Elucidation of the Alum Shale kerogen structure using a multi-disciplinary approach

The significance and validity of integrating data obtained from a variety of analytical techniques to understand, elucidate and model kerogen's complex chemical structure is reported here using degradative (open and closed system pyrolysis, chemical oxidation), non-degradative (¹³C CP/MAS NMR) and optical (incident white light and blue light) methods. Seven Cambrian Alum Shale samples, ranging in maturity from immature to post-mature with respect to petroleum generation, were studied and were chosen for their simple geological history, uniform organic matter type and high organic carbon content. The Alum Shale kerogens, which primarily consist of algal organic matter, liberate low molecular weight gaseous and aromatic compounds on pyrolysis and give mostly branched dicarboxylic acids on chemical oxidation. ¹³C NMR spectroscopy shows that the Alum Shale kerogens are anomalously rich in oxygen-bearing functional groups (such as C = O, ArCO, CHO, CH_xO), most of which apparently remain intact within the kerogen macro-molecule (KMM) through the diagenetic and catagenetic stages. Fragments released by different degradative techniques are quantified and the aromaticity (f_a), O/C and relative proportions of various carbon types estimated by ¹³C NMR. A synthesis of these data has allowed us to better understand the chemistry of the Alum Shale kerogen.     

The axial momentum balance of Earth and its fluid envelope

The emergence of greatly improved data sets over the past decade has heightened awareness of the close relationship between changes in the axial component of the angular momentum of the atmosphere and that of the solid Earth, the latter being reflected in small, though detectable, changes in the planet's rate of rotation. Changes in the large-scale wind field, and hence in atmospheric angular momentum, on intraseasonal through interannual time scales can be associated with a number of identifiable meteorological phenomena, whose further study has been given new impetus by the discovery of their signals in Earth's rotation. Future advances in the subject are apt to occur in connection with new data sets that will help address questions remaining about rapid changes in Earth rotation and the torques responsible for the momentum changes. Also in the coming decade, both new data and modeling approaches should help clarify the role of the oceanic portion of Earth's fluid envelope in the planetary momentum balance.     

The lithification and metamorphism of lunar breccias

Experimental data have been used to establish the temperature coordinates for Warner's [1] scale of lunar metamorphic grades. A model of an ejecta blanket with a hot base layer overlain by a cold top layer can produce the observed features of the Apollo 14 breccias. The breccia formation process probably encompassed temperatures between 700°C and at least 1100°C and was a reasonably rapid process (hours to days).     

Numerical analyses of deformability tests in jointed rock — “Joint Perturbation” and “No Tension” Finite Element solutions

SummaryNumerical Analyses of Deformability Tests in Jointed Rock — Joint Perturbation and No Tension Finite Element Solutions Sound design of structures in or upon rock requires a thorough knowledge of the rock mass deformability. Field test data interpretation has generally relied upon analytical or Finite Element linear elastic solutions. However, when testing in jointed rock, these can no longer be readily used since the medium cannot resist the tension induced upon loading. Accordingly, other solutions are required. If the discontinuities of the rock mass can all be mapped and their surface properties determined, the Finite Element model will use a Joint Perturbation solution where the joint elements have variable stiffnesses to account for movements along the fractures. If the discontinuities cannot be satisfactorily mapped, a global approach is provided by a No Tension analysis of the stress transfer type. The two techniques are compared in the case of bore hole jack deformability tests and found to agree remarkably well, indicating an appreciable difference from results of linear elasticity.

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ZusammenfassungNumerische Analyse von Verformungsversuchen in geklüfteten Fels — Lösungen mittels Kluft-Perturbation und No Tension Analysis auf Grund der Methode der Finiten Elemente Der Entwurf von Bauwerken in oder auf Fels erfordert eine genaue Kenntnis des Formänderungsverhaltens der Felsmasse. Im allgemeinen basiert die Interpretation der Ergebnisse von Feldversuchen auf den Lösungen des zugehörigen Randwertproblems der linearen Elastostatik mittels klassischer analytischer Methoden oder der Methode der Finiten Elemente. Wenn die Versuche aber in geklüftetem Fels durchgeführt werden, müssen die theoretischen Methoden modifiziert werden, da das Medium keine Zugspannungen aufnehmen kann. Zwei Fälle können unterschieden werden. Erstens: die Kluftflächen der Felsmasse können geometrisch erfaßt und ihre Oberflächeneigenschaften können bestimmt werden; in diesem Falle kann die Finite-Elemente-Lösung eine Kluft-Perturbations-Methode verwenden, in welcher spezielle Kluft-Elemente verschiedener Steifigkeiten normal und tangential zu den Kluftflächen die Bewegungen entlang derselben bestimmen. Zweitens: die Diskontinuitäten der Felsmasse können nicht hinreichend beschrieben werden; für diesen Fall ist vorgekehrt durch die Finite-Element-Analyse vom Typ der Spannungsumlagerung unter Ausschaltung der Zugspannungen (No Tension Analysis), um das globale Verhalten der geklüfteten Felsmasse zu erfassen. Die Lösungen dieser beiden Methoden wurden für den Fall der Bohrloch-Verformungs-Tests verglichen; der Vergleich zeigt ausgezeichnete Übereinstimmung, im Gegensatz zu den Lösungen als lineares Elastizitätsproblem.

