Molecular and isotopic characterization of the particulate organic matter from an eutrophic coastal bay in SE Brazil

The present work aimed at studying the origin of particulate organic matter in Guanabara Bay and in some rivers of the Guanabara basin by using elemental composition, isotopic ratios (δ¹³C and δ¹⁵N) and molecular markers (sterols) in samples collected in two periods (winter and summer). Elemental and isotopic compositions were determined by dry combustion and mass spectrometry, respectively, while sterols were investigated by GC–FID and GC–MS. Higher sterol concentrations were present in the north-western part of the bay in winter (5.10–23.5 μg L^–1). The high abundance of algal sterols (26–57% of total sterols), the elemental composition (C/N=6–8) and the isotopic signatures (δ¹³C=−21.3‰ to −15.1‰ and δ¹⁵N=+7.3‰ to +11.1‰) suggested the predominance of autochthonous organic matter, as expected for an eutrophic bay, although seasonal variation in phytoplankton activity was observed. Coprostanol concentration (fecal sterol) was at least one order of magnitude higher in the particulate material from fluvial samples (4.65–55.98 μg L^–1) than in the bay waters (<0.33 μg L^–1). This could be ascribed to a combination of factors including efficient particle removal to sediments in the estuarine transition zone, dilution with bay water and bacterial degradation during particle transport in the water column.     

Implementation aspects of eigendecomposition‐based high‐resolution velocity spectra

In this paper, we discuss high‐resolution coherence functions for the estimation of the stacking parameters in seismic signal processing. We focus on the Multiple Signal Classification which uses the eigendecomposition of the seismic data to measure the coherence along stacking curves. This algorithm can outperform the traditional semblance in cases of close or interfering reflections, generating a sharper velocity spectrum. Our main contribution is to propose complexity‐reducing strategies for its implementation to make it a feasible alternative to semblance. First, we show how to compute the multiple signal classification spectrum based on the eigendecomposition of the temporal correlation matrix of the seismic data. This matrix has a lower order than the spatial correlation used by other methods, so computing its eigendecomposition is simpler. Then we show how to compute its coherence measure in terms of the signal subspace of seismic data. This further reduces the computational cost as we now have to compute fewer eigenvectors than those required by the noise subspace currently used in the literature. Furthermore, we show how these eigenvectors can be computed with the low‐complexity power method. As a result of these simplifications, we show that the complexity of computing the multiple signal classification velocity spectrum is only about three times greater than semblance. Also, we propose a new normalization function to deal with the high dynamic range of the velocity spectrum. Numerical examples with synthetic and real seismic data indicate that the proposed approach provides stacking parameters with better resolution than conventional semblance, at an affordable computational cost.     

Geomorphic influence on small glacier response to post‐Little Ice Age climate warming: Julian Alps,Europe

The evolution of glaciers and ice patches, as well as the equilibrium‐line altitude (ELA) since the Little Ice Age (LIA) maximum were investigated in the Julian Alps (south‐eastern European Alps) including ice masses that were previously unreported. Twenty‐three permanent firn and ice bodies have been recognized in the 1853 km² of this alpine sector, covering a total area in 2012 of 0.385 km², about one‐fifth of the area covered during the LIA (2.350 km²). These features were classified as very small glaciers, glacierets or ice patches, with major contribution to the mass balance from avalanches and wind‐blown snow. Localized snow accumulation is also enhanced in the area due to the irregular karst topography. The ice masses in the region are at the lowest elevations of any glaciers in the Alpine Chain, and are characterized by low dynamics. The ELAs of the two major LIA glaciers (Canin and Triglav) have been established at 2275 ± 10 m and 2486 ± 10 m, respectively, by considering the reconstructed area and digital elevation model (DEM) and using an accumulation area ratio (AAR) of 0.44 ± 0.07, typical of small cirque glaciers. Changes in the ELA and glaciers extension indicate a decoupling from climate. This is most evident in the smallest avalanche‐dominated ice bodies, which are currently controlled mainly by precipitation. The damming effect of moraine ridges and pronival ramparts at the snout of small ice bodies in the Julian Alps represents a further geomorphological control on the evolution of such ice masses, which seem to be resilient to recent climate warming instead of rapidly disappearing as should be expected. Copyright © 2016 John Wiley & Sons, Ltd.     

Urbanization impacts upon catchment hydrology and gully development using mutli‐temporal digital elevation data analysis

Urbanization can change catchment hydrology, accelerating gully erosion and causing serious damage to urban structures like roads, bridges and buildings. Increased impervious surfaces lead to large, rapid increases in surface runoff in urban catchments during storm events, as well as changes in the upslope contributing area due to rerouting of urban runoff that can exacerbate erosion. Accounting for changes in surface drainage patterns Gama City, Brazil, is used to predict areas prone to accelerate gullying and develop a method of assessing the potential for gully erosion produced by urbanization. The method is based on the analysis and comparison of detailed digital elevation models (DEMs) of the natural condition before urbanization and the topography after urbanization. The study site is located in an area where changes in drainage patterns associated with rapid urbanization in the last 30 years have resulted in severe gullying. Our analysis identifies areas potentially susceptible to gullying and highlights the erosional influence of increased flow concentration caused by urban occupation, a finding that has implications and applications for strategies to prevent gully development in cities or areas undergoing urban expansion. Copyright © 2010 John Wiley & Sons, Ltd.     

