22: ca. 1850-present) that may prove useful for gauging the size of cycle 23, the next sunspot cycle, several years ahead of its actual onset. These features include an inferred long-term increase against time of maximum amplitude (RM, the maximum value of smoothed sunspot number for a cycle) and the apparently inherent differing natures of even- and odd-numbered sunspot cycles, especially when grouped consecutively as even-odd cycle pairs. Concerning the first feature, one finds that 6 out of the last 6 sunspot cycles have had RM 110.6 (the median value for the modern era record) and that 4 out of 6 have had RM > 150. Presuming this trend to continue, one anticipates that cycle 23 will likewise have RM 110.6 and, perhaps, RM > 150. Concerning the second feature, one finds that, when one groups sunspot cycles into consecutively paired even-odd cycles, the odd-following cycle has always been the larger cycle, 6 out of 6 times. Because cycle 22 had RM = 158.5, one anticipates that cycle 23 will have RM > 158.5. Additionally, because the average difference between RM(odd) and RM(even) for consecutively paired even-odd cycles is 40.3 units (sd = 14.2), one expects cycle 23 to have RM 162.3 (RM = 198.8 ± 36.5 at the 95% level of confidence). Further, because of the rather strong linear correlation (r = 0,959, se = 13.5) found between RM(odd) and RM(even) for consecutively paired even-odd cycles, one infers that cycle 23 should have RM 176.4 (RM = 213.9 ± 37.5 at the 95% level of confidence). Since large values of RM tend to be associated with fast rising cycles of short ascent duration and high levels of 10.7-cm solar radio flux, cycle 23 is envisioned to be potentially one of the greatest cycles of the modern era, if not the greatest.