Waveform Shaping of Sonar Transducers for Improving the Vertical Resolution in Sub-bottom Sediments Profiling

Vertical resolution is of fundamental importance in sonar exploration and is directly related to the duration of the acoustic pulse generated by the transducer. The shorter the radiated pulse, the higher the vertical resolution. Many sub-bottom profiling sonar systems use piezoelectric transducers because they are reversible and well understood. Piezoelectric projectors are normally resonant transducers, which are intrinsically narrowband. A piezoelectric transducer is usually driven by a tone-burst. However, it is possible to use Fourier techniques to find a pre-compensated electrical driving function so that the transducer radiates a prescribed wider band acoustic waveform. This technique can be applied to synthesize zero-phase cosine-magnitude, Gaussian, and bionic pulses, with a conventional sandwich transducer. Zero-phase cosine-magnitude waveforms provide minimum length pulses (and therefore maximum resolution) within a prescribed frequency band.The aim of this paper is to illustrate the synthesis of wideband acoustic pulses using an underwater piezoelectric projector. The conventional acoustic waveform radiated when a Tonpiltz transducer is transiently excited using a “click” and allows its frequency response function to be measured. This function is used to design the electrical signal which then drives the transducer so that it radiates the shortest pulse compatible with its mechanical response. The significant resolution enhancement of the waveform shaping process is illustrated by its application to a sediment wedge model.     

Measuring and modelling temporal trends of 226Ra in waters of a Spanish estuary affected by the phosphate industry

The presence and temporal evolution (1990-2001) of (226)Ra in a tidal estuary affected by the phosphate industry has been investigated. Water samples collected in the course of four separate sampling campaigns were analysed for (226)Ra content using a gas flow proportional counter following Ba coprecipitation. Two (226)Ra sources have been identified: direct discharges from the industrial complex and run-off from a phosphogypsum pile. Although activity levels are similar, or even higher, than those found in other environments affected by the phosphate industry, there has been a general decrease in contamination since direct discharges ceased in 1998 due to new regulations from the EU. However, sediments are now acting as a source of Ra to the water column due to redissolution processes. A numerical model of the estuary has been developed to describe quantitatively the experimental results. The model solves the hydrodynamics and the dispersion equation of (226)Ra including interactions with sediments. Model results are, in general, in good agreement with observations.     

Patterns of heritability of decreased EROD activity and resistance to PCB 126-induced teratogenesis in laboratory-reared offspring of killifish (Fundulus heteroclitus) from a creosote-contaminated site in the Elizabeth River,VA, USA

Killifish (Fundulus heteroclitus) from a highly contaminated site on the Elizabeth River are resistant to the acute toxicity and the cytochrome P4501A (CYP1A)-inducing activity of both the sediments from the site and chemically pure polycyclic aromatic hydrocarbons (PAHs). These effects are highly heritable for one generation, but heritable to a lesser degree by subsequent generations, in clean conditions in the laboratory. We show that offspring of this population of Elizabeth River killifish are also resistant to the teratogenicity and P4501A-inducing activity of PCB congener 126, a prototypical coplanar halogenated aromatic hydrocarbon (HAH). Furthermore, the pattern of greater resistance to acute toxicity and P4501A-inducing activity in the first generation and less in subsequent generations is also observed upon exposure to PCB-126.     

An aromatase inhibitor and tamoxifen decrease plasma levels of o,p'-DDT and its metabolites in Nile tilapia (Oreochromis niloticus)

The objective of this study was to determine if tamoxifen or an aromatase inhibitor (4-hydroxyandrostenedione; 4-OHA) affected plasma concentrations of o,p' -DDT and its metabolites, o,p'-DDD and o,p'-DDE, in mature tilapia. Male and female tilapia were injected 6 times intraperitoneally with o,p'-DDT (40 mg/kg) alone or in combination with 4-OHA (2 mg/kg) over a 12 day period. An additional group of male fish was injected with tamoxifen (5 mg/kg) plus o,p'-DDT. At the end of the treatment period, plasma samples were extracted and analyzed by GC/ECD. Females injected only with o,p'-DDT had significantly higher levels of o,p'-DDT compared with males. Interestingly, females and males treated concomitantly with o,p'-DDT and 4-OHA or tamoxifen had significantly lower concentrations of plasma o,p'-DDT (about 50%) compared with fish treated with only o,p'-DDT. These initial results suggest that an interaction between endocrine-active compounds occurs in vivo in tilapia and may involve alterations in metabolism of o,p'-DDT.     

A genetic assessment of the taxonomic status of New Zealand mussels of the genus Xenostrobus Wilson, 1967

ABSTRACT

The genus Xenostrobus consists of small, marine and estuarine mussels that all appear similar externally. One of its estuarine species, Xenostrobus securis, with a native range in New Zealand and Australia, has become invasive in the Northern Hemisphere. No genetic data are available to determine if X. securis populations from the two countries are conspecific. Additionally, marine Xenostrobus from New Zealand have often been regarded as a species, X. neozelanicus, distinct fromthe marine Australian species X. pulex. We combined new DNA sequences with published data to assess the taxonomic status of New Zealand Xenostrobus. The data comprised 658 aligned bases of mitochondrial cytochrome c oxidase subunit I (COI) gene and 331 bases of nuclear histone H3. There was no evidence that X. securis populations from Australia and New Zealand are specifically distinct. Northern Hemisphere specimens of X. securis belonged to Australian, not New Zealand, clades in phylogenetic analyses of COI data, suggesting the former country as their more likely original source. The results confirm that X. neozelanicus and X. pulex are distinct species and for nomenclatural completeness for this taxonomic decision a lectotype is designated for Mytilus ater Zelebor in Dunker and Zelebor, 1866 DunkerW, ZeleborJ. 1866. Bericht über die von der Novara-expedition mitgebrachten Mollusken. Verhandlungen der Kaiserlich-Königlichen Zoologisch-Botanischen Gesellschaft in Wien. 16:909–916. [Google Scholar] [?=?Modiolus neozelanicus Iredale, 1915 IredaleT. 1915. A commentary on Suter’s ‘Manual of New Zealand Mollusca’. Transactions of the New Zealand Institute. 47:417–497. [Google Scholar]].     

