Performance of upflow anoxic bioreactor for wastewater treatment

Laboratory scale studies were conducted in an up-flow anoxic bioreactor using synthetic fertilizer wastewater for ascertaining the denitrification efficiency. The performance of the reactor was compared using ethanol and topioca starch as the carbon source. The initial No₃-N concentrations (50–250 mg/L) and hydraulic retention time (FTRT, 12–24 h) were varied to evaluate the COD and No₃-N removal. The results from this study shows that ethanol gave very good denitrification efficiency (78–98%) compared to topioca starch (68–96%).     

Sample return of interstellar matter (SARIM)

The scientific community has expressed strong interest to re-fly Stardust-like missions with improved instrumentation. We propose a new mission concept, SARIM, that collects interstellar and interplanetary dust particles and returns them to Earth. SARIM is optimised for the collection and discrimination of interstellar dust grains. Improved active dust collectors on-board allow us to perform in-situ determination of individual dust impacts and their impact location. This will provide important constraints for subsequent laboratory analysis. The SARIM spacecraft will be placed at the L2 libration point of the Sun–Earth system, outside the Earth’s debris belts and inside the solar-wind charging environment. SARIM is three-axes stabilised and collects interstellar grains between July and October when the relative encounter speeds with interstellar dust grains are lowest (4 to 20 km/s). During a 3-year dust collection period several hundred interstellar and several thousand interplanetary grains will be collected by a total sensitive area of 1 m². At the end of the collection phase seven collector modules are stored and sealed in a MIRKA-type sample return capsule. SARIM will return the capsule containing the stardust to Earth to allow for an extraction and investigation of interstellar samples by latest laboratory technologies.     

Chemical characterization and multivariate analysis of atmospheric PM<Subscript>2.5</Subscript> particles

The new European Council Directive (PE-CONS 3696/07) frames the inhalable (PM₁₀) and fine particles (PM_2.5) on priority to chemically characterize these fractions in order to understand their possible relation with health effects. Considering this, PM_2.5 was collected during four different seasons to evaluate the relative abundance of bulk elements (Cl, S, Si, Al, Br, Cu, Fe, Ti, Ca, K, Pb, Zn, Ni, Mn, Cr and V) and water soluble ions (F⁻, Cl⁻, NO₂ ⁻, NO₃ ⁻, SO₄ ²⁻, Na⁺, NH₄ ⁺, Ca²⁺ and Mg²⁺) over Menen, a Belgian city near the French border. The air quality over Menen is influenced by industrialized regions on both sides of the border. The most abundant ionic species were NO₃ ⁻, SO₄ ²⁻ and NH₄ ⁺, and they showed distinct seasonal variation. The elevated levels of NO₃ ⁻ during spring and summer were found to be related to the larger availability of the NO_x precursor. The various elemental species analyzed were distinguished into crustal and anthropogenic source categories. The dominating elements were S and Cl in the PM_2.5 particles. The anthropogenic fraction (e.g. Zn, Pb, and Cu) shows a more scattered abundance. Furthermore, the ions and elemental data were also processed using principal component analysis and cluster analysis to identify their sources and chemistry. These approach identifies anthropogenic (traffic and industrial) emissions as a major source for fine particles. The variations in the natural/anthropogenic fractions of PM_2.5 were also found to be a function of meteorological conditions as well as of long-range transport of air masses from the industrialized regions of the continent. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Hydrologic Dynamics of a Subtropical Estuary Using Geochemical Tracers,Celestún,Yucatan, Mexico

Oxygen isotopes and strontium concentrations were used as geochemical tracers to discern the sources of water to Celestún Lagoon, a small subtropical estuary on the western side of the Yucatán Peninsula of Mexico. Celestún Lagoon is underlain by karstified limestone with numerous locations where groundwater is observed discharging directly to the lagoon. In this study, samples of groundwater, lagoon surface water, and seawater (SW) were collected in April 2008 and June 2009 and analyzed for salinity, stable isotopes of oxygen, and strontium (Sr²⁺) concentrations. These geochemical tracers were used in two tertiary mixing models to calculate the relative ratio inputs of fresh groundwater, brackish groundwater, and SW to the lagoon. Two sources of groundwater were found to contribute to the surface water in the lagoon; one fresh and the other brackish with an average salinity of 19 psu. The fresh groundwater had an oxygen isotopic signature (δ¹⁸O) and strontium concentration (Sr²⁺) of δ¹⁸O?=?-3.30‰ and Sr²⁺?=?0.03 mmol/l, respectively. The brackish groundwater observed in the northern end of the lagoon add a dissimilar oxygen isotopic signature and Sr²⁺ concentration of δ¹⁸O?=?3.01‰ and Sr²⁺?=?0.12 mmol/l, respectively. Local SW had an isotopic oxygen signature and Sr²⁺ concentration between the two fresher sources (δ¹⁸O?=?1.40‰, Sr²⁺?=?0.09 mmol/l). The lagoonwide results of the two tracer mixing models (δ¹⁸O and Sr²⁺) agreed well (within 5 %) and indicated a ratio of brackish groundwater–fresh groundwater– SW of 31 %–26 %–43 % (±5 %) for the Sr²⁺ model and 35 %–25 %–40 % (± 5 %) for the δ¹⁸O model. Brackish groundwater is dominant in the northern portion of the lagoon, while SW dominates the southern portion. Fresh groundwater discharge is a significant contributor of water along the entire eastern boundary of the lagoon where mangrove forests are the dominant vegetation.     

