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961.
An ephemeral estuarine turbidity maximum (ETM) occurs at high water in the macrotidal Taf estuary (SW Wales, United Kingdom).
A new mechanism of ETM formation, due to resuspension and advection of material by flood tidal currents, is observed that
differs from classical mechanisms of gravitational circulation and tidal pumping. The flood tide advances across intertidal
sand flats in the main body of the estuary, progressively entraining material from the rippled sands. Resuspension creates,
a turbid front that has suspended sediment concentrations (SSC) of about 4,000 mg I−1 by the time it reaches its landward limit which is also the landward limit of salt penetration. This turbid body constitutes
the ETM. Deposition occurs at high slack water but the ETM retains SSC values up to 800 mg I−1, 1–2 orders of magnitude greater than ambient SSC values in the river and estuarine waters on either side. The ETM retreats
down the estuary during the ebb; some material is deposited thinly across emergent intertidal flats and some is flushed out
of the estuary. A new ETM is generated by the next flood tide. Both location and SSC of the ETM scale on Q/R3 where Q is tidal range and R is river discharge. The greatest expression of the ETM occurs when a spring tide coincides with
low river discharge. It does not form during high river discharge conditions and is poorly developed on neap tides. Particles
in the ETM have effective densities (120–160 kg m−3) that are 3–4 times less than those in the main part of the estuary at high water. High chlorophyll concentrations in the
ETM suggest that flocs probably originate from biological production in the estuary, including production on the intertidal
sand flats. 相似文献
962.
963.
The effects of advection, dispersion, and biological processes on nitrogen and phytoplankton dynamics after a storm event
in December 2002 are investigated in an estuary located on the northern New South Wales coast, Australia. Salinity observations
for 16 d after the storm are used to estimate hydrodynamic transports for a one-dimensional box model. A biological model
with nitrogen limited phytoplankton growth, mussel grazing, and a phytoplankton mortality term is forced by the calculated
transports. The model captured important aspects of the temporal and spatial dynamics of the bloom. A quantitative analysis
of hydrodynamic and biological processes shows that increased phytoplankton biomass due to elevated nitrogen loads after the
storm was not primarily regulated by advection or dispersion in spite of an increase in river flow from <1 to 928×103 m3 d−1. Of the dissolved nitrogen that entered the surface layer of the estuary in the 16 d following the storm event, the model
estimated that 28% was lost through exchange with the ocean or bottom layers, while 15% was removed by the grazing of just
one mussel species,Xenostrobus securis, on phytoplankton, and 50% was lost through other biological phytoplankton loss processes.X. securis grazing remained an important loss process even when the estimated biological parameters in the model were varied by factors
of ± 2. The intertidal mangrove pneumatophore habitat ofX. securis allows filtering of the upper water column from the lateral boundaries when the water column is vertically stratified, exerting
top-down control on phytoplankton biomass. 相似文献
964.
The feasibility of using the more sophisticated weighted least-squares (WLS) model, as opposed to the traditional ordinary least-squares (OLS), in linear regressions of BHT data to estimate the static formation temperatures (SFT) was investigated. The most commonly used analytical methods (line-source; spherical and radial heat flow; and cylindrical heat source) were applied. Error propagation equations were derived to calculate errors in the time function of each method. These errors were combined with the BHT measurement errors to compute weighting factors for applying the WLS. Intercept uncertainties were estimated for all regressions using sets of synthetic and actual borehole logs taken from geothermal and oil applications. SFT computed with the spherical and radial heat flow method were generally greater than those from the other two methods. 相似文献
965.
J.D. Martín-Martín J. Tritlla E. Cardellach D. Gmez-Gras 《Journal of Geochemical Exploration》2006,89(1-3):267
Fluid inclusions and clay mineralogy of the Permo-Triassic rocks from the Espina and Espadà Ranges (SE Iberian Chain, Spain) have been investigated to establish their relationship with hydrothermal fluid circulation during the Alpine Orogeny. Primary fluid inclusions in quartz-filled tension gashes in Permo-Triassic sandstones reveal maximum temperatures around 230 °C and very constant salinities of 8.5% wt. eq. NaCl. Secondary fluid inclusions found in quartz from the Santonian Ba–Cu–Hg deposits show similar compositional and thermodynamic characteristics, denoting an Alpine recrystallization. Clay mineral composition of Permo-Triassic mudrocks is characterized by pyrophyillite, indicating low-grade metamorphic conditions. Field observations and experimental data suggest that the crystallization of quartz in tension gashes, the formation of secondary fluid inclusions and the development of the metamorphism are contemporaneous and related to fluid circulation during the Alpine compression. Fluid flow took place along the Hercynian fault system that was reactivated during the Mesozoic rift stage and inverted during the Alpine deformation. 相似文献
966.
The genesis of Lower Eocene calcite-cemented columns, “pisoid”-covered structures and horizontal interbeds, clustered in dispersed outcrops in the Pobiti Kamani area (Varna, Bulgaria) is related to fossil processes of hydrocarbon migration. Field observations, petrography and stable isotope geochemistry of the cemented structures and associated early-diagenetic veins, revealed that varying seepage rates of a single, warm hydrocarbon-bearing fluid, probably ascending along active faults, controlled the type of structure formed and its geochemical signature. Slow seepage allowed methane to oxidize within the sediment under ambient seafloor conditions (δ18O = − 1 ± 0.5‰ V-PDB), explaining columns' depleted δ13C ratios of − 43‰. Increasing seepage rates caused methane to emanate into the water column (δ13C = − 8‰) and raised precipitation temperatures (δ18O = − 8‰). Calcite-cemented conduits formed and upward migrating fluids also affected interbed cementation. Even higher-energy fluid flow and temperatures likely controlled the formation of “pisoids”, whereby sediment was whirled up and cemented. 相似文献
967.
