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301.
The rate of compositional and isotopic exchange between minerals may be enhanced significantly if the rock is deformed simultaneously. The enhanced exchange rate may result from a reduction in grain size (shorter distance for volume diffusion), dissolution and growth of grains by diffusion creep (pressure solution), or the movement of high-angle grain boundaries through strained grains during recrystallization in the dislocation creep regime. The migration of high-angle grain boundaries provides high diffusivity paths for the rapid exchange of components during recrystallization. The operation of the latter process has been demonstrated by deforming aggregates consisting of two plagioclases (An1 and An79) at 900°C, 1 GPa confining pressure, and a strain rate of ∼2x10-6s-1. The polygonal, recrystallized grains were analyzed using an analytical transmission electron microscope and have a variable but often intermediate composition. At the conditions of these experiments, the volume interdiffusion rate of NaSi/CaAl is too slow to produce any observable chemical change, and microstructural-chemical relations indicate that the contribution from diffusion creep was insignificant except for initially fine-grained (2–10 μm) aggregates. These results indicate that strain-induced recrystallization can be an effective mechanism for enhancing the kinetics of metamorphic reactions and for resetting the isotope systematics of minerals such as feldspars, pyroxenes, and amphiboles.  相似文献   
302.
In 1991, a deep seismic reflection line, MPNI-9101, was acquired in the southern North Sea from the Mesozoic Broad Fourteens Basin, across the West Netherlands Basin onto the London-Brabant Massif (LBM). The resultant section shows a strongly reflective lower crust beneath the area of Mesozoic basin development. This lower crustal reflectivity continues to be strong beneath the LBM. The travel time to the base of the reflective zone increases from approximately 11.0 s beneath the Mesozoic basins to 12.5 s beneath the LBM, suggesting a southward thickening of the crust (Rijkers et al., 1993). Based on these travel times and information from deep wells and refraction surveys. Moho depth is estimated to increase from about 31 km beneath the Mesozoic basins to about 38 km beneath the LBM. This difference in depth to the Moho can partly be explained by coaxial stretching of the crust beneath the Mesozoic basins. In comparison with the Mesozoic basins, the crust beneath the LBM was thickened during the Caledonian and Variscan orogenies.  相似文献   
303.
A wide compositional continuum of basalts has been erupted from near-ridge seamounts constructed on the Cocos Plate between the Clipperton and Orozco Francture Zones. They range from highly evolved to moderately primitive (3.0–7.8% MgO), LREE-enriched alkali basalts, to moderately evolved to near-primary (5.2–9.5% MgO) tholeiites indistinguishable from N-type MORB. The data set of 159 quench glass analyses exhibits a remarkably consistent variation in both major and trace element composition that is keyed to variations in (La/Sm). Modeling of potential liquid lines of descent at pressures ranging from 1 bar to 8 kbar shows that this covariation is partially due to systematic differences in liquid lines of descent, where the alkaline lavas have undergone substantially more high pressure clinopyroxene fractionation and substantially less low pressure plagioclase fractionation than the tholeiites. In addition, systematic variation in the composition of the more primitive glasses indicates that they were derived from mixing of discrete enriched and depleted melts in the heterogenous seamount mantle source at pressures of 8–10 kbar and greater, and that clinopyroxene may be a residual phase during partial melting. These results show that porous media flow in the seamount mantle source is minor and that melt transport is accomplished primarily through cracking and diking. This study supports suggestions that the general homogeneity of basalt along the EPR is due to mixing in sub-axial magma chambers and mush zones, with additional mixing during partial mantle melting and melt segregation.  相似文献   
304.
Temporal variations in bedload transport rates that occur at a variety of timescales, even under steady flow conditions, are accepted as an inherent component of the bedload transport process. Rarely, however, has the cause of such variations been explained clearly. We consider three data sets, obtained from laboratory experiments, that refer to measurements of bedload transport made with continuously recording bedload traps. Each data set is characterized by a predominant low-frequency oscillation, on which additional higher-frequency oscillations generally are superimposed. The period of these oscillations, as isolated through the use of spectral analysts, ranged between 0·47 and 168 minutes, and was associated unequivocally with the migration of bedforms such as ripples, dunes, and bars. The extent to which such oscillatory behaviour may be recognized in a data set depends on the duration of sampling and the length of the sampling time, with respect to the period of a given bedform. Several theoretical probability distribution functions have been developed to describe the frequency distributions of (relative) bedload transport rates that are associated with the migration of bedforms (Einstein, 1937b; Hamamori, 1962; Carey and Hubbell, 1986). These distribution functions were derived without reference to a sampling interval. We present a modification of Hamamori's (1962) probability distribution function, generated by Monte Carlo simulation, which permits one to specify the sampling interval, in relation to the length of a bedform. Comparisons between the simulated and observed frequency distributions, that were undertaken on the basis of the data described herein, are good (significant at the 90 per cent confidence level). Finally, the implications that temporal variability, which is associated with the migration of bedforms, have for the accurate determination of bedload transport rates are considered.  相似文献   
305.
