Late Cretaceous ophiolite obduction and Paleocene India-Asia collision in the westernmost Himalaya

Abstract

Collision of the Kohistan island arc with Asia at ~100 Ma resulted in N-S compression within the Neo-Tethys at a spreading center north of the Indo-Pakistani craton. Subsequent India-Asia convergence converted the Neo-Tethyan spreading center into a short-lived subduction zone. The hanging wall of the subduction zone became the Waziristan, Khost and Jalalabad igneous complexes. During the Santonian- Campanian (late Cretaceous), thrusting of the NW IndoPakistani craton beneath Albian oceanic crust and a Cenomanian volcano-sedimentary complex, generated an ophiolite-radiolarite belt. Ophiolite obduction resulted in tectonic loading and flexural subsidence of the NW Indian margin and sub-CCD deposition of shelf-derived olistostromes and turbidites in the foredeep. Campanian-Maastriehtian calci- clastic and siliciclastic sediment gravity flows derived from both margins filled the foredeep as a huge allochthon of Triassic-Jurassic rise and slope strata was thrust ahead of the ophiolites onto the Indo-Pakistani craton. Shallow to intermediate marine strata covered the foredeep during the late Maastrichtian. As ophiolite obduction neared completion during the Maastrichtian, the majority of India-Asia convergence was accommodated along the southern margin of Asia. During the Paleocene, India was thrust beneath a second allochthon that included open marine middle Maastrichtian colored mélange which represents the Asian Makran-Indus-Tsangpo accretionary prism. Latérites that formed on the eroded ophiolites and structurally higher colored mélange during the Paleocene wei’e unconformably overlapped by upper Paleocene and Middle Eocene shallow marine limestone and shale that delineate distinct episodes of Paleocene collisional and Early Eocene post-collisional deformation.     

Structural chemistry of synthetic cordierite: Evidence for solid solutions and disordered compositional domains in Bi-flux-grown Mg-cordierites

The structure, crystal chemistry, and microstructure of disordered and ordered Mg-cordierites synthesized in a bismuth oxide flux system have been studied by a combination of x-ray and neutron powder diffraction and quantitative x-ray microanalysis using analytical electron microscopy. Microchemical data obtained on Bi-flux cordierites using energy-dispersive x-ray analysis is interpreted through comparison with data collected on stoichiometric Mg₂Al₄Si₅O₁₈ glass and α- and β-cordierite samples synthesized by subsolidus crystallization of the glass. Bi-flux cordierites crystallize in both the hexagonal and orthorhombic polymorphs and contain 5 to 10 at% occupancy of bismuth on the C1 and C2 channel sites. The microstructure of Bi-flux α-cordierite is characterized by the existence of local domains of disordered cordierite solid solutions with variable composition and significant vacancy concentrations on the octahedral site. The β-cordierites have a more homogeneous microstructure but are still Al-deficient, Si-rich solid solutions.     

Changes in Nutrient Biogeochemistry in Response to the Regression of Zostera noltii Meadows in the Arcachon Bay (France)

From 1989 to 2007, a severe decline in Zostera noltii meadows was reported in the Arcachon Bay, with an accelerated regression after 2005. We investigated the inter-annual variability of the biogeochemistry of the sediment in an area affected by seagrass decline. In late summer and in winter of the years 2006, 2010, and 2011, sediment cores were collected at low tide on vegetated and adjacent non-vegetated sediments located in the eastern part of the Arcachon Bay. The geochemical analyses of sediment solid-phase organic carbon, reactive P and Fe, and the pore water concentrations of Fe²⁺, DIP, and NH₄ ⁺ are presented. The changes in the chemistry of sediment and pore water between 2006 and 2010 are interpreted as a consequence of the decrease in the Z. noltii biomass between 2006 and 2010. The absence of significant seasonal variations in biomass throughout the growth period (March–September) in 2011 is most likely related to the regression of Z. noltii meadow that strongly affects the study area. In contrast to the healthy meadow in 2006, the declining meadow favored the dissolution of sedimentary particulate phosphorus in winter. In late summer, the low biomass of seagrass resulted in a net release of ammonium in the pore water of the upper 20 cm of sediment. This study clearly shows that seagrass decay may enhance nutrient release in sediments, resulting in a significant supply of phosphorus to the water column of a magnitude comparable to annual inputs to the lagoon from the rivers and the tidal pump.     

Cretaceous and Tertiary terrane accretion in the Cordillera Occidental of the Andes of Ecuador

New field, geochronological, geochemical and biostratigraphical data indicate that the central and northern parts of the Cordillera Occidental of the Andes of Ecuador comprise two terranes. The older (Pallatanga) terrane consists of an early to late (?) Cretaceous oceanic plateau suite, late Cretaceous marine turbidites derived from an unknown basaltic to andesitic volcanic source, and a tectonic mélange of probable late Cretaceous age. The younger (Macuchi) terrane consists of a volcanosedimentary island arc sequence, derived from a basaltic to andesitic source. A previously unidentified, regionally important dextral shear zone named the Chimbo-Toachi shear zone separates the two terranes. Regional evidence suggests that the Pallatanga terrane was accreted to the continental margin (the already accreted Cordillera Real) in Campanian times, producing a tectonic mélange in the suture zone. The Macuchi terrane was accreted to the Pallatanga terrane along the Chimbo-Toachi shear zone during the late Eocene, probably in a dextral shear regime. The correlation of Cretaceous rocks and accretionary events in the Cordillera Occidental of Ecuador and Colombia remains problematical, but the late Eocene event is recognised along the northern Andean margin.     

