Estrogen pollution in a highly productive ecosystem off central-south Chile

While the presence of steroid estrogens in the environment has become a major environmental and health concern, their occurrence in coastal sediments remains poorly characterized. In this study, we measured the levels of three natural (estrone, 17β-estradiol, estriol) and one synthetic (17α-ethinylestradiol) estrogens in 54 coastal sediment samples collected from nine locations off central-southern Chile. Steroid estrogens were found in every sample. Remarkably high levels of 17α-ethinylestradiol were detected, reaching up to 48.14 ng/g dry weight. As a result, the global estrogenic loads were estimated to be high at all sites. Interestingly, they were found to correlate with the size of human populations served by sewage plants. Our study indicates that 17α-ethinylestradiol may accumulate in coastal sediments. The possible impact of this highly potent synthetic estrogen on the biota of the marine ecosystem off central-south Chile and on human health remains an open question.     

Benthic foraminifera distribution in a tourist lagoon in Rio de Janeiro, Brazil: a response to anthropogenic impacts

Rodrigo de Freitas Lagoon, located in the Rio de Janeiro City, receives several types of polluted discharges. The knowledge of the sediment microfauna correlated with heavy metal and organic matter concentrations could supply important data about the conditions of the lagoon. The benthic foraminiferal assemblage presented larger diversity and more abundant samples in the lagoon entrance than in the inner area. The Ammonia tepida - Elphidiumexcavatum foraminiferal assemblage is characterized by dwarf, corroded and weak organisms. Agglutinated species were found only near the entrance. Low abundance values and sterility of five samples in the inner area (north/northeast) can be caused by high levels of heavy metals and organic matter. A. tepida shows negative correlation with increasing heavy metals values. PAHs and coprostanol high indexes, and the absence or low presence of microfauna in samples around the lagoon margin confirm illegal flows from gas stations and domestic sewage.     

Delivery and deposition of organic matter in surface sediments of Lagoa do Caçó (Brazil)

Elemental and isotopic compositions of organic matter in surficial sediments from five transects across Lagoa do Caçó (Brazil) were analyzed to identify the depth-related processes that affect the production and deposition of sedimentary organic matter in this shallow tropical lake. Each of four transverse transects began at a margin dominated by aquatic macrophytes (Eleocharis), crossed the central deep part of the lake, and terminated in the opposite, macrophyte-dominated margin. In each transect, TOC concentrations, C/N ratios, and δ¹³C values decreased between 0 and 4 m, whereas δ¹⁵N values increased. The variables remained stable in sediment from 4 m water depth to the center of the lake at 10 m. The depth-related patterns reflect differences in both the delivery and the deposition of organic matter in the lake. Organic matter is produced in abundance in the marginal area by emersed and submerged macrophyte vegetation that diminishes with depth and disappears at 4 meters. After the disappearance of macrophytes, organic matter is produced at low rates principally by open-lake phytoplankton. Drawdown of dissolved oxygen is high in the lake margins, but it is low in the oligotrophic open waters of the lake. Preservation of organic matter is consequently better in sediments of the lake margins than in deep waters. The depth-related pattern of organic matter delivery and deposition in the sediments of Lagoa do Caçó, in which water levels are sensitive to groundwater fluctuations, shows that the elemental and isotopic compositions of sediment organic matter can provide a record of changes in the paleohydrology of this and other similar shallow lake systems.     

Volatile-rich magma injection into the feeding system during the 2001 eruption of Mt. Etna (Italy): its role on explosive activity and change in rheology of lavas

The explosive behavior and the rheology of lavas in basaltic volcanoes, usually driven by differentiation, can also be significantly affected by the kinetics of magma degassing in the upper portion of the feeding system. The complex eruption of 2001 at Mt. Etna, Italy, was marked by two crucial phenomena that occurred at the Laghetto vent on the southern flank of the volcano: 1) intense explosive activity and 2) at the end of the eruption, emission of a lava flow with higher viscosity than flows previously emitted from the same vent. Here, we investigate the hypothesis that these events were driven by the injection of volatile-rich magma into the feeding system. The input and mixing of this magma into a reservoir containing more evolved magma had the twofold effect of increasing 1) the overall concentration of volatiles and 2) their exsolution with consequent efficient vesiculation and degassing. This led to an explosive stage of the eruption, which produced a ~75-m-high cinder cone. Efficient volatile loss and the consequent increase of the liquidus temperature brought about the nucleation of Fe-oxides and other anhydrous crystalline phases, which significantly increased the magma viscosity in the upper part of the conduit, leading to the emission of a high viscosity lava flow that ended the eruption. The 2001 eruption has offered the opportunity to investigate the important role that input of volatile-rich magma may exert in controlling not only the geochemical features of erupted lavas but also the eruption dynamics. These results present a new idea for interpreting similar eruptions in other basaltic volcanoes and explaining eruptions with uncommonly high explosivity when only basic magmas are involved.     

Reconstructing fluvial bar surfaces from compound cross‐strata and the interpretation of bar accretion direction in large river deposits

The interpretation of fluvial styles from the rock record is based for a significant part on the identification of different types of fluvial bars, characterized by the geometric relationship between structures indicative of palaeocurrent and surfaces interpreted as indicative of bar form and bar accretion direction. These surfaces of bar accretion are the boundaries of flood‐related bar increment elements, which are typically less abundant in outcrops than what would be desirable, particularly in large river deposits in which each flood mobilizes large volumes of sediment, causing flood‐increment boundary surfaces to be widely spaced. Cross‐strata set boundaries, on the other hand, are abundant and indirectly reflect the process of unit bar accretion, inclined due to the combined effect of the unit bar surface inclination and the individual bedform climbing angle, in turn controlled by changes in flow structure caused by local bar‐scale morphology. This work presents a new method to deduce the geometry of unit bar surfaces from measured pairs of cross‐strata and cross‐strata set boundaries. The method can be used in the absence of abundant flood‐increment bounding surfaces; the study of real cases shows that, for both downstream and laterally accreting bars, the reconstructed planes are very similar to measured bar increment surfaces.     

