Untersuchung der Sorptionseigenschaften des Kationenaustauschers KB-2M mit Makronetzstruktur zur Abtrennung von Zinkionen aus Ab- und Spülwässern

Study of Sorptional Properties of the Cation Exchanger KB-2M with Macroreticular Structure for Recovery of Zinc Ions from Sewage and Rinsing Water Although a number of ion-exchange methods have been employed for the recovery of some transition metals from industrial effluents, knowledge about ion-exchange resins with macroreticular structure is poor. The present paper describes the mechanism of sorption on such exchangers and their application for recovery of zinc from sewage rinsing water. Ion exchanger of macroreticular structure are polymers with long-chained cross-linking agents. We have synthesized carboxylic ion-exchange resins by hydrolysis of copolymerisates of methyl acrylate with different cross-linking agents: divinylbenzene, divinyl sulfide, divinyl ester of ethylene glycol and divinyl ester of di- or triethylene glycol. The sorption process on modifications of the carboxylic resins KB-2 of various structure was studied with different methods: potentiometric titration, infrared spectroscopy, electron microscopy, X-ray structural analysis. The initial zinc concentration in rinsing water was 0.05 mol/L at pH from 3 to 6. For the sorption, 0.2…1.0 g of resin were equilibrated with 100 mL of zinc solution. After equilibrium (12 h), the resin was separated from solution. The zinc ions were determined by atomic absorption spectrometry after stripping with 100 mL of 10% sulfuric acid. The distribution ratio D was calculated (D: mmole of Zn sorbed per gram of resin divided by mmole of Zn per millilitre of solution). By means of infrared spectroscopy, the mechanism of sorption of zinc ions from rinsing water was determined. There may be a possibility of the formation of complexes in the cation-exchange resin phase. It was found out in this paper that the cation-exchanger KB-2M of macroreticular structure is the most effective for the sorption of the Zn²⁺-ions from sewage and rinsing water.     

Application of sodars in the study and monitoring of the environment

Summary Application of acoustic sounders (sodars) to study the atmospheric boundary layer (ABL) began in the early 1970s. During the last two decades the scope of sodars applications enlarged considerably. The proceedings of eleven symposia of the International Society for Remote Acoustic Sensing of the Atmosphere and Oceans (ISARS) are a unique collection of papers, where all directions of the sodar use since 1981 are presented. In this paper, a review of sodar applications to atmospheric research is presented based on materials published in these proceedings in the following fields: conditions of microwave and light propagation; regional climatology of the ABL; air pollution meteorology and weather forecast; mesoscale phenomena under stable and unstable stratification; micrometeorology; peculiarities of the ABL in remote and complex terrain.     

Elevated stratified layers observed with sodar during VTMX

Summary A combination of low frequency sodar, radar wind profiler and in-situ balloon-borne measurements of temperature and water vapor have been used to investigate the structure of elevated stratified layers within the transition layer above the nocturnal boundary layer during the Vertical Transport and Mixing Field Campaign in Salt Lake City Utah, during October, 2000. Elevated layers determined from sodar and radar vertical time sections were penetrated with a balloon-born instrument package to determine the fine scale temperature and moisture structure of the layers. As expected a potential temperature increase was found in the upper half of the layers; however the magnitude was considerably smaller than found above the daytime well-mixed layer and the vertical distance of the increase was quite variable. Mixing ratio, in the mean was found to have a relative maximum in the lower portion of the layers. It was found that the potential temperature within the layers decreased with time relative to background values, regardless of whether the layer descended or ascended.     

Two decades of progress in sodar techniques: a review of 11 ISARS proceedings

Summary For 20 years the biennial symposia organized by the International Society for Acoustic Remote Sensing of the Atmosphere and Oceans and Associated Techniques (ISARS) have been held in different countries. The original papers collected in the proceedings of the symposia reflect the development of ideas, equipment, and methods, plus results obtained in the area. The spectrum of themes discussed at the symposia is broad. More than 60% of the papers were devoted to the role of sodars in atmospheric boundary-layer research. This paper presents an overview of the development of sodar technique as elucidated in the proceedings of 11 ISARS symposia. Topics include (1) instrumentation, (2) methods of measuring different meteorological quantities and their turbulence characteristics, and (3) validating the methods by comparison of sodar data with in situ measurements.     

Turbulent Pressure Statistics in the Atmospheric Boundary Layer from Large-Eddy Simulation

We use large-eddy simulation (LES) to study the turbulent pressure field in atmospheric boundary layers with free convection, forced convection, and stable stratification. We use the Poisson equation for pressure to represent the pressure field as the sum of mean-shear, turbulence–turbulence, subfilter-scale, Coriolis, and buoyancy contributions. We isolate these contributions and study them separately. We find that in the energy-containing range in the free-convection case the turbulence–turbulence pressure dominates over the entire boundary layer. That part dominates also up to midlayer in the forced-convection case; above that the mean-shear pressure dominates. In the stable case the mean-shear pressure dominates over the entire boundary layer.We find evidence of an inertial subrange in the pressure spectrum in the free and forced-convection cases; it is dominated by the turbulence–turbulence pressure and has a three-dimensional spectral constant of about 4.0. This agrees well with quasi-Gaussian predictions but is a factor of 2 less than recent results from direct numerical simulations at moderate Reynolds numbers. Measurements of the inertial subrange pressure spectral constant at high Reynolds numbers, which might now be possible, would be most useful.     

