Relationships between multibeam backscatter,sediment grain size and Posidonia oceanica seagrass distribution

The use of data, including bathymetry, backscatter intensity and the angular response of backscatter intensity, collected using multibeam sonar (MBS) systems to recognise seabed types was evaluated in the inner shelf of central western Sardinia (western Mediterranean sea), a site characterised by a complex seabed including sandy and gravelly sediments, Posidonia oceanica seagrass beds growing on hardgrounds (i.e. biogenic carbonates) and sedimentary substrates.     

Eruptive versus non-eruptive behaviour of large calderas: the example of Campi Flegrei caldera (southern Italy)

Caldera eruptions are among the most hazardous of natural phenomena. Many calderas around the world are active and are characterised by recurrent uplift and subsidence periods due to the dynamics of their magma reservoirs. These periods of unrest are, in some cases, accompanied by eruptions. At Campi Flegrei caldera (CFc), which is an area characterised by very high volcanic risk, the recurrence of this behaviour has stimulated the study of the rock rheology around the magma chamber, in order to estimate the likelihood of an eruption. This study considers different scenarios of shallow crustal behaviour, taking into account the earlier models of CFc ground deformation and caldera eruptions, and including recent geophysical investigations of the area. A semi-quantitative evaluation of the different factors that lead to magma storage or to its eruption (such as magma chamber size, wall-rock viscosity, temperature, and regional tectonic strain rate) is reported here for elastic and viscoelastic conditions. Considering the large magmatic sources of the CFc ignimbrite eruptions (400–2,000 km³) and a wall-rock viscosity between 10¹⁸ and 10²⁰ Pa s, the conditions for eruptive failure are difficult to attain. Smaller source dimensions (a few cubic kilometres) promote the condition for fracture (eruption) rather than for the flow of wall rock. We also analyse the influence of the regional extensional stress regime on magma storage and eruptions, and the thermal stress as a possible source of caldera uplift. The present study also emphasises the difficulty of distinguishing eruption and non-eruption scenarios at CFc, since an unambiguous model that accounts for the rock rheology, magma-source dimensions and locations and regional stress field influences is still lacking.     

Adriatic coast as a microcosm for global genotoxic marine contamination--a long-term field study

Global changes in the marine environment and the continuing disposal of genotoxic xenobiotics are increasing the importance of environmental pollution monitoring and of biomonitoring programs. Current approaches focus on investigations at regional and local levels in an attempt to precisely define the nature and extent of any potential environmental crisis. We have initiated, for the first time, a long-term biomonitoring program focusing on the Croatian coast of the Adriatic Sea to contribute to a more detailed understanding of marine genotoxic effects using the mussels Mytilus galloprovincialis Lam., collected along the eastern Adriatic coast over a period of five years (1998-2002), as a key test organism. The integrity of DNA in its gill homogenate was examined by the Fast Micromethod. The strand scission factor (SSF) values, as a measure of DNA integrity, DNA damage or incomplete repair have been used for the ranking of sampling sites with respect to significant genotoxic stress due to the influence or effects of genotoxic xenobiotics. The region of Split (Kastela Bay) proved to be the area with the heaviest load of genotoxic agents. The investigation of harmful effects in the ecosystem based on biomonitoring of genetic and other agents, not only on local levels but also on a wider scale, is considered as an important step in marine environmental management.     

Crustal contamination and crystal entrapment during polybaric magma evolution at Mt. Somma–Vesuvius volcano, Italy: Geochemical and Sr isotope evidence

New major and trace element analyses and Sr-isotope determinations of rocks from Mt. Somma–Vesuvius volcano produced from 25 ky BP to 1944 AD are part of an extensive database documenting the geochemical evolution of this classic region. Volcanic rocks include silica undersaturated, potassic and ultrapotassic lavas and tephras characterized by variable mineralogy and different crystal abundance, as well as by wide ranges of trace element contents and a wide span of initial Sr-isotopic compositions. Both the degree of undersaturation in silica and the crystal content increase through time, being higher in rocks produced after the eruption at 472 AD (Pollena eruption). Compositional variations have been generally thought to reflect contributions from diverse types of mantle and crust. Magma mixing is commonly invoked as a fundamental process affecting the magmas, in addition to crystal fractionation. Our assessment of geochemical and Sr-isotopic data indicates that compositional variability also reflects the influence of crustal contamination during magma evolution during upward migration to shallow crustal levels and/or by entrapment of crystal mush generated during previous magma storage in the crust. Using a variant of the assimilation fractional crystallization model (Energy Conservation–Assimilation Fractional Crystallization; [Spera and Bohrson, 2001. Energy-constrained open-system magmatic processes I: General model and energy-constrained assimilation and fractional crystallization (EC–AFC) formulation. J. Petrol. 999–1018]; [Bohrson, W.A. and Spera, F.J., 2001. Energy-constrained open-system magmatic process II: application of energy-constrained assimilation–fractional crystallization (EC–AFC) model to magmatic systems. J. Petrol. 1019–1041]) we estimated the contributions from the crust and suggest that contamination by carbonate rocks that underlie the volcano (2 km down to 9–10 km) is a fundamental process controlling magma compositions at Mt. Somma–Vesuvius in the last 8 ky BP. Contamination in the mid- to upper crust occurred repeatedly, after the magma chamber waxed with influx of new mantle- and crustal-derived magmas and fluids, and waned as a result of magma withdrawal and production of large and energetic plinian and subplinian eruptions.     

