Application of singular value decomposition (SVD) and semi-discrete decomposition (SDD) techniques in clustering of geochemical data: an environmental study in central Iran

Common multivariate clustering techniques are ineffective in identifying subtle patterns of correlation, and clustering of variables or samples within complex geochemical datasets. This study compares the combination of singular value decomposition (SVD) and semi discrete decomposition (SDD), with that of hierarchical cluster analysis (HCA), to examine patterns within a multielement soil geochemical dataset from an agricultural area in the vicinity of Pb–Zn mining operations in central Iran. SVD was used to both identify patterns of correlation between variables and samples and to “denoise” the data, and SDD to simultaneously cluster the samples and variables. The results reveal various spatial associations of mining waste-associated metals As, Ba, Pb and Zn, and within the remaining elements whose distribution is largely controlled by the major oxides. SVD–SDD was found to be superior to HCA, in its ability to detect subtle clusters in soil geochemistry indicative of mine-related contamination in the study area.     

Surface nuclear magnetic resonance signals recovery by integration of a non‐linear decomposition method with statistical analysis

Presence of noise in the acquisition of surface nuclear magnetic resonance data is inevitable. There are various types of noise, including Gaussian noise, spiky events, and harmonic noise that affect the signal quality of surface nuclear magnetic resonance measurements. In this paper, we describe an application of a two‐step noise suppression approach based on a non‐linear adaptive decomposition technique called complete ensemble empirical mode decomposition in conjunction with a statistical optimization process for enhancing the signal‐to‐noise ratio of the surface nuclear magnetic resonance signal. The filtering procedure starts with applying the complete ensemble empirical mode decomposition method to decompose the noisy surface nuclear magnetic resonance signal into a finite number of intrinsic mode functions. Afterwards, a threshold region based on de‐trended fluctuation analysis is defined to identify the noisy intrinsic mode functions, and then the no‐noise intrinsic mode functions are used to recover the partially de‐noised signal. In the second stage, we applied a statistical method based on the variance criterion to the signal obtained from the initial phase to mitigate the remaining noise. To demonstrate the functionality of the proposed strategy, the method was evaluated on an added‐noise synthetic surface nuclear magnetic resonance signal and on field data. The results show that the proposed procedure allows us to improve the signal‐to‐noise ratio significantly and, consequently, extract the signal parameters (i.e., and V₀) from noisy surface nuclear magnetic resonance data efficiently.     

Study of near bed stochastic turbulence and sediment entrainment over the ripples at the bed of open channel using image processing technique

In this study, the coherent structure in near bed bursting events over the ripples and mechanism of sediment bed load transport were investigated experimentally. The experiments in this study were carried out in the laboratory flume, in two parts; fixed bed ripple and mobile bed ripple. Tow artificial ripples, were built and used for making both fixed and mobile bed. For the fixed bed part, velocity fluctuations were measured using an Acoustic Doppler Velocimeter. In order to apply bursting analysis for obtained data, a computer program was written in visual basic language. Then, variation of turbulence shear stress associated with different bed form geometries was determined and mechanism of sediment transport by ripple shape at the bed of open channel was investigated. For the mobile bed part, artificial ripples were used as mould to make ripples. An image processing technique was used to record amount of sediment particles which are entrained and deposited over the same selected points at the fixed bed part. Results of mobile bed part, confirmed the results of shear stress analysis of fixed bed part.     

The solar lithium abundance

A detailed observational study of the solar photospheric lithium feature has been carried out with emphasis on center-limb observations, continuum location, possible effects of telluric lines, effects of blending by atomic and molecular lines, and decomposition of the solar spectrum around λ6707 Å.     

Strike-slip faulting, rotation, and along-strike elongation in the Kopeh Dagh mountains, NE Iran

The Kopeh Dagh is a linear mountain range separating the shortening in Iran from the stable, flat Turkmenistan platform. In its central part is an array of active right-lateral strike-slip faults that obliquely cut the range and produce offsets of several kilometres in the geomorphology and geological structure. They are responsible for major destructive earthquakes in the 19th and 20th centuries and represent an important seismic hazard for this now-populous region of NE Iran. These strike-slip faults all end in thrusts, revealed by the uplift and incision of Late Quaternary river terraces, and do not continue beyond the Atrak river valley, which forms the southern margin of the Kopeh Dagh. The cumulative offset on these strike-slip faults, and their associated rotation about vertical axes, can account for ∼60 km of N–S shortening. This value is similar to estimates of the Late Quaternary N–S right-lateral shear between central Iran and Afghanistan, which must be accommodated in NE Iran. The strike-slip faults also require ∼30 km of along-strike extension of the Kopeh Dagh, which is taken up by the westward component of motion between the South Caspian Basin and both Eurasia and Central Iran. It is probable that these motions occurred over the last ∼10 Ma.     

