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701.
Stephen V. Smith Silvia E. Ibarra-Obando Victoria Díaz-Castañeda Francisco Javier Aranda-Manteca José D. Carriquiry Brian N. Popp Oscar Gonzalez-Yajimovich 《Estuaries and Coasts》2008,31(4):719-727
Sediment grain size and organic carbon (OC) data collected over the past 50 years, together with δ13C values of OC in recently collected samples, were analyzed to improve understanding of sediment OC distribution and abundance in Todos Santos Bay. Sediments in the submarine canyon at the mouth of the bay and in quiet-water locations along the shore are fine grained, high in OC, and have generally low δ13C values; sediments in high-energy environments are low in OC and have high δ13C values. A bivariate isotopic mixing model indicates that none of the sediments contain >50% terrigenous OC (average ~30%), and that the terrigenous OC content of the sediments is a small proportion of the OC content of local soils. Sediment OC composition is apparently controlled by energy-related sorting and deposition, oxidation of much of the original terrigenous OC, and replacement of some terrigenous OC by marine OC. 相似文献
702.
703.
A combined mathematical geophysical model for prediction of pyrite oxidation and pollutant leaching associated with a coal washing waste dump 总被引:3,自引:0,他引:3
F. Doulati Ardejani Ph.D. B. Jodieri Shokri M.Sc. A. Moradzadeh Ph.D. E. Soleimani Ph.D. M. Ansari Jafari Ph.D. 《International Journal of Environmental Science and Technology》2008,5(4):517-526
The waste produced by coal washing process produces many environmental problems. In this study, the pollution problems associated with the waste produced by Alborz Sharghi Coal Washing Plant was investigated by mathematical modeling. The study area is located at 11 km. to Razmjah coal region and 45 km. to Tehran-Mashhad road in the north part od Iran. To achieve the goal, a few samples were taken from different depths at three points on the waste dump in order to investigate pyrite oxidation and pollution generation. The samples were then analysed, using an AA-670 Shimadzu atomic absorption to determine the fraction of pyrite remained within the waste particles. A numerical finite volume model using Phoenics package has been developed to simulate pyrite oxidation and pollution generation from the Alborz Sharghi coal washing waste dump. The pyrite oxidation reaction is described by the shrinking-core model. Gaseous diffusion is the main mechanism for the transport of oxygen through the waste. The results of numerical modelling were compared with the field observations and close agreement was achieved. A simple mathematical model incorporating advection and hydrodynamic dispersion processes was also presented in order to verify the results of geophysical time-laps method showing transportation of the pollutants through the downstream of the waste dump. Both mathematical model and geophysical time-laps method are agreed in the identification of pollutant transport emanated from the waste dump. The results of such investigations can be used for designing an effective environmental management program. 相似文献
704.
R. A. Oktyabrsky A. A. Vrzhosek A. M. Lennikov T. A. Yasnygina S. V. Rasskazov E. Yu. Moskalenko T. A. Velivetskaya 《Russian Journal of Pacific Geology》2008,2(4):325-335
New geochemical data are presented on the magmatic rocks of the Late Jurassic Koksharovka alkaline-ultrabasic massif, which is associated with deposits of vermiculite, apatite, V-bearing titanomagnetite, and placer isoferroplatinum. The REE geochemistry and strontium, oxygen, and carbon isotopic composition of carbonatites and related ijolites and pyroxenites, together with geological observations, point to the magmatic origin of the Koksharovka carbonatites. The origin of associated magmatic rocks is discussed. Trace element modeling of partial melting of mantle sources was conducted to decipher the genesis of the melts of the Koksharovka carbonatites and host titanite-kaersutite pyroxenites. 相似文献
705.
Inversely-Mapped Analytical Solutions for Flow Patterns around and within Inclined Elliptic Inclusions in Fluid-Saturated Rocks 总被引:1,自引:0,他引:1
Chongbin Zhao Bruce E. Hobbs Alison Ord Shenglin Peng Liangming Liu 《Mathematical Geosciences》2008,40(2):179-197
In this paper, an inverse mapping is used to transform the previously-derived analytical solutions from a local elliptical
coordinate system into a conventional Cartesian coordinate system. This enables a complete set of exact analytical solutions
to be derived rigorously for the pore-fluid velocity, stream function, and excess pore-fluid pressure around and within buried
inclined elliptic inclusions in pore-fluid-saturated porous rocks. To maximize the application range of the derived analytical
solutions, the focal distance of an ellipse is used to represent the size of the ellipse, while the length ratio of the long
axis to the short one is used to represent the geometrical shape of the ellipse. Since the present analytical solutions are
expressed in a conventional Cartesian coordinate system, it is convenient to investigate, both qualitatively and quantitatively,
the distribution patterns of the pore-fluid flow and excess pressure around and within many different families of buried inclined
elliptic inclusions. The major advantage in using the present analytical solution is that they can be conveniently computed
in a global Cartesian coordinate system, which is widely used in many scientific and engineering computations. As an application
example, the present analytical solutions have been used to investigate how the dip angle of an inclined elliptic inclusion
affects the distribution patterns of the pore-fluid flow and excess pore-fluid pressure when the permeability ratio of the
elliptic inclusion is of finite but nonzero values. 相似文献
706.
