The nature and origin of pigments in black opal from Lightning Ridge,New South Wales,Australia

Abstract

Black opal (opal-AG) owes its dark coloration to a fine-grained pigment commonly inferred to be mainly carbon, yet chemical compositions for black opals suggest there may be additional components. Here we search for such components in pigment concentrates prepared by dissolving black opal nodules (nobbies) from Lightning Ridge (NSW) in hydrofluoric acid, using electron microscopy (scanning electron microscopy, transmission electron microscopy), X-ray diffraction and laser-ablation ICP-MS. The results demonstrate the presence of sulfides—predominantly pyrite and chalcopyrite, with minor galena and Ti-oxide phases, as additional components of the pigment. ATR-FTIR analysis indicates the presence of C=O and C–H groups, consistent with an organic origin. Transmission electron microscopy images of pigment show variously deformed, originally spherical ～100?nm particles rich in sulfide and carbon, which are interpreted as thin coatings of pigment on now dissolved opaline silica spheres. Laser-ablation ICP-MS analysis identifies remnant silica in pigment concentrates, which may be interpreted as opaline silica surviving HF treatment protected as inclusions in sulfides. When examined within the context of petrographic observations from more than 1000 opal nodules (nobbies) at Lightning Ridge, these new results suggest that pigment carbon and sulfides in the nodules formed microbially under initially anoxic groundwater conditions, within pre-existing cavities concurrently being filled with silica sol ultimately derived from chemical weathering of feldspar-rich volcaniclastic sediment. Intensely black pigment layers observed at the floor of many nodules indicate settling of dark, high-density (sulfide–Ti-oxide-rich) pigment within cavities, with the implication that sulfate-reducing bacterial (SRB) activity commences early during the silica sol-gel ripening process. Microbial activity may persist until after the cavity has completely filled with the silica sol, as illustrated by abundant black opals with uniformly distributed pigment. Pigment formed at this stage may no longer be able to settle out within the ripening and increasingly viscous silica gel, thus forming pigmentation throughout the opal cavity. The existence of ‘amber’, pigment-poor opal with intensely black basal pigment layers is interpreted as signalling a lack of sulfate to sustain further SRB activity, or a change to more oxidising conditions, possibly related to interaction with surface waters within a downward-penetrating weathering front. A change in redox conditions would shut off activity of SRB and thus sulfide pigment production and allow development of aerobic microbial activity as described by others.     

Plant root traits affecting the resistance of soils to concentrated flow erosion

The effect of plant species on erosion processes may be decisive for long‐term soil protection in degraded ecosystems. The identification of functional effect traits that predict species ability for erosion control would be of great interest for ecological restoration purposes. Flume experiments were carried out to investigate the effect of the root systems of three species having contrasted ecological requirements from eroded marly lands of the French Southern Alps [i.e. Robinia pseudo acacia (tree), Pinus nigra austriaca (tree) and Achnatherum calamagrostis (grass)], on concentrated flow erosion rates. Ten functional traits, describing plant morphological and biomechanical features, were measured on each tested sample. Analyses were performed to identify traits that determine plant root effects on erosion control. Erosion rates were lowest for samples of Robinia pseudo acacia, intermediate in Achnatherum calamagrostis and highest in Pinus nigra austriaca. The three species also differed strongly in their traits. Principal components analysis showed that the erosion‐reducing potential of plant species was negatively correlated to root diameter and positively correlated to the percentage of fine roots. The results highlighted the role of small flexible roots in root reinforcement processes, and suggested the importance of high root surface and higher tensile strength for soil stabilization. By combining flume experiment to plant functional traits measurements, we identified root system features influencing plant species performance for soil protection against concentrated flow erosion. Plant functional traits related to species efficiency for erosion control represent useful tools to improve the diagnosis of land vulnerability to erosion, plant community resistance and the prediction of ecosystem functioning after ecological restoration. Copyright © 2012 John Wiley & Sons, Ltd.     

Show me the code: spatial analysis and open source

This paper considers the intersection of academic spatial analysis with the open source revolution. Its basic premise is that the potential for cross-fertilization between the two is rich, yet some misperceptions about these two communities pose challenges to realizing these opportunities. The paper provides a primer on the open source movement for academicians with an eye towards correcting these misperceptions. It identifies a number of ways in which increased adoption of open source practices in spatial analysis can enhance the development of the next generation of tools and the wider practice of scientific research and education.

Tectonic,volcanic, and hydrothermal event sequence on Deception Island (Antarctica)

On the basis of the correlation between seismic tectonostratigraphic units, volcanism, and geochemical distribution patterns of sea-floor sediments on Deception Island (Antarctica), a regional tectonic extension is suggested to explain the sequence of volcanic and hydrothermal events. The syncollapse caldera episode is composed of five tectonostratigraphic units separated by progressively tilted and bent unconformities. Each unit shows a sequence of Quaternary volcanic cones and mound structures that display high contents of Fe, Mn, and Zn. As-rich active fumaroles and hot-spring areas are associated with the postcollapse episode and linked to normal faulting and present volcanism.     

Spatio-temporal analysis of industrial composition with IVIID: an interactive visual analytics interface for industrial diversity

The industrial composition of places has received considerable attention because of the widespread belief that industrial diversity buffers regional economies from economic shocks. Subsequently, a variety of toolkits and indices have been developed with the goal of better capturing the compositional dynamics of regions. Although useful, a key drawback of these indices is their static nature, which limits the utility of these indices in a space–time context. This paper provides an overview of and applications of an interface called interactive visualization tool for indices of industrial diversity, which is a visual analytics tool developed specifically for the analysis and visualization of local measures of industrial composition for areal data. This overview will include a discussion of its key features, as well as a demonstration of the utility of the interface in exploring questions surrounding diversity and the dynamic nature of composition through space and time. A focus of this demonstration is to highlight how the interactivity and query functionality of this interface overcome several of the obstacles to understanding composition through space and time that prior toolkits and comparative static approaches have been unable to address.     

Characterization of phanerogam communities (Posidonia oceanica and Cymodocea nodosa) using side-scan-sonar images

This paper presents the most appropriate image-processing techniques available at the present time to differentiate two different seameadow communities, Posidonia oceanica and Cymodocea nodosa. The pre-processing program is an integral part of the sonar system and, therefore, is not discussed in this paper. We propose a methodology based on unsupervised classification to chart and monitor these meadows, so fundamentally important to the mediterranean ecosystem. The images used for discussion were of seabottoms in the Cabrera Archipielago in the Mediterranean Sea.