Proposed Adsorption–Diffusion Model for Characterizing Chromium(VI) Removal Using Dried Water Hyacinth Roots

Experiments have been carried out to characterize the adsorption of chromium(VI) in the aqueous phase onto dried roots of water hyacinth. Results revealed a very high degree of removal efficiency (∼100%). Theoretical analyzes are also made for describing the sorption and diffusion processes. The effective pore diffusivity of chromium(VI) in the water hyacinth roots is determined by a suitable global optimization technique. The depth of penetration, on the other hand, has been estimated for various initial concentrations of chromium(VI). Theoretically predicted concentration profiles are in excellent agreement with the experimental values.     

Rock-water interaction and evolution of sulphide ores in the late Archaean Chitradurga greenstone belt of southern India

Sulphide ore mineralization developed in proximity to iron formations in a cyclic volcano-sedimentary sequence that forms the offshore part of the late Archaean intracratonic basin of the Chitradurga greenstone belt, south India. The chemistry of volcanic suite attests to an extensive rock-water interaction resulting in exchange of Si and Na for divalent cations, including Cu, Pb and Zn. The exchange took place during hydrothermal alteration of basalt prior to its involvement in regional deformation and metamorphism. A hydrothermal convection system extracted Cu, Zn and Pb from sea-floor basalts during a static phase of evolution of the Chitradurga basin and developed the stratabound ore deposit within the pyroclastics and the stringer ores below.     

GSC 45401533: Observations and Analysis of a NewlyDiscovered Binary Star

R observations of a newly discovered binary GSC 4540_1533 are presented. Analysis of the light curve with the Wilson-Devinney program indicates that the system is detached and consist of 2 main sequence stars. This revised version was published online in July 2006 with corrections to the Cover Date.     

A Bianchi type I tilted universe

The Bianchi type I cosmological models have been extensively studied in the past especially as examples of the homogeneous shearing universe. This paper presents a tilted universe solution admitting this group of motion where the velocity field is shear-free but there is an energy flux term.     

Stable isotope dynamics of groundwater interactions with Ganges river

Groundwater depletion has been an emerging crisis in recent years, especially in highly urbanized areas as a result of unregulated exploitation, thus leaving behind an insufficient volume of usable freshwater. Presently Ganges river basin, the sixth largest prolific fluvial system and sustaining a huge population in South Asia, is witnessed to face (i) aquifer vulnerability through surface waterborne pollutant and (ii) groundwater stress due to summer drying of river as a result of indiscriminate groundwater abstraction. The present study focuses on a detailed sub-hourly to seasonally varying interaction study and flux quantification between river Ganges and groundwater in the Indian subcontinent which is one of the first documentations done on a drying perennial river system that feeds an enormous population. Contributing parameters to the total discharge of a river at its middle course on both temporal and spatial scale is estimated through three-component hydrograph separation and end-member mixing analysis using high-resolution water isotope (δ¹⁸O and δ²H) and electrical conductivity data. Results from this model report groundwater discharge in river to be the highest in pre-monsoon, that is, 30%, whereas, during post-monsoon the contribution lowers to 25%; on the contrary, during peak monsoon, the flow direction reverses thus recharging the groundwater which is also justified using annual piezometric hydrographs of both river water and groundwater. River water-groundwater interaction also shows quantitative variability depending on river morphometry. The current study also provides insight on aquifer vulnerability as a result of pollutant mixing through interaction and plausible attempts towards groundwater management. The present study is one of the first in South Asian countries that provides temporally and spatially variable detailed quantification of baseflow and estimates contributing parameters to the river for a drying mega fluvial system.     

Characterizing atmospheric surface layer turbulence using chaotic return map analysis

Nonlinear time series analysis methods are used to investigate the dynamics of mechanical and convective turbulences in the atmospheric surface layer flow. Using dynamical invariant analysis (e.g. correlation dimension, Lyapunov exponent and mutual information) along with recurrence quantification analysis (e.g. recurrent rate, determinism, average diagonal length of recurrence plot, etc.) of the vertical wind component data, it is confirmed that a convective turbulence is a lower order manifold in its phase space exhibiting higher degree of organization than a mechanical turbulence. Applying a quasi-one-dimensional chaotic return map technique, the topological differences between the mechanical and convective turbulences are explored. These quasi-one-dimensional return maps are produced using the local maxima of the first principal component of the reconstructed turbulence data. A comparison of the probability distribution of the local maxima of a forced Lorenz model with the turbulence data indicates the possible existence of a stable fixed point for both type of turbulences. Furthermore, dynamically the mechanical turbulence is found to resemble an unforced Lorenz model whereas the convective turbulence resembles a forced Lorenz model.     

