Keck observations of near-Earth asteroids in the thermal infrared

We present the results of thermal-infrared observations of 20 near-Earth asteroids (NEAs) obtained in the period March 2000-February 2002 with the 10-m Keck-I telescope on Mauna Kea, Hawaii. The measured fluxes have been fitted with thermal-model emission continua to determine sizes and albedos. This work increases the number of NEAs having measured albedos by 35%. The spread of albedos derived is very large (p_v=0.02−0.55); the mean value is 0.25, which is much higher than that of observed main-belt asteroids. In most cases the albedos are in the ranges expected for the spectral types, although some exceptions are evident. Our results are consistent with a trend of increasing albedo with decreasing size for S-type asteroids with diameters below 20 km. A number of objects are found to have unexpectedly low apparent color temperatures, which may reflect unusual thermal properties. However, the results from our limited sample suggest that high thermal-inertia, regolith-free objects may be uncommon, even amongst NEAs with diameters of less than 1 km. We discuss the significance of our results in the light of information on these NEAs taken from the literature and the uncertainties inherent in applying thermal models to near-Earth asteroids.     

Calibration of regional pollen data to construct maps of former forest types in southern Sweden

A method was developed to construct maps of former forest types based on regional pollen data in southern Sweden. The considered species were Alnus, Betula, Carpinus, Corylus, Fagus, Fraxinus, Juniperus, Picea, Pinus, Populus, Quercus, Salix, Tilia and Ulmus. A network of 37 regional pollen sites with high data quality from lakes and peat deposits were selected from Sweden south of 60 ° N. Pollen percentage values were calculated and converted into estimates of tree composition. For controlling the reliability of the reconstruction, the estimates from the core-tops were compared with present day forest inventory data, and local pollen diagrams were compared with the regional pollen diagrams. An inverse distance weighted interpolation algorithm was used to generate maps for each tree species distribution at 2000 BP, 1500 BP, 1000 BP, 500 BP and 0 BP. A supervised classification routine was implemented to generate nine different forest types common to the five studied time intervals. The maps show that the amounts and patterns of distribution of the species and the forest types have varied in a significant but systematic manner through time. The changes are due to human activities, migrational patterns and changes in climate. These maps will be of value as a basis for future landscape planning, forestry and conservation of biodiversity.This is the 20th in a series of papers published in this special AMQUA issue. These papers were presented at the 1994 meeting of the American Quaternary Association held 19–22 June, 1994, at the University of Minnesota, Minneapolis, Minnesota, USA. Dr Linda C. K. Shane served as guest editor for these papers.     

Simulation of moist mountain waves with an anelastic model

Abstract

A two-dimensional, nonlinear, time-dependent, non-hydrostatic, anelastic, numerical model is used to assess the effect of condensation on the evolution and structure of gravity waves generated by the passage of a stable, moist stream over topography. Precipation is ignored but water phase changes are taken into account explicitly.

The main effect of condensation is to damp the wave intensity and to reduce the wave drag, which can be diminished by as much as 50% compared to its value in dry simulations. This result agrees with some earlier analytical models and some more recent fully compressible numerical models.

This model also confirms that the presence of condensation delays the overturning of isentropes, and the formation of the critical layer that accompanies wave-breaking.     

Natural Gradient Tracer Test to Evaluate Natural Attenuation of MTBE Under Anaerobic Conditions

A natural gradient tracer test using perdeuterated MTBE was conducted in an anaerobic aquifer to determine the relative importance of dispersion and degradation in reducing MTBE concentrations in ground water. Preliminary ground water chemistry and hydraulic conductivity data were used to place the tracer within an existing dissolved MTBE plume at Port Hueneme, California. Following one year of transport, the tracer plume was characterized in detail.
Longitudinal dispersion was identified as the dominant mechanism for lowering the perdeuterated MTBE concentrations. The method of moments was used to determine the longitudinal and lateral dispersion coefficients (0.85 m²/day and 0.08 m²/day, respectively). A mass-balance analysis, carried out after one year of transport, accounted for 110% of the injected mass and indicated that no significant mass loss occurred. The plume structure created by zones of higher and lower hydraulic conductivity at the site was complex, consisting of several localized areas of high tracer concentration in a lower concentration plume. This is important because the aquifer has generally been characterized as exhibiting fairly minor heterogeneity. In addition, the tracer plume followed a curved flowpath that deviated from the more macroscopic direction of ground water flow inferred from local ground water elevation measurements and the behavior of the existing plume. Understanding the mass balance, plume structure, curvature of the tracer plume, and consequently natural attenuation behavior required the detailed sampling approach employed in this study. These data imply that a detailed understanding of site hydrogeology and an extensive sampling network may be critical for the correct interpretation of monitored natural attenuation of MTBE.     