Modeling the Uncertainty in the Layout of Geological Units by Implicit Boundary Simulation Accounting for a Preexisting Interpretive Geological Model

Natural Resources Research - An implicit simulation algorithm that uses signed distance functions is proposed to represent subsurface geological configuration while accounting for two sources of...     

Fracture system in Phlegraean Fields (Naples,southern Italy)

During the 1983 seismic crisis in the Phlegraean Fields bradyseismic region (southern Italy), a structural analysis of the area was carried out.With a detailed field survey based on a net of 34 measure stations, a total of 536 fractures (mainly joints and a few normal faults) were measured on a 10 × 10 km area in volcanites capable of memorizing post depositional stress activity by fracturing.The analysis of the collected data was performed with the data bank of the University of Rome computer facilities. The azimuthal analysis of total fractures showed a nonrandom distribution with 5 major sets: N13°E, N45°E, N14°W, N55°W and E-W. These preferential orientations have been detected with an automatic fitting of gaussian curves (bell curves) on the azimuthal histograms. The areal distribution showed that all these fracture sets are in general present in the main collapse area. An azimuthal analysis performed by selecting the data collected for rocks older than 4,600 y BP showed a possible youngest age for the N14°W set (domain) (E-W extension). Fractures with an «opening» wider than 1 cm presented the same 5 azimuthal sets and fit fairly well with a concentric distribution around the main collapse area. The presence of an analogous radial pattern is not evident. A tentative interpretation model relates the superficial fracture sets to two possible causes: volcanic activity, including doming and collapsing, and propagation of active tensile deformations in the sedimentary basement due to regional stress trajectories.Contribution of «Centro di Studio per la Geologia dell'Italia Centrale», CNR, Roma.     

Petrology of potassic alkaline ultramafic and carbonatitic rocks from Planalto da Serra (Mato Grosso State), Brazil

The Planalto da Serra igneous rocks form plugs, necks and dykes of carbonate-rich ultramafic lamprophyres (aillikites and glimmerites with kamafugitic affinity) and carbonatites (alvikites and beforsites). Phlogopite and/or tetraphlogopite, diopside and melanitic garnet are restricted to aillikitic rock-types, whereas pyroclore occurs only in carbonatites. Aillikites and carbonatites are altered to hydrotermalites, having chlorite and serpentine as dominant minerals. Planalto da Serra igneous rock association has kamafugitic affinity (i.e. effusive, ultrapotassic. High LREE/HREE fractionation, incompatible elements data and Sr-Nd isotopes, suggest that the K-ultramafic alkaline and carbonatite rocks originated from a variably metasomatized mantle source enriched in radiogenic Sr. Crustal contamination is negligible or absent. Age values of 600 Ma rule out the geochronological relationship between the investigated intrusions and the Mesozoic alkaline bodies from the Azimuth 125° lineament. The TDM model ages allow to conclude that Planalto da Serra magma is derived from the partial melting of a mantle source metasomatised by K-rich carbonatated melt during the Early to Late Neoproterozoic. On the basis of alkaline magmatism repetitions at 600 Ma and 90–80 Ma we question the subsistence of a stationary mantle plume for so long time.     

Application of Laser‐Induced Breakdown Spectroscopy and Hyperspectral Images for Direct Evaluation of Chemical Elemental Profiles of Coprolites

This study demonstrates the application of laser‐induced breakdown spectroscopy (LIBS) and hyperspectral imaging to the investigation of coprolite and fossil samples. Solid samples from the Permian (seven coprolites and one fossil), Cretaceous (one coprolite) and Oligo‐Miocene (two coprolites) periods were directly analysed, and emission spectra from 186 to 1042 nm were obtained in several areas covering coprolite/fossil and rock material. Initial exploratory analyses were performed using principal component analysis with the data set normalised by the norm (Euclidean norm = 1). After identification and selection of emission lines of eleven elements (Al, Ca, Cr, Fe, K, Mg, Mn, Na, Ni, P and Si), the signals were normalised again by the relative intensity of the selected element. Phosphorus was identified mainly in the coprolites, while K and Na were primarily found in the rock material. In several cases, there was a positive correlation between Ca and P. A sample from the Oligo‐Miocene series was also analysed using inductively coupled plasma‐optical emission spectrometry (ICP‐OES) (rock and coprolites were analysed separately). Based on the quantitative results from ICP‐OES, it was confirmed that the tendency was the same as that observed with the results obtained from LIBS directly in the solid sample.     

Insights into ground response during underground coal gasification through thermo-mechanical modeling

This paper presents a coupled thermo-mechanical model to investigate the ground response during underground coal gasification (UCG). The model incorporated the temporal and spatial development of temperature, the gradual growth of the cavity, and temperature-dependent material properties. Model verification was made against two benchmarks to acquire the confidence for the predictive purpose. The first exercise demonstrated the correctness of the model implemented in COMPASS. The second exercise showed that using the ash-filled cavity to represent null or empty zones is a good option in the numerical modeling and provided highly comparable results to other models. Based on the Hanna UCG trial, different cases were simulated to investigate the effects of the cavity size in the coal seam and the thermal expansion coefficient of the caprock and base rock on key features that take place during the process of UCG. A maximum temperature in the range of 1200–1500 ℃ was induced by the gasification of coal, and a cavity with a maximum length of 13.5 m was formed after 30 days of simulation. Meanwhile, small vertical displacement in the range of -5–12 mm took place near the cavity because of the thermal expansion of the geologic materials and the reduction of the overall weight with the creation of the cavity. In addition, it was found the thermal expansion coefficients can influence the thermo-mechanical response of geologic materials, but the effects were insignificant when its order of magnitude was smaller than 10^-6 K^-1.