On the use of gravity and magnetic anomalies for locating probable areas of metallic mineralization in South Sinai, Egypt 总被引:1,自引:0,他引:1
The present study deals with processing and interpreting the potential gravity and magnetic data in order to locate promising
sites for metallic mineral occurrences in the basement rocks of South Sinai. Two promising sites were anticipated by combining
the geophysical results and the available geological information. Each site was profiled and interpreted to the nearly approximated
subsurface feature model, and the geometrical parameters of the expected subsurface structures may form mineralized bodies
such as depth, thickness, width, dipping, density contrast, and magnetic susceptibility contrast could be delineated. Detailed
ground Very Low Frequency (VLF) and Vertical Magnetic Gradient (VMG) methods were carried out in the site A2, eight VLF and
VMG anomalies were determined, and their depths were calculated. 相似文献
707.
In Part I we focussed on a convergent representation of the gravitational potential generated bytopographic masses on top of the equipotential surface atMean Sea Level, thegeoid, and by those masses which compensate topography. Topographic masses have also been condensated, namely represented by a single layer. Part II extends the computation of the gravitational field of topographic-isostatic masses by a detailed analysis of itsforce field in terms ofvector-spherical harmonic functions. In addition, the discontinuous mass-condensated topographic gravitational force vector (head force) is given. Once we identify theMoho discontinuity asone interface of isostatically compensated topographical masses, we have computed the topographic potential and the gravitational potential which is generated by isostatically compensated masses atMean Sea Level, the geoid, and illustrated by various figures of geoidal undulations. In comparison to a data oriented global geoid computation ofJ. Engels (1991) the conclusion can be made that the assumption of aconstant crustal mass density, the basic condition for isostatic modeling, does not apply. Insteaddensity variations in the crust, e.g. betweenoceanic and continental crust densities, have to be introduced in order to match the global real geoid and its topographic-isostatic model. The performed analysis documents that thestandard isostatic models based upon aconstant crustal density areunreal. 相似文献
708.
We used transmission electron microscopy (TEM) and scanning electron microscopy (SEM) to study magmatic crystals in the Ben
Lomond rhyolite lava dome, Taupo Volcanic Center, New Zealand. Using TEM and SEM to investigate the size distributions of
these crystals, we identified three size populations: microphenocrysts (>1.2 μm wide), microlites (>0.6 μm wide), and smaller
crystals (<0.6 μm wide) which we term "nanolites". The predominant mineral phases of the microlites and nanolites are augites,
pigeonites, and hypersthenes. The compositions and microstructures within these pyroxenes indicate disequilibrium crystallization
at approximately 850–900 °C and undercoolings as high as 300 °C from equilibrium crystallization temperatures. Complex microstructures
resulting from subsolidus reactions in augite and pigeonite are consistent with moderate cooling rates within the upper obsidian
layer of the Ben Lomond rhyolite dome. This study demonstrates the existence of sub-micron magmatic crystals in a rhyolite
and illustrates the potential of TEM to provide unique information about the crystallization and cooling histories of glassy
volcanic rocks.
Received: May 8, 1995 / Accepted: November 27, 1995 相似文献
709.
Summary In-situ microprobe LREE analyses of perovskite and titanite (La, Ce, Nd), and apatite (La, Ce), from SW Ugandan clinopyroxenite xenoliths and kamafugite lavas indicate that LREE distribution in these minerals is determined by a number of factors related to their different parageneses: In particular LREE content is affected by whether the LREE-bearing minerals have crystallised from metasomatic carbonate or from silicate (i.e. metasomatic or magmatic) melts in the mantle. In this situation LREE partition favours carbonate over silicate melts. Distribution of LREE in perovskite and apatite crystallised from magmatic mantle melts or mantle-derived lavas is chiefly determined by preference of LREE for perovskite > apatite > titanite. LREE zoning in perovskite is influenced by changes in melt structure: increasing melt polymerisation enhancing mineralLREE/meltLREE partition into perovskite rims in magmatic xenoliths; decreasing melt polymerisation depleting LREE in lava perovskite rims. This zoning is reinforced by perovskite competition with apatite for LREE: perovskite (cores/rims) co-crystallising with apatite is reduced in LREE. There are 37 instances of perovskitewith Ce below detection while La and Nd levels are normal. These occur in both xenoliths and lavas; in grain zones or whole grains. Likewise Ce alone of the LREE is below detection in six out of ten titanite analyses. These observations are interpreted as evidence for increased fO
2, Ce4 + being excluded from these mineral structures. Recognition of these various processes can elucidate the interpretation of bulk rock and bulk mineral LREE signatures in kamafugite volcanism.