Thermodynamics of feldspathoid solutions

We have developed models for the thermody-namic properties of nephelines, kalsilites, and leucites in the simple system NaAlSiO₄?KAlSiO₄?Ca_0.5AlSiO₄?SiO₂?H₂O that are consistent with all known constraints on subsolidus equilibria and thermodynamic properties, and have integrated them into the existing MELTS software package. The model for nepheline is formulated for the simplifying assumptions that (1) a molecular mixing-type approximation describes changes in the configurational entropy associated with the coupled exchange substitutions □Si?NaAl and □Ca? Na₂ and that (2) Na⁺ and K⁺ display long–range non-convergent ordering between a large cation and the three small cation sites in the Na₄Al₄Si₄O₁₆ formula unit. Notable features of the model include the prediction that the mineral tetrakalsilite (“panunzite”, sensu stricto) results from anti-ordering of Na and K between the large cation and the three small cation sites in the nepheline structure at high temperatures, an average dT/dP slope of about 55^°/kbar for the reaction over the temperature and pressure ranges 800–1050 ^°C and 500–5000 bars, roughly symmetric (i.e. quadratic) solution behavior of the K–Na substitution along joins between fully ordered components in nepheline, and large positive Gibbs energies for the nepheline reciprocal reactions and and for the leucite reciprocal reaction      

Comparing gravity and gravity gradient surveys

Noise levels in marine and airborne full tensor gravity gradiometer surveys together with conventional land, marine and airborne gravity surveys are estimated and analysed in gridded form, resulting in relations that detail how these different survey systems can be compared analytically. After defining survey parameters including line spacing, speed and instrument bandwidth, the relations estimate the noise levels that result on either grids of gravity (gz) or gravity gradient (Gzz) as a function of the spatial filtering often applied during geological interpretation. Such comparisons are believed to be a useful preliminary guide for survey selection and planning.     

Persistent organic pollutants and stable isotopes in biopsy samples (2004/2006) from Southern Resident killer whales

“Southern Resident” killer whales include three “pods” (J, K and L) that reside primarily in Puget Sound/Georgia Basin during the spring, summer and fall. This population was listed as “endangered” in the US and Canada following a 20% decline between 1996 and 2001. The current study, using blubber/epidermis biopsy samples, contributes contemporary information about potential factors (i.e., levels of pollutants or changes in diet) that could adversely affect Southern Residents. Carbon and nitrogen stable isotopes indicated J- and L-pod consumed prey from similar trophic levels in 2004/2006 and also showed no evidence for a large shift in the trophic level of prey consumed by L-pod between 1996 and 2004/2006. ∑PCBs decreased for Southern Residents biopsied in 2004/2006 compared to 1993–1995. Surprisingly, however, a three-year-old male whale (J39) had the highest concentrations of ∑PBDEs, ∑HCHs and HCB. POP ratio differences between J- and L-pod suggested that they occupy different ranges in winter.     