旋转扰动流体中壁面湍流不稳定及其拟序结构研究Ⅱ：数值模式

对第一部分的实验结果进行了讨论,指出局地最大、最小涡度的存在与所谓的正压不稳定和大气中经常观测到的滚动涡有关。速度廓线中的拐点和涡度极大值点对应不稳定发展的位置。另外,为了改进湍流的模拟,根据“准正则”近似,发展了一个三阶闭合模式。这个模型已被证明可以描述与湍流过程有关的流体动力学变量的趋势。     

Contribution of the tully groups to the soft X-ray background

We examine a model for the expected contributions to the soft X-ray background (SXRB) due to bremsstrahlung and re-combination radiation of gas, enriched with heavy elements, located in groups of galaxies taken from Tully'sCatalog of Nearby Groups of Galaxies. It is shown that the contribution to the SXRB of groups of galaxies can explain up to 20% of the observed flux depending on the chemical composition and ratio of emitting mass to assumed virial mass.     

Eruption and mass-wasting-induced processes during the late holocene destructive phase of Nevado del Ruiz volcano, Colombia

The November 13, 1985, eruption was characteristic of the Arenas eruptive stage of Nevado del Ruiz, the most recent of a series of twelve eruptive stages that have occurred in the past 11,000 years. Eruptive sequences, deposits and processes similar to that of 1985 have characterized the behavior of Nevado del Ruiz during three major prehistorical and historical eruptive stages: the approximately 3300-3100 yr. B.P. Hedionda, the 16th century Azufrado, and the mid-1800's Lagunillas eruptive stages, that partly destroyed the present Ruiz summit.According to the interpretation of the stratigraphic record of prehistorical eruptions and historical accounts, almost every recent magmatic event was small or short-lived. Nevertheless, rockslide-debris avalanches and catastrophic debris flows were triggered in all the eruptions owing to slope failures related to specific tectonic features of Ruiz volcano and/or to significant interactions between pyroclastic debris and the ice cap. Evidence for headward retreat of avalanche scarps during multiple eruptions reinforce the case that large slope failures can occur repeatedly at a large-volume volcano like Ruiz without reconstruction of the edifice. The latest Ruiz eruptions that involved rockslide-debris avalanches resemble in part the Shiveluch 1964 event for which evidence of lateral blast deposits are lacking, but differ in part from this type because non-eruptive and mass-wasting processes also triggered rockslide-debris avalanches.Many factors render the cluster of domes of the Ruiz summit unstable, including: (1) deeply dissected troughs opened toward the north-northeast (Azufrado), east (Lagunillas), and south (Recio) flanks; (2) strongly hydrothermally altered north and east flanks of the summit; (3) currently glaciated or recently deglaciated, high cliffs; (4) steep unstable margins of the ice cap on the north and east.Thus, in light of its past behavior, a small eruption or an earthquake might trigger catastrophic rockslide-debris avalanches. Furthermore, such avalanches as well as glacial outburst-floods and ice avalanches could induce debris flows by mobilizing weathered, water-saturated, and unconsolidated rocks or deposits.     

Growth pattern and changes in abundance of the endangered bat star Asterina stellifera

The sea star Asterina stellifera has declined during the last decade and is currently abundant only in the southern limit of its former range. We surveyed this population over 5 years to model individual growth and explore the relationship of changes in local abundance with variation in environmental factors and the reproductive status of individuals. Our results show that A. stellifera is a species with slow growth and a relatively long lifespan. Contrary to expectations for temperate species, growth rates were fairly constant through the year and therefore models including seasonal oscillations were inappropriate. The abundance of this species increased significantly from early spring to early summer, likely due to augmented activity and small‐scale aggregation during the reproductive season that affected our estimates of abundance. No significant recruitment occurred during the 5 years studied. The lack of recruitment during long periods and the slow individual growth rates make A. stellifera particularly vulnerable to local extinction. This study was performed prior to the arrival in the study area of the invasive kelp Undaria pinnatifida and side‐gilled sea slug Pleurobranchaea maculata, species that threaten the community structure where A. stellifera lives. Therefore, the information reported here will be essential to assessing the impacts of these exotic species on this sea star population.     

天然气水合物稳定带内流体压裂计算的程序耦合方法

海洋天然气水合物稳定带气烟囱结构中存在被水合物充填的裂隙, 表明在自然条件下沉积物中曾发生过流体压裂以及相关的流体流动和水合物形成。在水合物稳定带内实施人为的流体压裂工程, 并联合其他方法(如降压或注热)进行水合物开采, 有望提高开采效率。水合物稳定带内, 无论是自然条件下发生的流体压裂过程, 还是人为实施的流体压裂工程, 都存在水合物反应和沉积物裂隙变形之间的耦合响应。当前, 已有不少数值程序对水合物反应与沉积物弹塑性变形的耦合过程进行了定量研究, 但尚没有数值程序能够计算水合物反应和离散裂隙变形之间的耦合过程。文章将TOUGH+Hydrate程序、IC-FERST和Solidity两者的耦合程序进行了进一步耦合, 为水合物稳定带内的流体压裂计算提供了一种耦合计算方法, 同时通过一个算例初步验证了该耦合计算方法的可行性。验证结果表明, 该耦合计算方法经进一步改进后有望应用于定量研究水合物稳定带内的裂隙变形和水合物反应过程。