With 3 Figures 相似文献
LREE Verteilung in Perovskit, Apatit und Titanit aus Xenolithen und kamafugitischen Laven Südwest-Ugandas
Zusammenfassung In-situ LREE Analysen von Perovskit und Titanit (La, Ce, Nd) und Apatit (La, Ce) aus Klinopyroxenit-Xenolithen und kamafugitischen Laven Südwest-Ugandas zeigen, daß die LREE Verteilung in diesen Mineralen durch eine Vielzahl von Faktoren, die mit Unterschieden in den Paragenesen zusammenhängen, bestimmt wird: Der LREE-Gehalt wird im besonderen davon bestimmt, ob die LREE-führenden Minerale aus metasomatischen Karbonat- oder aus (metasomatischen oder magmatischen) Silikatschmelzen im Mantel auskristallisierten. Dabei erfolgt die LREE Fraktionierung zu Gunsten der Karbonatschmelzen. Die LREE-Verteilung von Perovskit und Apatit, die aus magmatischen Mantelschmelzen oder -laven kristallisierten, wird vorrangig durch den bevorzugten Einbau der LREE in Perovskit > Apatit > Titanit kontrolliert. Der LREE Zonarbau von Perovskit wird durch die Änderungen der Schmelzstruktur beinflußt: Verstärkte Schmelzpolymerisation führt zu verstärkter MineralLFEE/SchmelzeLREE Fraktionierung in den Perovskiträndern magmatischer Xenolithe, eine Abnahme der Schmelzpolymerisation hingegen resultiert in einer Abreicherung der LREE in den Perovskiträndern. Diese Art der Zonierung wird durch den Wettbewerb von Perovskit mit Apatit um die LREE verstärkt. Perovskit (Kerne/Ränder), der mit Apatit gemeinsam auskristallisierte, ist ärmer an LREE. 37 Fälle, in denenCe nicht nachweisbar war, La und Nd aber in normaler Konzentration auftreten, wurden sowohl in den Xenolithen als auch in den Laven gefunden; und zwar entweder in Kornbereichen oder in ganzen Körnern. Vergleichsweise liegt Ce nur in sechs von zehn Titanitproben unterhalb der Nachweisgrenze. Diese Beobachtungen werden als Hinweise auf erhöhte SauerstoffFugazitäten, bei denen Ce4– aus der Mineralstruktur ausgeschlossen wird, angesehen.Ein Verständnis dieser verschiedenen Prozesse kann zur besseren Interpretation von LREE Gesamtgesteins- und Gesamtmineral-Signaturen in Kamafugiten beitragen.
With 3 Figures 相似文献
710.
Ohishi M Ishikawa SI Amano T Oka H Irvine WM Dickens JE Ziurys LM Apponi AJ 《The Astrophysical journal》1996,471(1):L61-L64
A new interstellar molecular ion, H2COH+ (protonated formaldehyde), has been detected toward Sgr B2, Orion KL, W51, and possibly in NGC 7538 and DR21(OH). Six transitions were detected in Sgr B2(M). The 1(1,0)-1(0,1) transition was detected in all sources listed above. Searches were also made toward the cold, dark clouds TMC-1 and L134N, Orion (3N, 1E), and a red giant, IRC + 10216, without success. The excitation temperatures of H2COH+ are calculated to be 60-110 K, and the column densities are on the order of 10(12)-10(14) cm-2 in Sgr B2, Orion KL, and W51. The fractional abundance of H2COH+ is on the order of 10(-11) to 10-(9), and the ratio of H2COH+ to H2CO is in the range 0.001-0.5 in these objects. The values in Orion KL seem to be consistent with the "early time" values of recent model calculations by Lee, Bettens, & Herbst, but they appear to be higher than the model values in Sgr B2 and W51 even if we take the large uncertainties of column densities of H2CO into account. We suggest production routes starting from CH3OH may play an important role in the formation of H2COH+. 相似文献