Petrology and geochemistry of Camiguin Island, southern Philippines: insights to the source of adakites and other lavas in a complex arc setting

Camiguin is a small volcanic island located 12 km north of Mindanao Island in southern Philippines. The island consists of four volcanic centers which have erupted basaltic to rhyolitic calcalkaline lavas during the last ∼400 ka. Major element, trace element and Sr, Nd and Pb isotopic data indicate that the volcanic centers have produced a single lava series from a common mantle source. Modeling results indicate that Camiguin lavas were produced by periodic injection of a parental magma into shallow magma chambers allowing assimilation and fractional crystallization (AFC) processes to take place. The chemical and isotopic composition of Camiguin lavas bears strong resemblance to the majority of lavas from the central Mindanao volcanic field confirming that Camiguin is an extension of the tectonically complex Central Mindanao Arc (CMA). The most likely source of Camiguin and most CMA magmas is the mantle wedge metasomatized by fluids dehydrated from a subducted slab. Some Camiguin high-silica lavas are similar to high-silica lavas from Mindanao, which have been identified as “adakites” derived from direct melting of a subducted basaltic crust. More detailed comparison of Camiguin and Mindanao adakites with silicic slab-derived melts and magnesian andesites from the western Aleutians, southernmost Chile and Batan Island in northern Philippines indicates that the Mindanao adakites are not pure slab melts. Rather, the CMA adakites are similar to Camiguin high-silica lavas which are products of an AFC process and have negligible connection to melting of subducted basaltic crust. Received: 27 February 1998 / Accepted: 27 August 1998     

Quantification of Metals and Semimetals in Carbon‐Rich Rocks: A New Sequential Protocol Including Extraction from Humic Substances

We have developed a new sequential extraction technique that does not require complex procedures and is efficient in determining metal and semimetal contents of carbon‐rich rocks. Six geological reference materials (SBC‐1, SCHS‐1, SCo‐1, SDO‐1, SGR‐1b and SLg‐1) and an in‐house black shale (SH‐1) were selected to test the method, which consists of four main digestion steps involving: (a) dilute HCl acid; (b) NaOH; (c) aqua regia; and (d) hydrofluoric acid. Compared with traditional aqua regia + hydrofluoric acid attack, this new protocol recovers more of the moderately volatile elements during early extraction of humic substances. In addition when compared with reference values, those for most elements are in agreement within uncertainty. Furthermore, this new protocol reveals important information on the partitioning of elements; for instance, steps one and two indicate which elements are associated with carbonates and organic phases from fulvic and humic acid extractions, whereas step three provides results for which elements are associated with sulfide minerals and step four indicates which elements remained in the silicate and oxide phases.     

The role of intracontinental deformation in supercontinent assembly: insights from the Ribeira Belt,Southeastern Brazil (Neoproterozoic West Gondwana)

In this study, we challenge the multiple collision model for the tectonic evolution of the Neoproterozoic Ribeira Belt in Southeastern Brazil. New U–Pb SHRIMP data reveal Palaeoproterozoic (2153 ± 15 Ma) and Cryogenian (783 ± 6 and 768 ± 8 Ma) granitic rocks in the Embu Domain, and detrital zircon data of metasedimentary units from the Embu and Costeiro domains suggest a coherent tectonic evolution for the whole Ribeira Belt. Rather than by multiple collisions, these data are best explained by a simpler tectonic model involving continent (craton)‐volcanic arc collisions in the Dom Feliciano and Brasilia belts that led to intracontinental crustal thickening of the adjacent thinned hinterland (Ribeira Belt) at ~640–610 Ma, followed by widespread post‐collisional magmatism and rift‐related sedimentation at ~600–540 Ma. We suggest that intracontinental orogeny is a relevant process during supercontinent assembly, as illustrated here by the evolution of significant parts of the Brasiliano orogen.     

DNA damage and apoptosis in the mussel Mytilus galloprovincialis

The effects of known genotoxic substances (4-nitroquinoline-N-oxide, benzo[a]pyrene, teniposide, etoposide, cycloheximide, tributyltin) on human cells (FLC, HL-60) and on mussels were investigated. The correlations between formation of DNA strand breaks and DNA fragmentation characteristic for the process of apoptosis were estimated. Strand breaks induced by 4-nitroquinoline-N-oxide and benzo[a]pyrene did not correlate with DNA fragmentation detected in the process of apoptosis. Induction of internucleosomal DNA fragmentation in HL-60 cells was initiated by teniposide, etoposide and tributyltin, while in the gills of mussels this was detected only with tributyltin. Levels of DNA strand breaks in natural mussel populations, living at locations under the influence of urban and industrial wastes, do not mirror the apoptotic processes.     

Symmetries and choreographies in families that bifurcate from the polygonal relative equilibrium of the <Emphasis Type="Italic">n</Emphasis>-body problem

We use numerical continuation and bifurcation techniques in a boundary value setting to follow Lyapunov families of periodic orbits and subsequently bifurcating families. The Lyapunov families arise from the polygonal equilibrium of n bodies in a rotating frame of reference. When the frequency of a Lyapunov orbit and the frequency of the rotating frame have a rational relationship, then the orbit is also periodic in the inertial frame. We prove that a dense set of Lyapunov orbits, with frequencies satisfying a diophantine equation, correspond to choreographies. We present a sample of the many choreographies that we have determined numerically along the Lyapunov families and along bifurcating families, namely for the cases \(n=3\), 4, and 6–9. We also present numerical results for the case where there is a central body that affects the choreography, but that does not participate in it. Animations of the families and the choreographies can be seen at the link below.