The origin of chloritoid – 3‐mica pseudomorph growth in staurolite–muscovite schist,Bangriposi (Eastern India)

At Bangriposi, variable stages in replacement of staurolite by chloritoid – Na–K–Ca mica shimmer aggregates in muscovite schists provides insight into the complex interplay between fluid flow, mass transfer, and dissolution–precipitation during pseudomorph growth. Idioblastic chloritoid growing into mica caps without causing visible deformation, and monomineralic chloritoid veins (up to 300 μm wide) within shimmer aggregates replacing staurolite attest to chloritoid nucleation in fluid‐filled conduits along staurolite grain boundaries and crystallographic planes. The growth of shimmer aggregates initiated along staurolite margins, and advanced inwards into decomposing staurolite along networks of crystallographically controlled fluid‐filled conduits. Coalescence among alteration zones adjacent to channel fills led to dismemberment and the eventual demise of staurolite. Mass balance calculation within a volume‐fixed, silica‐conserved reference frame indicate the shimmer aggregates grew via precipitation from fluids in response to mass transport that led to the addition of H₂O, K₂O, Na₂O and CaO in the reaction zone, and Al₂O₃ was transported outward from the inward‐retreating margin of decomposing staurolite. This aided precipitation of chloritoid in veins and in the outer collars, and as disseminated grains in the shimmer aggregates at mid‐crustal condition (~520 ± 20 °C, 5.5 ± 2.0 kbar). Computation using one‐dimensional transport equation suggests that staurolite decomposition involved advection dominating over diffusive transport; the permeation of externally derived H₂O caused flattening of chemical potential gradients in H₂O and aqueous species, for example, and , computed using the Gibbs method. This suggests that staurolite decomposition was promoted by the infiltration of a large volume of H₂O that flattened existing chemical potential gradients. In the initial stages of replacement, chloritoid super‐saturation in fluid caused preferential nucleation and growth of chloritoid at staurolite grain boundaries and in crystallographic planes. As reaction progressed, further chloritoid nucleation was halted, but chloritoid continued to grow as the 3‐mica aggregates continued to replace the remaining staurolite in situ, while the chloritoid‐compatible elements were transported in the water‐rich phase facilitating continued growth of the existing chloritoid grains.     

Petrology of the rajmahal traps of the Northwestern Rajmahal Hills,Bihar, India

Nine basaltic lava-flows, which vary in thickness between 60 feet and 300 feet, were established in the NW Rajmahals. The flows were, at places, laid down one above the other and, at others, were found to contain intervening intertrappean horizons. All the flows are essentially of basaltic composition and are made up of labradoritie plagioclase, pigeonitic and augitic pyroxene, opaque ore, primary glass and secondary minerals (palagonite, secondary silica, calcite and zeolite). The phenocrystic plagioclase ranges in composition between An₇₂ and An₆₂, while the constituents of the groundmass range between An₅₀ and An₁₇. The microphenocrysts of pyroxene are mainly augitic and occasionally pigeonitic while the constituents of the groundmass are essentially pigeonitic. The opaque minerals are magnetite and ilmenite. Petrographically, the lava-flows are more or less similar to one another. The first three flows are, however, more remarkably porphyritic and a little coarser in grain size than the six overlying flows. The eighth flow is devoid of palagonite. Calcite occurs only in certain portions of the second flow. There is a gradual increase in the percentage of primary glass from the first to the ninth flow with a corresponding fall in the total percentage of plagioclase and pyroxene. Statistical analysis of the grain size variation in the plagioclases was carried out and the results were found to be directly related to the prevailing rates of cooling in the different flows and also in the different horizons of the same flow. Modal analysis of the nine flows (in all, 98 samples) was carried out and this brought out some interesting results. Samples from three of the flows were analysed chemically and the corresponding norms were calculated. The order of crystallisation of the primary constituents was established from petrographic and petrological studies. The basaltic magma, which gave rise to the lava-flows of this region, does not appear to have undergone any significant differentiation during the course of its cooling and consolidation. The only discernible effect of crystallisati on differentiation was an enrichment of silica (and, perhaps, alkalis) in the residual liquids and no noteworthy enrichment of iron appears to have occurred at any stage.     

Higher Himalayan Shear Zone, Zanskar Indian Himalaya: microstructural studies and extrusion mechanism by a combination of simple shear and channel flow

Thin-section studies of the Zanskar Shear Zone (ZSZ) rocks reveal a top-to-SW and subsequent primary and secondary top-to-NE ductile shearing; brittle–ductile and brittle extensions; top-to-SW brittle shear, steep normal faulting and fracturing. In the proposed two-phase model of ductile extrusion of the Higher Himalayan Shear Zone (HHSZ), a top-to-SW simple shearing during 22–18 Ma was followed by a combination of top-to-SW simple shear and channel flow at 18–16 Ma. The second phase simulates a thin ZSZ characterized by a top-to-NE shearing. The channel flow component ceased around 16 Ma, the extruding HHSZ entered the brittle regime but the top-to-SW shearing continued until perturbed by faults and fractures. Variation in the extrusion parameters led to variable thickness of the ZSZ. Shear strain after the extrusion is presumably maximum at the boundaries of the HHSZ and falls towards the base of the ZSZ, which crudely matches with the existing data. The other predictions: (1) spatially uniform shear strain after the first stage, (2) fastest extrusion rate at the base of the ZSZ, and (3) a lack of continuation of the ZSZ along the Himalayan trend are not possible to validate due to paucity of suitable data. Non-parabolic shear fabrics of the ZSZ indicate their heterogeneous deformation.