Carbon Isotope Geochemistry of the Orinoco Basin

Stable carbon isotope ratios have been used to study the sources of particulate organic carbon (POC) and total dissolved inorganic carbon in the Orinoco Basin. The isotopic composition of total dissolved inorganic carbon shows a range of from -8·1 to -23·0 ppt, an indication of dominance of biological processes. The isotopic composition of POC exhibits a range of from -24·1 to -34·6 ppt with little seasonal variation. The isotopic evidence indicates that the POC is predominantly of terrestrial origin rather than a result of in situ planktonic production. The similarity of isotopic composition of POC and coastal sediments suggests that riverine organic detritus has been transported 30-50 km offshore in a direction parallel to the Orinoco river channel.     

Modelling the sustainability and productivity of pastoral systems in the communal areas of Namaqualand

We investigated the effects of rainfall and the number of animals on changes in vegetation and on the output of milk and meat from the communal areas of Namaqualand. Previously published short- and long-term models link processes that range from the levels of tissue (in, for example, the mammary gland), to the milk yields of individual animals, to the growth and survival of their young and to long-term changes in plant species populations at the ecosystem level. These models have been used to study how different factors and management strategies affect livestock productivity and vegetation composition on a 20,000 ha rangeland in Namaqualand. First, the inter-relations between rainfall, stocking rate and productivity were studied using the short-term model. This model shows that in addition to total rainfall and stocking rate, the timing of rainfall within a year also influences doe live weight and survival to the end of the year. When the long-term model is run, using recorded rainfall, predictions of small stock numbers agree closely with livestock data recorded over the same 30-year period. One thousand replicates of 100-year runs of the long-term model were then used to study the probable impact of different upper limits to stock numbers on animal performance. Off take (sales and slaughterings) are maximal when stock numbers are limited to 2000 adults. Animal numbers increase marginally as the limit is increased above this level, but the variability between years in numbers increases. Secondly, the long-term model was used to study the long-term effects of the stocking rate strategies on rangeland condition. The model predicts that although these effects are variable, when moderately degraded range is stocked with an upper limit at the recommended level it is unable to recover to less degraded states over 100 years. Thirdly, the model was used to examine the effects of reduction in stock numbers and slaughtering of kids in a drought year on goat numbers during the subsequent 5 years. Finally, the model predicts that a 10% reduction in mean annual rainfall will lead to a 35% reduction in animal numbers over 200 years.     

The nature of crystalline silica from the TAG submarine hydrothermal mound, 26°N Mid Atlantic Ridge

Silica occurs in abundance in a variety of hydrothermal samples from the Trans-Atlantic Geotraverse (TAG) hydrothermal mound, 26°N Mid-Atlantic Ridge. The water content, trace element chemistry, and mineralogy of crystalline silica from 15 different samples have been examined by vibrational spectroscopy and probe microanalysis. The samples are from: shallow subsurface ferric iron oxyhydroxide silica deposits (n=4), a fragment of an active white smoker chimney (n=1), anhydrite bearing hydrothermal breccias (n=2), pyrite silica breccias (n=3), and silicified wall rock breccias (n=5). Length-fast chalcedony occurs in association with variable quantities of ferric iron oxyhydroxides in hydrothermal breccias from the mound flanks, within shallower subsurface chert samples, and within white smoker chimney walls. Samples from the anhydrite zone contain textures which are suggestive of an origin involving replacement of anhydrite. Samples taken from TAG 1 and 5 from below the anhydrite zone contain no chalcedony. Instead they contain subhedral quartz crystals which show oscillatory zoning in aluminium. Two types of crystalline silica namely, type A and type B quartz, are defined on the basis of the infrared spectra in the OH region from 3200 cm⁻¹ to 3600 cm⁻¹. The type A quartz occurs beneath the anhydrite zone at TAG 1 and 5. We propose a model that relates specific varieties of crystalline silica to different thermal and chemical environments within the mound interior. Length-fast chalcedony occurs in an outer low temperature envelope across the top and sides of the mound. The common association between length-fast chalcedony and ferric iron oxyhydroxides suggests that chalcedony crystallization is favoured where catalysis by ferric iron can occur. The apparent suppression of fibrous silica at the expense of single quartz crystals with increasing depth is attributed to differing growth rates and degrees of supersaturation of silica-bearing solutions with increasing temperature within the mound. The transition from type A to type B single crystal growth is interpreted to occur at temperatures approaching ˜360 °C due to decreasing solubility of aluminium in quartz, so that aluminium is rendered unavailable for type A valence compensation. Received: 10 September 1998 / Accepted: 6 July 1999     

The Ni–Antimonide Mineral Assemblage: A Product of Recrystallization of Sn–Pb–Zn Ores of the Yuzhnoe Deposit,Sikhote-Alin,Russia

Doklady Earth Sciences - A mineral assemblage with nisbite NiSb2 and breithauptite NiSb unique for a Mesozoic (Sn)–Pb–Zn vein deposit is found during mineralogical–geochemical...     