A comparative mineralogical study of gas-related sediments of the Gulf of Cádiz

The Gulf of Cádiz area has been extensively surveyed in recent years and several gas-related fluid escape seafloor structures have been identified. In this study, gravity cores, collected during the ANASTASYA/00 and ANASTASYA/01 cruises, on mud volcanoes, hemipelagic sediments and dredged material from diapiric structures, have been studied. A comparative mineralogical analysis by XRD and SEM of samples from different areas has been performed in order to determine whether there is a characteristic mineralogy related to these fluid escape structures, and also to determine the origin of the mud matrix and constrain the depth of the parent units. The mineralogical analysis reflects the different origins of the different units described in the cores: hemipelagic material of the slope, clays that underlie the mud volcanoes and are discharged at the sea bottom surface, and authigenic and diagenetic minerals possibly involved in the anaerobic oxidation of methane in the mud volcano sediments.     

Estimating the underwater light field from remote sensing of ocean color

We present a new approach that incorporates two models to estimate the underwater light field from remote sensing of ocean color. The first employs a series of analytical, semi-analytical, and empirical algorithms to retrieve the spectrum of inherent optical properties (IOPs), including the absorption and the backscatter coefficients, from the spectrum of remote sensing reflectance. The second model computes the profile of photosynthetically available radiation E _0,PAR (z) for a vertically homogeneous water column using the information of the retrieved IOPs and the ambient optical environment. This computation is based on an improved look-up table technology that possesses high accuracy, comparable with the full solution of the radiative transfer equation, and meets the computational requirement of remote sensing application. This new approach was validated by in situ measurements and an extensive model-to-model comparison with a wide range of IOPs. We successfully mapped the compensation depth by applying this new approach to process the SeaWiFS imagery. This research suggests that E _0,PAR (z) can be obtained routinely from ocean-color data and may have significant implications for the estimation of global heat and carbon budget.     

Methane-dominated thermochemical sulphate reduction in the Triassic Feixianguan Formation East Sichuan Basin, China: towards prediction of fatal H2S concentrations

New sour pools have recently found in the Lower Triassic Feixianguan Fm carbonate reservoirs in the East Sichuan Basin in China with H₂S up to 17.4% by volume. A recent blowout from a well drilled into this formation killed hundreds of people as a result of the percentage concentrations of H₂S. In order to assess the origin of fatal H₂S as well as the cause of petroleum alteration, H₂S concentrations and the isotopes, δ³⁴S and δ¹³C have been collected and measured in gas samples from reservoirs. Anhydrite, pyrite and elemental sulphur δ³⁴S values have been measured for comparison. The high concentrations of H₂S gas are found to occur at depths >3000 m (temperature now at 100 °C) in evaporated platform facies oolitic dolomite or limestone that contains anhydrite nodule occurrence within the reservoirs. Where H₂S concentrations are greater than 10% its δ³⁴S values lie between +12.0 and +13.2‰ CDT. This is within the range of anhydrite δ³⁴S values found within the Feixianguan Fm (+11.0 to +21.7‰; average 15.5±3.5‰ CDT). Thus H₂S must have been generated by thermochemical sulphate reduction (TSR) locally within the reservoirs. Burial history analysis and fluid inclusion data reveal that the temperature at which TSR occurred was greater than about 130–140 °C, suggesting that the present depth-temperature minimum is an artifact of post-TSR uplift. Both methane and ethane were actively involved in TSR since the petroleum became almost totally dry (no alkanes except methane) and methane δ¹³C values become significantly heavier as TSR proceeded. Methane δ¹³C difference thus reflects the extent of TSR. While it is tempting to use a present-day depth control (>3000 m) to predict the distribution of H₂S in the Feixianguan Fm, this is an invalid approach since TSR occurred when the formation was buried some 1000–2000 m deeper than it is at present. The likelihood of differential uplift across the basin means that it is important to develop a basinal understanding of the thermal history of the Feixianguan Fm so that it is possible to determine which parts of the basin have been hotter than 130–140 °C.     

Physical and biological factors influencing the spatial distribution of age-0 walleye pollock (Theragra chalcogramma) around the Pribilof Islands, Bering Sea

The waters around the Pribilof Islands, in the southeast Bering Sea, are a main nursery area for age-0 pollock. Each summer, the islands are surrounded by a well-mixed inshore region, separated from a stratified offshore region by a frontal zone. To study the spatial distribution of age-0 pollock around this frontal structure in relation to physical and biological factors that are likely to influence it, such as advection, age-0 pollock feeding, and predation, samples were collected during September of four consecutive years, 1994–97, along two transects. Samples collected included water column hydrography and currents, acoustic backscatter, and groundfish predator density.Our analysis suggested that different mechanisms may be involved in controlling age-0 pollock distribution north and south of the islands. On the shelf area north of the islands, high age-0 pollock density was significantly associated with areas of high potential for growth only in years or portions of the frontal transect in which predator numbers were relatively low, indicating the importance of predation in controlling fish distribution in this area. In contrast, south of the islands, age-0 pollock distribution was associated more with prey availability, which appeared to be determined by vertical spatial overlap between predators and prey. Moreover, south of the islands, the stronger geostrophic currents, typical of the slope region, were more likely to affect the overall standing biomass of juvenile pollock, by constantly advecting fish away from the area.