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RésuméLa méthode des Eléments Finis appliquée aux résultats d'essais de vérins cylindriques dans les roches fissurées — solutions dites Joint Pertubé et Sans Traction La construction de structures sur ou dans des roches nécessite une connaissance approfendie de la déformabilité du massif rocheux. L'analyse des résultats d'essais en place se fait généralement à l'aide de solutions analytiques ou par Eléments Finis, qui supposent une élasticité linéaire du milieu. De fait, dans les roches fissurées, ces solutions sont inadéquates puisque le milieu ne peut résister aux sollicitations de traction. Il s'agit donc d'utiliser d'autres méthodes d'analyse. Lors qu'il est possible de déterminer la géométrie et les propriétés de toutes les discontinuités, l'on pourra utiliser une solution par Eléments Finis, dite Joint Perturbé dans laquelle la rigidité de surface du joint (ou fissure) peut varier lorsque des movements prennent place au niveau du joint. Si cela est impossible, il faudra utiliser une approche globale dite Sans Traction qui redistribue les contraintes de traction et les dissipe. On compare ces deux types de solutions dans le cas des essais de vérins cylindriques unidirectionnels. Leurs résultats sont identiques et ont nettement différents de ceux obtenus avec une solution élastique linéaire.

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Research supported by the National Aeronautics and Space Administration — Contract NAS 8-21432.

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With 8 Figures     

Periodicity in namurian sediments of derbyshire,england (a quantitative sedimentary analysis)

Five facies associations are present in the basin-filling Namurian sediments (Grindslow Shales and Kinderscout Grit) of the southern Central Pennine Basin of England. Visual study of sequences fails to disclose any pattern in the occurrence of facies. A simple mathematical statistical analysis shows that patterns do occur and approximate models can be proposed. The homogeneous siltstones (facies A) occur roughly in accord with a Poisson process model; the striped siltstones (facies B) of the sequence deviate from a renewal process model in many ways and may be most nearly approximated by some process showing trend in the rate of occurrence of events; the sharp-based sandstones (facies C) seem to occur in agreement with some type of renewal process, but not a Poissonian variety. The intervals between the sediment-building periods of these facies categories may be renewal processes of some kind, although all deviate from a simple Poisson model. Owing to the limitations of the data available only tentative conclusions can be drawn.     

New determination of the air-earth current over the ocean and measurements of ionosphere potentials

Summary The electrode effect could be detected in full magnitude on the Atlantic during the expedition of the research vessel Meteor. The average value of the electric field over the sea surface is about 125 V/m, in about 10 to 100 m over the surface only about 60 V/m. This phenomenon as well as the results of small ion records lead to a value of the air earth current density on the sea of only 0.9×10^–12 A/m², a quarter of the value accepted up to now. With these values the total current of the global air electric circuit will be about 665 A instead of 1500 to 1800 A. The ionosphere potentials over two places in a distance of 8000 km at 15 dates are nearly identical and in the average 280 kV.     

Search for exoelectrons in apollo 12 materials

The search for exoelectron emission from Apollo 12 materials usually produced negative results, suggesting that the concentration of naturally occurring traps is very low. Weak exoelectron activity was found scattered inhomogeneously within a pigeonite basalt rock and in a deep core tube sample. Its erratic appearance and intensity makes any interpretation of radiation history most difficult and is attributed to the activity being carried by only a few scattered crystals. The thermally stimulated emission of exoelectrons is judged an unsuitable technique for tracing the radiation histories of these samples.