Microphytobenthos: The ecological role of the “secret garden” of unvegetated,shallow-water marine habitats. II. role in sediment stability and shallow-water food webs

The microphytobenthos form an important component of all shallow-water ecosystems where enough light reaches the sediment surface to support appreciable primary production. Although less conspicuous than macroalgae or vascular plants, the microphytobenthos can contribute significantly to primary production and can modify habitat characteristics. The microphytobenthos alter sediment properties (e.g., erodibility) both directly, in the extreme forming a mat or scum on the sediment surface, and indirectly by modifying the activities of benthic infauna (e.g., pelletization, burrowing, tube building, and sediment tracking). Carbon dioxide fixed by the microphytobenthos supports higher, grazing trophic levels. These include deposit-feeding and suspension-feeding macrofauna as well as meiofauna and microfauna. Quantitative relations between the feeding and growth rates of macrofauna and the abundance of microphytobenthos and suspended organic matter (i.e., functional responses) are reviewed. Given the current state of knowledge of the direct and indirect interactions involving trophic dynamics, sediment properties, and benthic microalgae, we argue for reductionist studies of particular interactions as distinct entities. This is a prerequisite for the emergence of a comprehensive picture of unvegetated ecosystems and the ability to predict their responses to man’s activities. *** DIRECT SUPPORT *** A01BY074 00005     

Some applications of paleoecology to the management of tidal marshes

The shallow-water habitat is under increasing environmental pressures from accelerated sea-level rise and continual urban sprawl and will require well-informed management decisions to maintain its health into the future. One of the keys to the effective management of the shallow-water habitat is understanding the processes responsible for its development. Paleoecology has the potential to provide much insight into the development of the system, particularly when the impacts of accelerated sea-level rise on vegetation and sedimentation dynamics in tidal marshes is being considered. For example, a paleoecological comparison of tidal salt marshes to tidal freshwater marshes shows that rates of development will dictate the system's response to accelerated sea-level rise, with tidal freshwater marshes capable of transgressing landward more rapidly than their saline counterparts. Such information implies that management of the adjacent uplands is as important to the future of the system as management of the marsh itself. Therefore, it is important to consult paleoecological research when management strategies are being considered. *** DIRECT SUPPORT *** A01BY074 00010     

On the breakdown of zircon upon “dry” thermal annealing

Zircon samples without and with secondary chemical alteration from diverse sources were subjected to heat treatment at 1400 °C for 96 h. Resulting new phases and textures suggest that decomposition of zircon into component oxides occurred in all experiments to various degrees. The crucible material was found to have a strong influence on the extent of breakdown, especially in the case of altered starting materials. In this study the progressive stages of the breakdown of zircon grains are described. The factors that may govern the decomposition are discussed, including radiation damage, secondary alteration and external reaction conditions (sample container, atmosphere). Alumina crucibles should generally be avoided in dry annealing of zircon, to minimise uncontrolled breakdown into oxides.     

A chemical and thermodynamic model of oil generation in hydrocarbon source rocks

Thermodynamic calculations and Gibbs free energy minimization computer experiments strongly support the hypothesis that kerogen maturation and oil generation are inevitable consequences of oxidation/reduction disproportionation reactions caused by prograde metamorphism of hydrocarbon source rocks with increasing depth of burial.These experiments indicate that oxygen and hydrogen are conserved in the process.Accordingly, if water is stable and present in the source rock at temperatures ?25 but ?100 °C along a typical US Gulf Coast geotherm, immature (reduced) kerogen with a given atomic hydrogen to carbon ratio (H/C) melts incongruently with increasing temperature and depth of burial to produce a metastable equilibrium phase assemblage consisting of naphthenic/biomarker-rich crude oil, a type-II/III kerogen with an atomic hydrogen/carbon ratio (H/C) of ∼1, and water. Hence, this incongruent melting process promotes diagenetic reaction of detritus in the source rock to form authigenic mineral assemblages.However, in the water-absent region of the system CHO (which is extensive), any water initially present or subsequently entering the source rock is consumed by reaction with the most mature kerogen with the lowest H/C it encounters to form CO₂ gas and a new kerogen with higher H/C and O/C, both of which are in metastable equilibrium with one another.This hydrolytic disproportionation process progressively increases both the concentration of the solute in the aqueous phase, and the oil generation potential of the source rock; i.e., the new kerogen can then produce more crude oil.Petroleum is generated with increasing temperature and depth of burial of hydrocarbon source rocks in which water is not stable in the system CHO by a series of irreversible disproportionation reactions in which kerogens with higher (H/C)s melt incongruently to produce metastable equilibrium assemblages consisting of crude oil, CO₂ gas, and a more mature (oxidized) kerogen with a lower H/C which in turn melts incongruently with further burial to produce more crude oil, CO₂ gas, and a kerogen with a lower H/C and so forth.The petroleum generated in the process progresses from heavy naphthenic crude oils at low temperatures to mature petroleum at ∼150 °C. For example, the results of Computer Experiment 27 (see below) indicate that the overall incongruent melting reaction in the water-absent region of the system C-H-O at 150 °C and a depth of ∼4.3 km of an immature type-II/III kerogen with a bulk composition represented by C₂₉₂H₂₈₈O_12(c) to produce a mature (oxidized) kerogen represented by C₁₂₈H₆₈O_7(c), together with a typical crude oil with an average metastable equilibrium composition corresponding to C_8.8H_16.9 (C_8.8H_16.9(l)) and CO₂ gas (CO_2(g)) can be described by writing

(A)     

ISIS IR: The first infrared fibre-fed spectrograph

ISIS IR is the first attempt to use fibre optics for near infrared spectroscopy (1.8m). It is a field spectrograph (2D spectroscopy), and can work at various resolving powers (up to 25000). It can be transported anywhere, and soon it will be used at CFHT with one NICMOS 3-based camera.Département d'Astrophysique Extragalactique et de Cosmologie