Sea‐level changes,river activity,soil development and glaciation around the western margins of the southern North Sea Basin during the Early and early Middle Pleistocene: evidence from Pakefield,Suffolk, UK

This paper outlines evidence from Pakefield (northern Suffolk), eastern England, for sea‐level changes, river activity, soil development and glaciation during the late Early and early Middle Pleistocene (MIS 20–12) within the western margins of the southern North Sea Basin. During this time period, the area consisted of a low‐lying coastal plain and a shallow offshore shelf. The area was drained by major river systems including the Thames and Bytham. Changes in sea‐level caused several major transgressive–regressive cycles across this low‐relief region, and these changes are identified by the stratigraphic relationship between shallow marine (Wroxham Crag Formation), fluvial (Cromer Forest‐bed and Bytham formations) and glacial (Happisburgh and Lowestoft formations) sediments. Two separate glaciations are recognised—the Happisburgh (MIS 16) and Anglian (MIS 12) glaciations, and these are separated by a high sea level represented by a new member of the Wroxham Crag Formation, and several phases of river aggradation and incision. The principal driving mechanism behind sea‐level changes and river terrace development within the region during this time period is solar insolation operating over 100‐kyr eccentricity cycles. This effect is achieved by the impact of cold climate processes upon coastal, river and glacial systems and these climatically forced processes obscure the neotectonic drivers that operated over this period of time. © British Geological Survey/Natural Environment Research Council copyright 2005. Reproduced with the permission of BGS/NERC. Published by John Wiley & Sons, Ltd.     

Slab melt as metasomatic agent in island arc magma mantle sources, Negros and Batan (Philippines)

Abstract Two new cases of association of adakites with ‘normal’ island arc lavas and transitional adakites are recognized in the islands of Batan and Negros in northern and central Philippines, respectively. The Batan lavas are related to the subduction of the middle Miocene portion of the South China Sea basin along the Manila trench; those of Negros come from the almost aseismic subduction of the middle Miocene Sulu Sea crust along the Negros trench. The occurrence of the Batan adakites is consistent with previous findings showing adakitic glass inclusions within minerals of mantle xenoliths associated with Batan arc lavas. The similarity of adakite ages (1.09 Ma) and that of the metasomatized xenoliths (1 Ma) suggests that both are linked to the same slab‐melting and metasomatic event. Earlier Sr, Pb and Nd‐isotopic studies, however, also reveal the presence of an important sediment contribution to the Batan lava geochemistry. Thus, the role played by slab melts, assumed to have mid‐ocean ridge basalts‐like (MORB) isotopic characteristics, in enriching the Batan subarc mantle is largely masked by the sediment input. The Negros adakites are present only in Mount Cuernos, the volcanic center nearest to the Negros trench. Batch partial melting calculations show that the Negros adakites could be derived from a garnet amphibolitic source with normal‐MORB (N‐MORB) geochemistry. This is supported by the MORB‐like isotopic characteristics of the Mount Cuernos lavas. The volcanic rocks from the other volcanoes consist of normal arc and transitional adakitic lavas that have slightly higher Sr‐ and Pb‐isotopic ratios, probably due to slight sediment input. Mixing of adakites and normal arc lavas to produce transitional adakites is only partly supported by trace element geochemistry and not by field evidence. The transitional adakites can be modeled as partial melts of an adakite‐enriched mantle. Trace element enrichment of non‐adakitic lavas could reflect the interaction of their mantle source with uprising slab melts, as metasomatic mantle minerals scavenge certain trace elements from the adakitic fluids. Therefore, in arcs beneath which thick (up to 2 km) continent‐derived detrital sediments are involved in subduction, like in Batan, the sediment signature can overwhelm the slab melt input. In arcs like Negros where slow subduction could cause a more efficient scraping of thinner (approximately 1 km) detrital sediments, the contribution of slab melts is easier to detect.     

