Simulating methane emission from a Chinese rice field as influenced by fertilizer and water level

Natural and agricultural wetlands are considered to be the major sources of global atmospheric methane (CH₄). A one‐dimensional model was developed to simulate methane emission and used to examine the influence of various physical processes on the rate of methane emission. Three processes involved in the methane emission are implemented in the model: production, reoxidation and transport. Three transport pathways were considered: diffusion across water–air or soil–air interfaces, ebullition and diffusion through plants. These pathways are influenced by soil properties, plant growth, water‐table conditions, temperature and external inputs (e.g. fertilizer). The model was used to examine the seasonal variation of the methane emission at a rice field in Hunan, China, which was observed during a field experiment for consecutive (early and late) rice seasons in 1992. The observed seasonal variations of methane emission, and role of plants in transporting methane to the atmosphere, are captured by the model simulation. Further model applications were conducted to simulate effects of fertilizer and water‐level condition on the methane emission. The results indicate that unfermented organic fertilizer produces a higher methane emission rate than mineral fertilizer. The simulations with treatments of a deep‐water covering and constant moisture reduced the methane emission. The rice field study provides a framework for further development of the model towards simulations based on spatially distributed variables (e.g. water table, soil temperature and vegetation) at a regional scale. Copyright © 2003 John Wiley & Sons, Ltd.     

Tensile stresses around boreholes due to transient fluid flow

We present solutions for the effective stress induced by gas flow through a porous solid into a borehole resulting from sudden pressure reduction. Tensile effective stress that exceeds the strength of the solid will lead to borehole failure. This has applications to the intentional creation of cavities, relevant to the efficient recovery of coalbed methane, and the avoidance of borehole stability problems in conventional gas production.     

Speciation of trace metals in sediments of a tropical estuary

Axial surveys were performed in the two river tributaries of the Cochin estuary, SW India during November 1988. Surficial sediments were subjected to sequential chemical extractions to delineate five metal fractions, namely, exchangeable, carbonate bound, easily reducible, organic/sulfide bound, and residual. The results indicated selective accumulation of Mn and Ni in carbonate bound and organic/sulfide forms, along with marginal amounts of Co in the exchangeable fraction. Large portions of Fe and Cr occurred in the residual fraction, whereas composite fractionation of Zn species was noticed. The exchangeable fractions of Fe and Cr as well as of easily reducible cobalt were below detection limits. The levels of Cr and Zn indicate anthropogenic inputs in this estuary, whereas Co and Ni show regional contamination exceeding natural levels. The analytical speciation procedure helps to deduce the sedimental diagenetic processes in the estuarine environment.     

Estimation of the sub-iron-iron flux ratio in cosmic rays over alice springs using a balloon flight experiment with a CR-39 detector

The sub-iron-iron flux ratio in cosmic rays at an atmospheric depth of 9.8 g cm^–2 has been estimated using a balloon-borne CR-39 (HCB) stack launched from Alice Springs for 32 hours. The recovered and chemically etched plates were analysed optically and the measured etch pit diameters yielded the sub-iron-iron flux ratio at the flight altitude. The sub-iron-iron flux ratio has been corrected for the top of the atmosphere by considering the loss of heavy ions due to nuclear interaction and fragmentation. The present result has been compared with the result expected from the source composition derived by Protheroeet al. as well as other authors.     

Late Oligocene-Miocene syn-/-late-orogenic successions in Western and Central Mediterranean Chains from the Betic Cordillera to the Southern Apennines*

The identification of syn- and late-orogenic flysch deposits, extending from the Betic Cordillera to the Southern Apennines, assists in the reconstruction of the tectonic-sedimentary evolution of the perimediterranean chains. A microplate was located between the European and African Plates during the Late Jurassic–Early Cretaceous, bordered northwards by the Piemontese Ocean and southwards by another (North Africa ‘Flysch’ Basin or Maghrebian) Ocean. The Piemontese Ocean and the northern margin of the microplate were structured from the Late Cretaceous to the Eocene to create an Eo-alpine Chain. The southern margin of the microplate was deformed in the Aquitanian, when the internal areas of the Maghrebian Ocean were characterized by syn-orogenic flysch deposits. This episode culminated with metamorphism (25–22 Ma) and nappe emplacement, which destroyed the former palaeogeography and created an orogenic belt (AlKaPeCa). Afterwards, a lower Burdigalian late-orogenic cycle started in the deformed area, which as a result of the opening of the Algero-Provençal Basin, caused the fragmentation of the AlKaPeCa, its thrusting on the ‘Flysch’ Basin and the collision with the North Africa and South Iberia Margins. These latter were folded and thrusted, the ‘Flysch’ Units pushed over the External Domain and also back-thrusted. Langhian late-orogenic deposits suture the new tectonic features. Finally, the whole orogen was thrust onto the foredeep during the Middle–Late Miocene.     

40Ar/39Ar and oxygen isotope studies of polymetamorphism from Tinos Island, Cycladic blueschist belt, Greece

Abstract Petrological, oxygen isotope and ⁴⁰Ar/³⁹Ar studies were used to constrain the Tertiary metamorphic evolution of the lower tectonic unit of the Cyclades on Tinos. Polyphase high-pressure metamorphism reached pressures in excess of 15 kbar, based on measurements of the Si content in potassic white mica. Temperatures of 450–500° C at the thermal peak of high-pressure metamorphism were estimated from critical metamorphic assemblages, the validity of which is confirmed by a quartz–magnetite oxygen isotope temperature of 470° C. Some ⁴⁰Ar/³⁹Ar spectra of white mica give plateau ages of 44–40 Ma that are considered to represent dynamic recrystallization under peak or slightly post-peak high-pressure metamorphic conditions. Early stages in the prograde high-pressure evolution may be documented by older apparent ages in the high-temperature steps of some spectra. Eclogite to epidote blueschist facies mineralogies were partially or totally replaced by retrograde greenschist facies assemblages during exhumation. Oxygen isotope thermometry of four quartz–magnetite pairs from greenschist samples gives temperatures of 440–470° C which cannot be distinguished from those deduced for the high-pressure event. The exhumation and overprint is documented by decreasing ages of 32–28 Ma in some greenschists and late-stage blueschist rocks, and ages of 30–20 Ma in the lower temperature steps of the Ar release patterns of blueschist micas. Almost flat parts of Ar–Ar release spectra of some greenschist micas gave ages of 23–21 Ma which are assumed to represent incomplete resetting caused by a renewed prograde phase of greenschist metamorphism. Oxygen isotope compositions of blueschist and greenschist facies minerals show no evidence for the infiltration of a δ¹⁸O-enriched fluid. Rather, the compositions indicate that fluid to rock ratios were very low, the isotopic compositions being primarily controlled by those of the protolith rocks. We assume that the fundamental control catalysing the transformation of blueschists into greenschists and the associated resetting of their isotopic systems was the selective infiltration of metamorphic fluid. A quartz–magnetite sample from a contact metamorphic skarn, taken near the Miocene monzogranite of Tinos, gave an oxygen isotope temperature of 555° C and calculated water composition of 9.1%. The value of δ¹⁸O obtained from this water is consistent with a primary magmatic fluid, but is lower than that of fluids associated with the greenschist overprint, which indicates that the latter event cannot be directly related to the monozogranite intrusion.