Century-Scale Change in Water Availability: CO2-Quadrupling Experiment

It has been suggested that, unless a major effort is made, the atmospheric concentration of carbon dioxide may rise above four times the pre-industrial level in a few centuries. Here we use a coupled atmosphere-ocean-land model to explore the response of the global water cycle to such a large increase in carbon dioxide, focusing on river discharge and soil moisture. Our results suggest that water is going to be more plentiful in those regions of the world that are already `water-rich'. However, water stresses will increase significantly in regions and seasons that are already relatively dry. This could pose a very challenging problem for water-resource management around the world. For soil moisture, our results indicate reductions during much of the year in many semi-arid regions of the world, such as the southwestern region of North America, the northeastern region of China, the Mediterranean coast of Europe, and the grasslands of Australia and Africa. In some of these regions, soil moisture values are reduced by almost a factor of two during the dry season. The drying in semi-arid regions is likely to induce the outward expansion of deserts to the surrounding regions. Over extensive regions of both the Eurasian and North American continents in high and middle latitudes, soil moisture decreases in summer but increases in winter, in contrast to the situation in semi-arid regions. For river discharge, our results indicate an average increase of ～ 15% during the next few centuries. The discharges from Arctic rivers such as the Mackenzie and Ob' increase by much larger fractions. In the tropics, the discharges from the Amazonas and Ganga-Brahmaputra also increase considerably. However, the percentage changes in runoff from other tropical and many mid-latitude rivers are smaller.     

Steady, annual, and monthly recharge implied by deep unconfined aquifer flow

We consider the response of a deep unconfined horizontal aquifer to steady, annual, and monthly recharge. A groundwater divide and a zero head reservoir constrain the aquifer, so that sinusoidal monthly and aperiodic annual recharge fluctuations create transient specific discharge near the reservoir and an unsteady water table elevation inland. One existing and two new long-term data sets from the Plymouth-Carver Aquifer in southeastern Massachusetts calibrate and confirm hydraulic properties in a set of analytical models. [Geohydrology and simulated groundwater flow, 1992] data and a new power law for tritiugenic helium to tritium ratios calibrate the steady recharge that drives the classical parabolic model of steady hydraulics [Applied Hydrogeology, 2001]. Observed water table and gradient fluctuations calibrate the transient recharge models. In the latter regard, monitoring wells within 1 km of Buttermilk Bay exhibit appreciable specific discharge and reduced water table fluctuations. We apply [Trans Am Geophys Union 32(1951)238] periodic model to the monthly hydraulics and a recharge convolution integral [J Hydrol 126(1991)315] to annual flow. An infiltration fraction of 0.79 and a consumptive use coefficient of 1.08×10⁻⁸ m/s °C relate recharge to precipitation and daylight weighted temperature across all three time scales. Errors associated with this recharge relation decrease with increasing time scale.     

Evolution of sand waves in the Messina Strait, Italy

In the present paper the morphodynamics of sand waves in the Messina Strait, Italy, is analysed by comparing data gathered during two different surveys carried out in 1991 and 2001, respectively. In particular, a morphometric analysis on the most recent data and a qualitative analysis of the differences between bottom bedform patterns, are carried out. At locations characterised by greater depths, only minor changes to the planimetric configuration of the field, i.e. crest orientation (which is seen to be orthogonal to the direction of net gross sand transport) and wave length are observed, while differences in wave length and crest direction are more evident in more shallow areas. On the other hand, wave height has significantly increased in the whole field. A possible explanation of such a change, based on the previsions of a theory which relates sand-wave growth and migration to the main components of the tidal ellipse, is provided.Responsible Editor: Jens Kappenberg     

Environmental Condition of Water Bodies in the Territory of an Oil–Gas Condensate Field (the Pechora Delta)

Chemical characteristics of the surface water and algae in lakes in the Seduiyakha River basin are presented. Specific features of components of limnetic ecosystems under the influence of anthropogenic factors in the territory of an oil–gas condensate field are shown. Ambiguous response of algal communities to changes in the aquatic environment is revealed.     

The State of Benthic Communities and Water Quality Evaluation in the Cheboksary Reservoir

Present-day quantitative and qualitative characteristics of the Cheboksary Reservoir have been investigated, and data on the biological diversity of benthic organisms have been compared to those of hydrobiological studies carried out in the region prior to the reservoir construction. The reservoir bottom communities include 75 species and forms of benthos. The reservoir water quality has been evaluated using different methods, including the determination of the degree of morphological structure abnormalities in chironomid larvae, regarded as sublethal indicators of bottom sediment pollution with toxic substances.