Holocene activity of the Scilla Fault, Southern Calabria: Insights from coastal morphological and structural investigations

Integration of on-land and offshore geomorphological and structural investigations coupled to extensive radiometric dating of co-seismically uplifted Holocene beaches allows characterization of the geometry, kinematics and seismotectonics of the Scilla Fault, which borders the eastern side of the Messina Strait in Calabria, Southern Italy. This region has been struck by destructive historical earthquakes, but knowledge of geologically-based source parameters for active faults is relatively poor, particularly for those running mostly offshore, as the Scilla Fault does. The  30 km-long normal fault may be divided into three segments of  10 km individual length, with the central and southern segments split in at least two strands. The central and northern segments are submerged, and in this area marine geophysical data indicate a youthful morphology and locally evidence for active faulting. The on-land strand of the western segment displaces marine terraces of the last interglacial (124 to 83 ka), but seismic reflection profiles suggest a full Quaternary activity. Structural data collected on bedrock faults exposed along the on-land segment provide evidence for normal slip and  NW-SE extension, which is consistent with focal mechanisms of large earthquakes and GPS velocity fields in the region. Detailed mapping of raised Holocene marine deposits exposed at the coastline straddling of the northern and central segments supplies evidence for two co-seismic displacements at  1.9 and  3.5 ka, and a possible previous event at  5 ka. Co-seismic displacements show a consistent site value and pattern of along-strike variation, suggestive of characteristic-type behaviour for the fault. The  1.5–2.0 m average co-seismic slips during these events document M_e  6.9–7.0 earthquakes with  1.6–1.7 ka recurrence time. Because hanging-wall subsidence cannot be included into slip magnitude computation, these slips reflect footwall uplift, and represent minimum average estimates. The palaeoseismological record based on the palaeo-shorelines suggests that the last rupture on the Scilla Fault during the February 6, 1783 M_w = 5.9–6.3 earthquake was at the expected time but it may have not entirely released the loaded stress since the last great event at  1.9 ka. Comparison of the estimated co-seismic extension rate based on the Holocene shoreline record with available GPS velocities indicates that the Scilla Fault accounts for at least  15–20% of the contemporary geodetic extension across the Messina Strait.     

The geology of the Caribbean crust, I: Beata Ridge

Igneous and sedimentary rocks recently dredged and cored from the steep western slope of the Beata Ridge provide important data on the composition, age and details of crustal evolution of the rock-types responsible for recorded compressional wave velocities. The sedimentary rock samples also provide new data concerning the age and depositional environment of overlying sedimentary reflectors.

The deepest (4,100 m) dredge haul contains deeply weathered coarsegrained igneous rocks. Nine other hauls, distributed between 4,000–2,300 m, contain holocrystalline basalts and diabases. The compressional wave velocity of air-dried samples of two holocrystalline basalts and a diabase at atmospheric pressure ranges from 5.0–5.6 km/sec. Sampling in depths less than 2,300 m shows that the crest of the Beata Ridge is capped by Quaternary deposits underlain by consolidated carbonate sediment of at least Middle Eocene age. The faunal assemblages of the Mid-Eocene samples are the product of normal accumulation in a shallow shelf environment.

The dredging results coupled with previously published seismic reflection and refraction data, suggest that the 5.4–5.7 km/sec crust is composed of a layer of basalt and diabase which outcrops below 2,300 m, on a fault-generated escarpment that was produced in the Late Cretaceous-Early Tertiary. The shallow shelf samples of Eocene age indicate that the Beata Ridge was higher in the Early Tertiary and has subsided subsequently to its present depth.     

Bioconcentration factors for petroleum hydrocarbons, PAHs, LABs and biogenic hydrocarbons in the blue mussel

Bioconcentration factors (K_bc) for petroleum hydrocarbons, PAHs, LABs and biogenic hydrocarbons in Mytilus edulis were measured in field experiments using time-integrating water samplers. Seven deployments at five sites gave lipid weight K_bcs for total hydrocarbons ranging from 0.99 × 10⁶ to 3.1 × 10⁶ (mean 1.6 × 10⁶)—a narrower range than has been obtained previously. Bioconcentration factors for the PAHs were similar to those for total hydrocarbons where the major hydrocarbon source was oil. However, at other sites the factors for PAHs were an order of magnitude lower than those for petroleum and for hydrocarbons originating from algae. Compositional profiles for the linear alkyl benzenes (LABs) suggested that these compounds were assimilated primarily from the dissolved phase, despite their greater abundance on particles.     