Remeasurements of weathering rates at six sites on the base of the balustrade of St. Paul's Cathedral gave substantially lower mean results (0.06 mm a?1, 1980–1985) than for earlier results (0.14 mm a?1, 1980–1981). Statistical analysis of the data showed that for five of the sites there were no significant differences between the measurement periods. The only significant spatial difference was for the southwest (exposed) site which was greater than the other sites for 1980–1981, but not at later times. This site also showed the only significant decrease over time. If this site is included in the statistical analysis, the whole set shows a significant decrease over time; omitting this site from the data removes any significant differences over time. The results for this one site for 1980–1981 thus have significant bias on the data body as a whole. Methodological problems, such as rock erosion by the probe and temperature effects, are thought to have minimal effect on the interpretation of the data. Calibrations showed that measurements were accurate to ±0.006 mm and that only results of a change ≥ 0.02 mm were reliably interpretable as different. Remeasurements of the Lead Plug Index (LPI) for the top of the balustrade in 1987 gave a mean rate for 1718–1985 of 0.081 mm a?1. This is not significantly different from the 1718–1980 mean rate of 0.078 mm a?1 but the data are not directly comparable, the 1987 sample being smaller than the 1980 set. For the 1987 data, the only statistically significant differences are for the southeast rate ≧ northeast and for a rise in rate in the northeast quadrant. The LPI data are comparable to most of the 1980–1985 MEM data. The conclusion is that most erosion rates have neither increased nor decreased significantly in the measurement time, except for a significant decrease at one (southwest) site from 1980–1981 to 1981–1982. Such a sustained level of erosion gives cause for concern in the context of stone conservation. Causative factors of air quality are discussed and while SO2 levels have decreased, NO2 and smoke levels show increases. An overall decrease in stone decay in association with the decrease in SO2 levels is thus not in evidence.  相似文献   
306.
The concept of planetary wave breaking (McIntyre andPalmer, 1983; 1984) is critically reviewed. It is concluded that the wave breaking signature is not unique to any particular dynamic event in the stratosphere. Therefore, the classification of stratospheric transport events, such as wave breaking, groups fundamentally different events together. Better qualification of the wave breaking signature and a more solid theoretical basis of planetary wave breaking must be presented if the concept is to be of significant utility in describing stratospheric tracer transport.  相似文献   
307.
Prior to the recent discovery of high-temperature vanadium sublimates at the fumaroles of Izalco volcano, El Salvador, the only vanadium minerals known were those formed at low-temperature surface conditions. Six new vanadium compounds have already been discovered at Izalco volcano, and five of these have been elevated to mineral status. Two of the minerals are among the most vanadium-rich compounds known in nature.Field studies and studies of the crystal chemistry of the sublimate phases have allowed delineation of the conditions of exsolution of vanadium-bearing gases from the magma and conditions of sublimation of the vanadium compounds. A vanadium halogen or oxyhalogen gas phase was exsolved from a basaltic magma when the magma was 550 m below the summit crater. As the gas rose to the fumaroles and mixed with the atmosphere, the oxygen fugacity rose from that of the magma to at least 10−3,5 bar. At the fumaroles, the vanadium compounds sublimated at various temperatures, but a minimum temperature of 760° can be determined for one of the phases based on geothermometry determined from phase relations in the system CuO-V2O5. The studies have demonstrated that a vanadium-bearing gas can segregate from a magma with normal basaltic concentrations of vanadium.  相似文献   
308.
Changes in the rate of soil erosion in lake catchments can be identified from changes in the rate of sediment accumulation in lakes. Here we compare recently afforested sites with non-afforested sites in the Galloway area of Southwest Scotland. We show that lakes with non-afforested catchments have slow, constant sediment accumulation rates, whereas lakes with recently afforested catchments have changes in accumulation that parallel the known history of afforestation. For Loch Grannoch the sediment accumulation rate increases from 0.1 cm yr?1 to over 2 cm yr?2 during the disturbance period. Data from L. Skerrow, however, suggest that the rate might decline to predisturbance levels after approximately 10 years as the forest canopy closes and drainage channels stabilize.  相似文献   
309.
The analytical data received in an inter-laboratory study of four Canadian reference samples were treated by two different methods in order to arrive at "usable values" for the concentration of each constituent. The first method ("Select Laboratories"), proposed by S. Abbey (S.A.), is based on the fact that some laboratories consistently produce better results than others. S.A. suggests an approach which permits isolation of results from such laboratories, calculation of a mean or a median of such results and use of one or the other as the concentration of a constituent. That approach involves a degree of subjectivity and S.A. attempts to demonstrate the validity of his approach by means of several tests applied to the results obtained for the four samples.  相似文献   
310.
Exposure of specimens of Mytilus edulis to dissolved copper leads to a fall in the filtration rate measured in whole animals. The copper concentration leading to a 50% reduction in the filtration rate was found to be 0.094 mg I−1. This effect was abolished on depletion of the monoamine content of the animal using reserpine. It is suggested that there may be a chemosensory mechanism present in the animals which responds to increased levels of metals in the seawater leading to a reduction in the rate of ciliary beating and mediated via the branchial nerve.  相似文献   
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