R.E. Villanueva R.M. Prol-Ledesma M.A. Torres-Vera C. Canet M.A. Armienta C.E.J. de Ronde 《Journal of Geochemical Exploration》2006,89(1-3):414
A primary aim for sampling of submarine hydrothermal vents is to minimize inclusion of ambient seawater. Here, we compare the results of three different sampling methods (air displacement, two-valve bottle, and syringes) for shallow submarine systems. Mixing of hydrothermal fluid with seawater is unavoidable; however, calculations based on linear mixing models allow estimation of the hydrothermal fluid end-member composition. The results show that sampling with a two-valve bottle and syringes are the best options because they allow collection of samples with a large proportion of hydrothermal fluid. Additionally, we compare the results of in situ and laboratory analyses of the fluid samples, and demonstrate that determination of chemical composition in situ is the best option for some components, as re-equilibration affects some component concentrations (i.e. bicarbonate). Conversely, silica determination in situ usually underestimates the concentration in the fluid, as it does not account for polymeric silica. Other components can be measured either in the field or in the laboratory. 相似文献
968.
E. Eseme P.A. Abanda C.M. Agyingi J. Foba-Tendo R.E. Hannigan 《Journal of Geochemical Exploration》2006,91(1-3):41-55
Salts produced using brines of the Mamfe Basin were analysed by XRD for their mineral composition and ICP-MS for minor element composition. Halite (NaCl) and dolomite (CaMg (CO3)2) constitute the major minerals with minor impurities from Mo and Cd in the chlorides and Sc and Cu in the carbonates. The mineral composition is evidence of dissolution of evaporites with parent brine of marine origin. Other elements analysed are suggested to be adsorbed to these salts and result from water–rock interaction. The elements partitioned based on their correlation to other elements are suggested to derive from sulphates including barite for Ba, sulphides for Pb, Zn, silicates for Zr, Mn and oxides for V, Cr. The electrical conductance of the brines is related to the salt yield by the equation; M = 9 × 10− 4E− 3.27, and it can be used to estimate salt yield throughout the year. Over 1200 tons of salt consisting dominantly of grade I halite are lost annually as brines across the basin. Purification is required for some minor elements including Ba, Pb, Hg and Cd for use as a condiment. A genetic relation between the parent brine, sulphide minerals and organic matter-rich sediments is proposed. 相似文献
969.
Christine E. Geibe Rolf Danielsson Patrick A.W. van Hees Ulla S. Lundstrm 《Applied Geochemistry》2006,21(12):2096-2111
The choice of sampling method for soil solution is of great importance. In this paper soil solution chemistry sampled by centrifugation, two types of suction lysimeters and zero-tension lysimeters have been studied with the purpose of investigating systematic differences between them. The samples were taken at 4 depths from an acidified forest soil as well as from adjacent lime and ash treated soils. A centrifugation drainage method was compared with two types of suction lysimeters (‘Rhizon’ and ‘Prenart’) and zero-tension lysimeters. About half of the 27 variables measured showed a significant difference between the sampling methods used. Typically the centrifuged samples had lower pH (4.0 vs. 4.4), Ca (21 μM vs. 30 μM) and Mg (25 μM vs. 34 μM) concentrations and higher Cl (330 μM vs. 230 μM) and DOC (4.4 mM vs. 3.2 mM) concentrations than the Rhizon lysimeters. Also the other lysimeters showed significant differences compared to the centrifuged samples for about half the number of analytes. Centrifuged samples had higher concentrations of all analytes except NO3 and PO4 compared to zero-tension lysimeters and also for all analytes except NO3 and Al compared to Prenart lysimeters. Among the environmental factors considered depth showed an influence to some extent, while sampling occasion had a great significant impact on the difference between the centrifugation method and the Rhizon lysimeters. Factors like individual pits or soil treatment did not show any influence on the difference between the methods. 相似文献
970.
Renato Moraes Reinhardt A. Fuck Mrcio Martins Pimentel Simone M.C.L. Gioia Maria H.B.M. de Hollanda Richard Armstrong 《Journal of South American Earth Sciences》2006,20(4):287-301
The Barro Alto Complex and Juscelândia volcanosedimentary sequence are exposed in the central part of the Neoproterozoic Brasília belt of central Brazil. The former is a large (approximately 150 km long), boomerang-shaped, mafic-ultramafic, layered complex formed by two different intrusions metamorphosed under granulite facies. These rocks are tectonically overlain by rocks of the Juscelândia volcanosedimentary sequence, represented mainly by biotite-gneiss and amphibolite, or amphibolite facies metamorphic equivalents of rhyolite and basalt, respectively. New SIMS U–Pb zircon data and Sm–Nd isochron data presented herein help clarify the igneous and metamorphic evolution of the Juscelândia volcanosedimentary sequence, as well as its relationship with the Barro Alto Complex. Zircon grains from two biotite gneisses were analyzed by SIMS (SHRIMP) and indicate Mesoproterozoic dates, approximately 1.28 Ga, interpreted as the time of bimodal volcanism in a tectonic setting transitional between a continental rift and an ocean basin. Metamorphism is constrained by Sm–Nd garnet-whole-rock isochrons for garnet amphibolite and pelitic schists of the Juscelândia sequence, as well as for clinopyroxene-garnet amphibolite and garnet granulite of the Barro Alto Complex, which give ages between 0.74 and 0.76 Ga, in agreement with SIMS dates for metamorphic zircon rims. These new data are significant, because they establish that a single metamorphic event affected both the Barro Alto Complex and the Juscelândia sequence. Based on these new data, we present a modified tectonic model for the Brasília belt. 相似文献