Assessment of long-range kinematic GPS positioning errors by comparison with airborne laser altimetry and satellite altimetry

Long-range airborne laser altimetry and laser scanning (LIDAR) or airborne gravity surveys in, for example, polar or oceanic areas require airborne kinematic GPS baselines of many hundreds of kilometers in length. In such instances, with the complications of ionospheric biases, it can be a real challenge for traditional differential kinematic GPS software to obtain reasonable solutions. In this paper, we will describe attempts to validate an implementation of the precise point positioning (PPP) technique on an aircraft without the use of a local GPS reference station. We will compare PPP solutions with other conventional GPS solutions, as well as with independent data by comparison of airborne laser data with “ground truth” heights. The comparisons involve two flights: A July 5, 2003, airborne laser flight line across the North Atlantic from Iceland to Scotland, and a May 24, 2004, flight in an area of the Arctic Ocean north of Greenland, near-coincident in time and space with the ICESat satellite laser altimeter. Both of these flights were more than 800 km long. Comparisons between different GPS methods and four different software packages do not suggest a clear preference for any one, with the heights generally showing decimeter-level agreement. For the comparison with the independent ICESat- and LIDAR-derived “ground truth” of ocean or sea-ice heights, the statistics of comparison show a typical fit of around 10 cm RMS in the North Atlantic, and 30 cm in the sea-ice region north of Greenland. Part of the latter 30 cm error is likely due to errors in the airborne LIDAR measurement and calibration, as well as errors in the “ground truth” ocean surfaces due to drifting sea-ice. Nevertheless, the potential of the PPP method for generating 10 cm level kinematic height positioning over long baselines is illustrated.     

Mineral Paragenesis of the Lepanto Copper and Gold and the Victoria Gold Deposits, Mankayan Mineral District, Philippines

Abstract: Mineral paragenesis of the alteration, ore and gangue minerals of the Lepanto epithermal copper‐gold deposit and the Victoria gold deposit, Mankayan Mineral District, Northern Luzon, Philippines, is discussed. The principal ore minerals of the Lepanto copper‐gold deposit are enargite and luzonite, with significant presence of tennantite‐tetrahedrite, chalcopyrite, sphalerite, galena, native gold/electrum and gold‐silver tellurides. Pervasive alteration zonations are commonly observed from silicification outward to advanced argillic then to propylitic zone. The ore mineralogy of the Lepanto copper‐gold deposit suggests high f_S2 in the early stages of mineralization corresponding to the deposition of the enargite‐luzonite‐pyrite assemblage. Subsequent decrease in the f_S2 formed the chalcopyrite‐tennantite‐pyrite assemblage. An increase in the f_S2 of the fluids with the formation of the covellite‐digenite‐telluride assemblage caused the deposition of native gold/electrum and gold‐silver tellurides. The principal ore minerals of the Victoria gold deposit are sphalerite, galena, chalcopyrite, tetrahedrite and native gold/electrum. The alteration halos are relatively narrow and in an outward sequence from the ore, silica alteration grades to illitic‐argillic alteration, which in turn grades to propylitic alteration. The Victoria gold mineralization has undergone early stages of silica supersaturation leading to quartz deposition. Vigorous boiling increased the pH of the fluids that led to the deposition of sulfides and carbonates. The consequent decrease in H₂S precipitated the gold. Gypsum and anhydrite mainly occur as overprints that cut the carbonate‐silica stages. The crosscutting and overprinting relationships of the Victoria quartz‐gold‐base metal veins on the Lepanto copper‐gold veins manifest the late introduction of near neutral pH hydrothermal fluids.     

Collision, subduction and accretion events in the Philippines: A synthesis

Abstract The Philippines preserves evidence of the superimposition of tectonic processes in ancient and present‐day collision and subduction zone complexes. The Baguio District in northern Luzon, the Palawan–Central Philippine region and the Mati–Pujada area in southeastern Mindanao resulted from events related to subduction polarity reversal leading to trench initiation, continent‐arc collision and autochthonous oceanic lithosphere emplacement, respectively. Geological data on the Baguio District in Northern Luzon reveal an Early Miocene trench initiation for the east‐dipping Manila Trench. This followed the Late Oligocene cessation of subduction along the west‐dipping proto‐East Luzon Trough. The Manila Trench initiation, which is modeled as a consequence of the counter‐clockwise rotation of Luzon, is attributed to the collision of the Palawan microcontinental block with the Philippine Mobile Belt. In the course of rotation, Luzon onramped the South China Sea crust, effectively converting the shear zone that bounded them into a subduction zone. Several collision‐related accretionary complexes (e.g. Romblon, Mindoro) are present in the Palawan–Central Philippine region. The easternmost collision zone boundary is located east of the Romblon group of islands. The Early Miocene southwestward shift of the collision boundary from Romblon to Mindoro started to end by the Pliocene. Continuous interaction between the Palawan microcontinental block and the Philippine Mobile Belt is presently taken up again along the collisional boundary east of the Romblon group of islands. The Mati–Pujada Peninsula area, on the other hand, is underlain by the Upper Cretaceous Pujada Ophiolite. This supra‐subduction zone ophiolite is capped by chert and pelagic limestones which suggests its derivation from a relatively deep marginal basin. The Pujada Ophiolite could be a part of a proto‐Molucca Sea plate. The re‐interpretation of the geology and tectonic settings of the three areas reaffirm the complex geodynamic evolution of the Philippine archipelago and addresses some of its perceived geological enigmas.