The kinematic dynamo action of spiralling convective flows

We consider the kinematic production of magnetic fields in a sphere by velocity fields dominated by differential rotation and spiralling convective cells. The high magnetic Reynolds number limit of Braginsky (1964) is considered and formulae are derived allowing an α-effect parametrization of such flows to be easily calculated. This permits an axisymmetric system to be investigated in parallel with the direct 3-D numerical computations. Good agreement between the asymptotic and 3-D calculations is found. The 'spiralling' property typical of convective motion in rotating spheres is important in terms of dynamo action; the differential rotation coexisting with this feature is also vital. Indeed, it is the presence of both features which allows the analysis of Braginsky to be employed. With flows approximating the columnar form anticipated for rapidly rotating convection, dynamo action is relatively easily achieved for all azimuthal wavenumbers; modes of differing wavenumbers interact almost by a simple superposition. With flows of more complex latitudinal form, the mutual interactions between modes become more complicated. For columnar-type flows, dipole magnetic fields are favoured when the sense of outward spiralling is prograde and the zonal flow is eastwards, as is physically preferred.     

Recherches complémentaires sur le bases du calculateur météorologique «Temp»

Résumé La formule de base, traduisant une propriété analytique d'une classe très générale de fonctions, est un corollaire du théorème fondamental démontré dans un mémoire précédent, d'après lequel, étant donnés une fonction continue,p(, ,t) des points (, ) d'une surface régulière fermée et du temps et le champ d'un vecteur vitesse de transfert ou d'advection tangent à et ayant des lignes de flux fermées et régulières, il existe un opérateur spatial, linéaire, non singulierA tel que la fonctionA(p+Const.) soit purement advective par rapport a (sans creusement ni comblement). Ce théorème peut être exprimé par l'équation , où est un opérateur spatial, linéaire et non singulier, fonction deA.La détermination de peut être faite, soit en comparant deux formes différentes de la solution générale de l'équation en , soit en utilisant un raisonnement a priori très simple. On arrive ainsi au résultat pour un certain scalaireu(, ).Dans le cas oùp(, ,t) est la perturbation de la pression sur la surface du géoïde l'équation résulte aussi, comme nous l'avons montré dans le mémoire précédent, de notre théorie hydrodynamique des perturbations. On montre ici que la même équation peut encore être déduite de l'équation de continuité associée à la condition d'équilibre quasi statique selon la verticale.Comme applications de la formule de base (solution générale de l'équation enM), on étudie les problèmes suivants: 1^o creusement et comblement en général; 2^o creusement et comblement des centres et des cols; 3^o mouvement des centres et des cols; 4^o instabilité d'un champ moyen; 5^o propriétés spatiales des champsp(, ,t) et des vecteurs d'advection analytiques.Après une discussion des erreurs de la prévision d'un champp(, ,t) par la formule de base, du fait des erreurs des observations et du fonctionnement du calculateur, on examine quelques particularités du transfert ou advection d'un champf ₀(, ) par le vecteur . Enfin, le dernier chapitre du mémoire donne des éclaircissements complémentaires sur la structure du calculateur électronique «Temp» (qui effectue automatiquement les opérations mathématiques de la formule de base) et expose l'état actuel de sa construction.

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Summary The basic formula, expressing an analytical property of a very general class of functions, is a corollary of the fundamental theorem, proved in a previous paper, according to which, given a functionp(, ,t) of the points (, ) of a closed regular surface and of the time, and a transfer or advection velocity vector tangent to and having regular closed streamlines, there is a spatial, linear, non singular operatorA such thatA(p+const.) is a purely advective function in respect to (no deepening). This theorem can be expressed by the equation where is a spatial, linear, non singular operator depending onA.The determination of can be attained, either by the comparison of two different forms of the general solution of the -equation, or by a simple a priori reasonning. The conclusion is thus reached that for a certain scalaru(, ).Whenp(, ,t) is the pressure perturbation at sea level, it was shown, in the preceding paper, that the equation can also be derived from our hydrodynamical perturbation theory. We now show that for this particular case, the same equation is also a consequence of the equation of continuity together with the condition of quasi statical vertical equilibrium.The following problems are then analysed by means of the basic formula: 1^o deepening and filling in general; 2^o deepening and filling of the centres and cols; 3^o motion of the centres and cols; 4^o instability of a mean field; 5^o spatial properties of the analytical fields and advection vectors .The errors in the forecast of a field,p(, ,t) by means of the basic formula, due to the observational and computational errors, are discussed, and some peculiarities of the transfer or advection of a fieldf ₀(, ) by are examined. Finally, complementary points are disclosed on the structure of the electronic computer «Temp» which performs automatically the mathematical operations of the basic formula, and a brief report is given of the present state of its construction.