Petrology and geochemistry of feldspathic impact‐melt breccia Abar al' Uj 012, the first lunar meteorite from Saudi Arabia

Abar al' Uj (AaU) 012 is a clast‐rich, vesicular impact‐melt (IM) breccia, composed of lithic and mineral clasts set in a very fine‐grained and well‐crystallized matrix. It is a typical feldspathic lunar meteorite, most likely originating from the lunar farside. Bulk composition (31.0 wt% Al₂O₃, 3.85 wt% FeO) is close to the mean of feldspathic lunar meteorites and Apollo FAN‐suite rocks. The low concentration of incompatible trace elements (0.39 ppm Th, 0.13 ppm U) reflects the absence of a significant KREEP component. Plagioclase is highly anorthitic with a mean of An_96.9Ab_3.0Or_0.1. Bulk rock Mg# is 63 and molar FeO/MnO is 76. The terrestrial age of the meteorite is 33.4 ± 5.2 kyr. AaU 012 contains a ~1.4 × 1.5 mm² exotic clast different from the lithic clast population which is dominated by clasts of anorthosite breccias. Bulk composition and presence of relatively large vesicles indicate that the clast was most probably formed by an impact into a precursor having nonmare igneous origin most likely related to the rare alkali‐suite rocks. The IM clast is mainly composed of clinopyroxenes, contains a significant amount of cristobalite (9.0 vol%), and has a microcrystalline mesostasis. Although the clast shows similarities in texture and modal mineral abundances with some Apollo pigeonite basalts, it has lower FeO and higher SiO₂ than any mare basalt. It also has higher FeO and lower Al₂O₃ than rocks from the FAN‐ or Mg‐suite. Its lower Mg# (59) compared to Mg‐suite rocks also excludes a relationship with these types of lunar material.     

TiO2 exsolution from garnet by open-system precipitation: evidence from crystallographic and shape preferred orientation of rutile inclusions

We investigated rutile needles with a clear shape preferred orientation in garnet from (ultra) high-pressure metapelites from the Kimi Complex of the Greek Rhodope by electron microprobe, electron backscatter diffraction and TEM techniques. A definite though complex crystallographic orientation relationship between the garnet host and rutile was identified in that Rt[001] is either parallel to Grt<111> or describes cones with opening angle 27.6° around Grt<111>. Each Rt[001] small circle representing a cone on the pole figure displays six maxima in the density plots. This evidence together with microchemical observations in TEM, when compared to various possible mechanisms of formation, corroborates a precipitate origin. A review of exchange vectors for Ti substitution in garnet indicates that rutile formation from garnet cannot occur in a closed system. It requires that components are exchanged between the garnet interior and the rock matrix by solid-state diffusion, a process we refer to as “open-system precipitation” (OSP). The kinetically most feasible reaction of this type will dominate the overall process. The perhaps most efficient reaction involves internal oxidation of Fe²⁺ to Fe³⁺ and transfer from the dodecahedral to the octahedral site just vacated by $ {\text{Ti}}^{ 4+ }: 6\,{\text{M}}^{ 2+ }_{ 3} {\text{TiAl}}\left[ {{\text{AlSi}}_{ 2} } \right]{\text{O}}_{ 1 2} + 6\,{\text{M}}^{ 2+ }_{ 2, 5} {\text{TiAlSi}}_{ 3} {\text{O}}_{ 1 2} = 10\,{\text{M}}^{ 2+ }_{ 3.0} {\text{Al}}_{ 1. 8} {\text{Fe}}_{0. 2} {\text{Si}}_{ 3} {\text{O}}_{ 1 2} + {\text{M}}^{2+} + 2 {\text{e}}^{-} + 1 2\,{\text{TiO}}_{ 2} . $ OSP is likely to occur at conditions where the transition of natural systems to open-system behaviour becomes apparent, as in the granulite and high-temperature eclogite facies.     

Baroclinic oscillations of tidal frequency at ocean weather station P

Abstract

We analyse time series records of isopleth depths derived from two extended sequences of hourly and bi‐hourly sampled profiles taken at Ocean Weather Station P during the summers of 1961 and 1969. Vertical displacements to 240‐m depth are mainly of semidiurnal frequency with r.m.s. amplitudes of 1–4 m. Displacements at diurnal and near‐inertial frequencies are typically less than a metre and have little statistical significance. Within the semidiurnal band, motions appear to be predominantly at the principal solar (S₂) rather than the principal lunar (M₂) semidiurnal frequency. The phase of the M₂ baroclinic tide is roughly equal to that of the M₂ barotropic tide (as extrapolated from coastal and seamount observations); phases of other constituents differ appreciably from barotropic values.