Nitrogen isotope indicators of seasonal source variability to groundwater

 A nitrogen isotope study of soil water and groundwater in southern Indiana, USA, in 1991–1992 demonstrated considerable variations in nitrate degradation processes compared to an earlier investigation in 1986–1987. Although N-fertilizers were applied in May 1991, the δ¹⁵N values in soil water decreased in February 1992, indicating its delayed release into the system after substantial rainfall. The δ¹⁵N values of groundwater decreased from +12.3‰ in November 1991 to +11.3‰ in February 1992, and to +7.5‰ in March 1992. The increased residence time of nitrate in the soil resulted in increased denitrification, ammonia volatilization and plant uptake, and reduced threat to the groundwater quality. The 1986–1987 study in the area reported that excessive rainfall during the summer rapidly transported the nitrate to deeper horizons and drastically reduced volatilization and microbial reduction of nitrate, thus increasing the immediate threat to the groundwater quality in the area. The present study demonstrated that nitrogen isotopic signatures can be used to determine the effects of local soil type, rainfall, and land-use practices on the fate of nitrate in the subsurface. Received: 18 February 1997 · Accepted: 17 June 1997     

An application of factor analysis for the study of the hydrogeological conditions in Plio-Pleistocene aquifers of NW Achaia (NW peloponnesus, Greece)

R- andQ-mode factor analysis is applied to 51 groundwater samples collected from wells drilled in the Plio-Pleistocene aquifers of NW Achaia, Greece. The purpose ofR- andQ-mode factor analysis application is to identify (i) the regional groundwater flow pattern, and (ii) the deterioration of groundwater quality. Sixteen hydrogeological parameters are used in order to examine their importance and to provide significant insight into their correlations. In theR-mode factor analysis, a six-factor model is suggested which can explain more than 77.5% of the total variance. The contribution of each factor at every site (factor scores) also is computed. Maps are constructed showing the geographical distribution of the factor scores. From these maps, the high salinity areas are delineated (seawater intrusion, possible appearance of halite layers) and the areas with elevated contribution of karastic-water are defined. Using theQ-mode correspondence analysis the meaning of the electrical conductivity as the most important variable in groundwater quality characterization is demonstrated.     

Effects of mass transfer, compaction and secondary porosity on hydrothermal upgrading of Paleoproterozoic sedimentary manganese ore in the Kalahari manganese field, South Africa

In the northwestern part of the Kalahari manganese field low-grade carbonate-rich Mamatwan-type ore is altered to high-grade oxide-rich Wessels-type ore in association with normal faults. Mass balance calculations, based on the assumption that manganese was geochemically immobile, suggest that upgrading of the manganese ore can be attributed to leaching of Mg, Ca, CO₂ and SiO₂ from the sedimentary ore with residual enrichment of Mn. Hydrothermal alteration resulted in development of about 10 to 20% of secondary porosity in the ores and the orebed was compacted to two thirds of its original stratigraphic thickness. Received: 28 May 1996 / Accepted: 22 January 1997     

Conservation tillage and input use

 There continues to be a question as to the overall effectiveness of conservation tillage practices in reducing the impact of agricultural production on the environment. While it is generally recognized that water runoff and soil erosion will decline further, as tillage and mulch tillage systems are not used more extensively on cropland, what will happen to pesticide and fertilizer use remains uncertain. To gain some insight into this, the conservation tillage adoption decision is modelled. On the assumption that the decision to adopt conservation tillage is a two-step procedure, the first decision is whether or not to adopt a conservation tillage production system and the second concerns the extent to which conservation tillage should be used – appropriate models of the Cragg and Heckman (dominance) type are estimated. Based on farm-level data on corn production in the United States for 1987, the profile of a farm on which conservation tillage was adopted is that the cropland had above-average slope and experienced above-average rainfall, the farm was a cash grain enterprise, and it had an above-average expenditure on pesticides and a below-average expenditure on fuel and custom pesticide applications. Additionally, for a farm adopting a no-tillage production practice, an above-average expenditure was made on fertilizer. Received: 18 September 1995 · Accepted: 6 December 1995     

Effect of tunnel depth on modulus of deformation of rock mass

Summary Deformability of rock mass significantly influences its behaviour and is, therefore, an important consideration for the design of underground openings. The modulus of deformation of rock mass is, however, normally obtained from expensive and time-consuming uniaxial jacking tests, whose results often have a large scatter. An empirical correlation has, therefore, been proposed for a quick and inexpensive preliminary estimation of the modulus of deformation of rock mass on the basis of field instrumentation carried out in tunnels in India.     

Spectrum Analysis of the Reflected Waves Observed in the Nikko Region, Central Japan

—The Nikko region, in northern Kanto, central Japan, which is a high seismicity region, is located near the volcanic front. Many seismic observations have been carried out around the Nikko region because the seismograms of the shallow earthquakes occurring in this region show an S-wave reflected phase (SxS) and an S-to-P mode-converted and reflected phase (SxP) from a mid-crustal seismic velocity discontinuity. The depth of the mid-crustal reflector was estimated to be about 9–16 km. From the amplitude analyses of SxS and SxP phases, the material of the mid-crustal layer just beneath the reflector was expected to be a low rigidity layer, which was interpreted as partially molten rocks. No evidence has been shown for the internal properties of the material of the reflector. The Vp/Vs ratio is a good measure to distinguish between the two candidates for seismic reflectors; i.e., partially molten rocks and rocks containing water. We investigate the Vp/Vs ratio of the reflector using the spectrum analyses of the data observed by a seismic array. From spectrum analysis of the data, we indicate that the Vp/Vs ratio of 2.5 is better than that of 1.8 to explain the observed data, which shows that the material beneath the reflector consists of partially molten rocks.     

Global modelling study (GSM TIP) of the ionospheric effects of excited N2, convection and heat fluxes by comparison with EISCAT and satellite data for 31 July 1990

Near-earth plasma parameters were calculated using a global numerical self-consistent and time-dependent model of the thermosphere, ionosphere and protonosphere (GSM TIP). The model results are compared with experimental data of different origin, mainly EISCAT measurements and simultaneous satellite data (N_e and ion composition). Model runs with varying inputs of auroral FAC distributions, temperature of vibrationally excited nitrogen and photoelectron energy escape fluxes are used to make adjustments to the observations. The satellite data are obtained onboard Active and its subsatellite Magion –2 when they passed nearby the EISCAT station around 0325 and 1540 UT on 31 July 1990 at a height of about 2000 and 2200 km, respectively. A strong geomagnetic disturbance was observed two days before the period under study. Numerical calculations were performed with consideration of vibrationally excited nitrogen molecules for high solar-activity conditions. The results show good agreement between the incoherent-scatter radar measurements (N_e, T_e, T_i) and model calculations, taking into account the excited molecular nitrogen reaction rates. The comparison of model results of the thermospheric neutral wind shows finally a good agreement with the HWM93 empirical wind model.