Identification of a hydrodynamic threshold in karst rocks from the Biscayne Aquifer, south Florida, USA

A hydrodynamic threshold between Darcian and non-Darcian flow conditions was found to occur in cubes of Key Largo Limestone from Florida, USA (one cube measuring 0.2 m on each side, the other 0.3 m) at an effective porosity of 33% and a hydraulic conductivity of 10 m/day. Below these values, flow was laminar and could be described as Darcian. Above these values, hydraulic conductivity increased greatly and flow was non-laminar. Reynolds numbers (Re) for these experiments ranged from <0.1 to 7. Non-laminar flow conditions observed in the hydraulic conductivity tests were observed at Re close to 1. Hydraulic conductivity was measured on all three axes in a permeameter designed specifically for samples of these sizes. Positive identification of vertical and horizontal axes as well as 100% recovery for each sample was achieved. Total porosity was determined by a drying and weighing method, while effective porosity was determined by a submersion method. Bulk density, total porosity and effective porosity of the Key Largo Limestone cubes averaged 1.5 g/cm³, 40 and 30%, respectively. Two regions of anisotropy were observed, one close to the ground surface, where vertical flow dominated, and the other associated with a dense-laminar layer, below which horizontal flow dominated.     

Landslide Susceptibility Mapping along Bhalubang–Shiwapur Area of Mid-Western Nepal Using Frequency Ratio and Conditional Probability Models

Roads constructed in fragile Siwaliks are prone to large number of instabilities. Bhalubang–Shiwapur section of Mahendra Highway lying in Western Nepal is one of them. To understand the landslide causative factor and to predict future occurrence of the landslides, landslide susceptibility mapping(LSM) of this region was carried out using frequency ratio(FR) and weights-of-evidence(W of E) models. These models are easy to apply and give good results. For this, landslide inventory map of the area was prepared based on the aerial photo interpretation, from previously published/unpublished reposts, and detailed field survey using GPS. About 332 landslides were identified and mapped, among which 226(70%) were randomly selected for model training and the remaining 106(30%) were used for validation purpose. A spatial database was constructed from topographic, geological, and land cover maps. The reclassified maps based on the weight values of frequency ratio and weights-of-evidence were applied to get final susceptibility maps. The resultant landslide susceptibility maps were verified andcompared with the training data, as well as with the validation data. From the analysis, it is seen that both the models were equally capable of predicting landslide susceptibility of the region(W of E model(success rate = 83.39%, prediction rate = 79.59%); FR model(success rate = 83.31%, prediction rate = 78.58%)). In addition, it was observed that the distance from highway and lithology, followed by distance from drainage, slope curvature, and slope gradient played major role in the formation of landsides. The landslide susceptibility maps thus produced can serve as basic tools for planners and engineers to carry out further development works in this landslide prone area.     

Reduced transition probabilities for 4~He radiative capture reactions at astrophysical energies

The reduced transition probabilities from an electric quadrupole B(E2) and reduced transition probabilities from a magnetic dipole B(M1) between the ground state and the first excited state have been calculated for the3He(α,γ)7Be,8Be(α,γ)12C and12C(α,γ)16O radiative capture reactions with the M3Y potential.These reactions are important in stellar evolution.The calculated B(M1) and B(E2) for7Be nuclei are found to be 1.082×10-3e2fm2and 1.921 e2fm4from transitions 3/2-to 1/2-,respectively.The obtained values for reduced transition probabilities B(E2) for the12C and16O nuclei from transitions 0+to 2+are 12.54 e2fm4and 14.18 e2fm4,respectively.The results are in satisfactory agreement with available experimental data.     

Characterisation of the Sarcheshmeh copper mine tailings,Kerman province,southeast of Iran

Mineral processing operation at the Sarcheshmeh porphyry copper mine has produced huge quantities of tailings materials containing sulphide minerals in particular pyrite. These tailings materials were geochemically and mineralogically characterised to assess pyrite and chalcopyrite oxidation, acid mine drainage generation, and trace element mobility to lead development of a proper remediation plan. Five vertical trenches up to 4.2 m deep were excavated from the tailings surface, and 70 solid samples were taken in 0.3 m intervals. The samples were first mineralogically analysed. Pyrite was the main sulphide mineral found in the tailings. The gangue minerals include quartz ± muscovite–illite ± chlorite ± albite ± orthoclase ± halite. The samples were geochemically analysed for total concentrations of 62 elements, paste pH, SO₄ ^2?, CO₃ ^2?, and HCO₃ ^?. The maximum concentrations of SO₄ ^2? (1,300, 1,170, 1,852, 1,960 and 837 mg/L) were observed at a depth of 0.9 m in profiles A, B, C, D and E, respectively. The tailings have a high acid-producing potential and low acid-neutralising potential (pyrite 4–6 wt %, calcite 1 wt %). Fe₂(SO₄)₃, CuSO₄, MgSO₄ and MnSO₄ were the dominant secondary sulphate minerals in the tailings. The lowest pH values (2.9, 3 and 3) were measured at a depth of 0.3 m in the profiles A, B and C, 3.9 at a depth of 0.6 m in the profile D and 3 at a depth of 0.9 m in the profile E. The upper portions of the profiles C (1.8 m) and D (2.1 m) were moderately oxidised, while oxidation in the profiles A, B and E did not extend more than 1.2, 1.2 and 1.5 m beneath the tailings surface. Zn, Pb, Rb, U, Hf, Nd, Zr and Ga show almost a constant trend with depth. Cd, Sr, Th, La and Ce increased with increasing depth of the tailings materials while, Co, V, Ti, Cr, Cu, As, Mn, Ag, Mo and Ni exhibit initially a decreasing trend from tailings surface to the depths that vary between 0.9 and 1.2. They then remained constant with the depth. The results show pyrite and chalcopyrite oxidation at surface layers of the tailings and subsequent leaching of the oxidation products and trace elements by infiltrated atmospheric precipitation.