Behaviour of metals and nutrients in soils and groundwater of a karst polje

The Croatian south part of the country is mainly composed of strongly krastified carbonate rocks. Also in this south part of Croatia is lacking of large depressions and poljes with thick covers. Some karst poljes and depressions may have thick covers, like for example the Vransko polje. The Vransko polje is characterised by an intensive agricultural activity. At the centre of the polje is located a karst spring (Turanjsko jezero), which is used for the water supply of the town Biograd and its surroundings. Total metals, nutrients (nitrate, ammonia, phosphate), organic matter content and cation exchange capacity (CEC) were measured in soil samples collected from the polje. Metals and nutrients were also measured in the water samples of channel Kotarka (which is passing through the area) and three springs (Turanjsko jezero, Kakma and Tinj). Measured total concentrations of metals of soil samples were treated by R-cluster multivariate statistical analysis. The result of statistical analysis showed grouping of metals with similar behaviour. Content of metals and nutrients were low in the spring samples but high in the water sample of the channel Kotarka, because the channel drains the water from the surroundings. Although agricultural activity in the Vransko polje is high, there is no high anthropogenic influence on groundwater and soil. They are both of good quality.     

The role of intracontinental deformation in supercontinent assembly: insights from the Ribeira Belt,Southeastern Brazil (Neoproterozoic West Gondwana)

In this study, we challenge the multiple collision model for the tectonic evolution of the Neoproterozoic Ribeira Belt in Southeastern Brazil. New U–Pb SHRIMP data reveal Palaeoproterozoic (2153 ± 15 Ma) and Cryogenian (783 ± 6 and 768 ± 8 Ma) granitic rocks in the Embu Domain, and detrital zircon data of metasedimentary units from the Embu and Costeiro domains suggest a coherent tectonic evolution for the whole Ribeira Belt. Rather than by multiple collisions, these data are best explained by a simpler tectonic model involving continent (craton)‐volcanic arc collisions in the Dom Feliciano and Brasilia belts that led to intracontinental crustal thickening of the adjacent thinned hinterland (Ribeira Belt) at ~640–610 Ma, followed by widespread post‐collisional magmatism and rift‐related sedimentation at ~600–540 Ma. We suggest that intracontinental orogeny is a relevant process during supercontinent assembly, as illustrated here by the evolution of significant parts of the Brasiliano orogen.     

Quantification of Metals and Semimetals in Carbon‐Rich Rocks: A New Sequential Protocol Including Extraction from Humic Substances

We have developed a new sequential extraction technique that does not require complex procedures and is efficient in determining metal and semimetal contents of carbon‐rich rocks. Six geological reference materials (SBC‐1, SCHS‐1, SCo‐1, SDO‐1, SGR‐1b and SLg‐1) and an in‐house black shale (SH‐1) were selected to test the method, which consists of four main digestion steps involving: (a) dilute HCl acid; (b) NaOH; (c) aqua regia; and (d) hydrofluoric acid. Compared with traditional aqua regia + hydrofluoric acid attack, this new protocol recovers more of the moderately volatile elements during early extraction of humic substances. In addition when compared with reference values, those for most elements are in agreement within uncertainty. Furthermore, this new protocol reveals important information on the partitioning of elements; for instance, steps one and two indicate which elements are associated with carbonates and organic phases from fulvic and humic acid extractions, whereas step three provides results for which elements are associated with sulfide minerals and step four indicates which elements remained in the silicate and oxide phases.     

Geophysical investigation of the Colônia structure,Brazil

The origin of the nearly circular Colônia structure, located at the southwestern edge of the city of São Paulo, Brazil, has been the subject of a long‐standing debate, ever since the 1960s when the structure was first investigated by geophysical methods. The structure still raises interest for geological research, as its sedimentary infill holds important paleoclimatic information about the evolution of the tropical rainforest, as well as the interplay between the South American summer monsoon, the Intertropical Convergence Zone, and the southern Westerly wind belt—for possibly as long as several million years. In addition, the search for evidence to conclusively establish the origin of this structure continues, and the answer most likely lies in the lower portions of the basin's sedimentary infill, which also holds a significant potential for underground water resources. Here, we present the results from recent seismic (reflection and HVSR), gravimetric, and geoelectrical surveys. They have provided a reliable image of the sedimentary infill, and the maximum depth to basement within the structure has been constrained consistently by the different methods to approximately ?400 m. The geophysical data have also allowed to map the lateral contact between the crystalline basement rocks and the sedimentary infill, which indicates a diameter of approximately 2.8 km for the sedimentary basin, with 3.6 km being the diameter of the outermost limit of the structure. A total of six seismic stratigraphic boundaries were identified within the sedimentary infill, providing a framework for the planning of a deep drilling campaign and subsequent sampling program aimed at geological and paleoclimatology studies.     

Dealing with uncertainties in angles-only initial orbit determination

A method to deal with uncertainties in initial orbit determination (IOD) is presented. This is based on the use of Taylor differential algebra (DA) to nonlinearly map uncertainties from the observation space to the state space. When a minimum set of observations is available, DA is used to expand the solution of the IOD problem in Taylor series with respect to measurement errors. When more observations are available, high order inversion tools are exploited to obtain full state pseudo-observations at a common epoch. The mean and covariance of these pseudo-observations are nonlinearly computed by evaluating the expectation of high order Taylor polynomials. Finally, a linear scheme is employed to update the current knowledge of the orbit. Angles-only observations are considered and simplified Keplerian dynamics adopted to ease the explanation. Three test cases of orbit determination of artificial satellites in different orbital regimes are presented to discuss the feature and performances of the proposed methodology.     

Reduced-order optimal control of water flooding using proper orthogonal decomposition

Model-based optimal control of water flooding generally involves multiple reservoir simulations, which makes it into a time-consuming process. Furthermore, if the optimization is combined with inversion, i.e., with updating of the reservoir model using production data, some form of regularization is required to cope with the ill-posedness of the inversion problem. A potential way to address these issues is through the use of proper orthogonal decomposition (POD), also known as principal component analysis, Karhunen–Loève decomposition or the method of empirical orthogonal functions. POD is a model reduction technique to generate low-order models using ‘snapshots’ from a forward simulation with the original high-order model. In this work, we addressed the scope to speed up optimization of water-flooding a heterogeneous reservoir with multiple injectors and producers. We used an adjoint-based optimal control methodology that requires multiple passes of forward simulation of the reservoir model and backward simulation of an adjoint system of equations. We developed a nested approach in which POD was first used to reduce the state space dimensions of both the forward model and the adjoint system. After obtaining an optimized injection and production strategy using the reduced-order system, we verified the results using the original, high-order model. If necessary, we repeated the optimization cycle using new reduced-order systems based on snapshots from the verification run. We tested the methodology on a reservoir model with 4050 states (2025 pressures, 2025 saturations) and an adjoint model of 4050 states (Lagrange multipliers). We obtained reduced-order models with 20–100 states only, which produced almost identical optimized flooding strategies as compared to those obtained using the high-order models. The maximum achieved reduction in computing time was 35%.     

Cost–benefit analysis of flood mitigation measures: a case study employing high-performance hydraulic and damage modelling

Natural Hazards - This paper shows a detailed, advanced procedure to implement cost–benefit analyses (CBAs) in order to assess the effectiveness of flood mitigation measures. The town of Lodi...